Surface and Coatings Technology, 49 (1991) ix—xiii Contents COATINGS FOR USE AT HIGH TEMPERATURES Coatings to resist high temperature corrosion Role of platinum in aluminide coatings H. M. Tawancy, N. M. Abbas (Dhahran, Saudi Arabia) and T. N. Rhys-Jones (Bristol, U.K.) Hydrogen ion interaction behaviour of plasma-sprayed TiC coatings M. S. Mathur and J. S. C. McKee (Winnipeg, Man, Canada) Chemical vapor deposition of Si,N, onto metal substrates T. Taniuchi, T. Adachi and K. Kobayashi (Tokyo, Japan) Oxidation resistance of slurry aluminides on high temperature titanium alloys B. G. McMordie (Limerick, PA, U.S.A.) Vacuum-plasma-sprayed silicon coatings D. J. Varacalle, Jr. (Idaho Falls, ID, U.S.A.), H. Herman, G. A. Bancke (Stony Brook, NY, U.S.A.), T. D. Burchell and G. R. Romanoski (Oak Ridge, TN, U.S.A.) Coatings to resist wear at high temperatures High temperature erosion behavior of titanium nitride and zirconium nitride coatings J. A. Sue and H. H. Troue (Indianapolis, IN, U.S.A.) Laser deposition of carbide-reinforced coatings W. Cerri, R. Martinella, C. P. Mor (Segrate, Italy), P. Bianchi and D. D. ‘Angelo (Milano, Italy) Thermal behaviour of thick TiC layers made by plasma spraying H.-D. Steffens, M. Dvorak (Dortmund, F.R.G.) and P. Groot (Petten, The Netherlands) Study of surface preparation for enhanced resistance to thermal shocks of plasma-sprayed TiC coatings F. Bordeaux, R. G. Saint Jacques (Varennes, Que, Canada) and C. Moreau (Boucherville, Que, Canada) Thermal barrier coatings Laser surface sealing and strengthening of zirconia coatings A. Petitbon, L. Boquet (Marcoussis, France) and D. Delsart (St.-Denis, France) Plasma-sprayed composite coatings for high temperature applications P. V. Ananthapadmanabhan, K. P. Sreekumar, K. V. Muraleedharan and N. Venkatramani (Bombay, India) Electron-beam deposition of zirconia films stabilized in high temperature phases by different oxides S. B. Qadri, E. F. Skelton, C. Kim, M. Z. Harford and P. Lubitz (Washington, DC, U.S.A.) Corrosion resistant coatings Thin metallic films for corrosion control W. B. Nowak (Boston, MA, U.S.A.) Corrosion characteristics of several thermal spray cermet-coating/alloy systems A. A. Ashary and R. C. Tucker, Jr. (Indianapolis, IN, U.S.A.) Niobium coatings on 316L stainless steel for improving corrosion resistance J. H. Hsieh, R. Lee, R. A. Erck, G. R. Fenske (Argonne, IL, U.S.A.), Y. Y. Su, M. Marek and R. F. Hochman (Atlanta, GA, U.S.A.) Adhesion and corrosion behavior of Al-Zn and TiN/Ti/TiN coatings on a DU-0.75wt.%Ti alloy F. C. Chang, M. Levy, R. Huie, M. Kane, P. Buckley (Watertown, MA, U.S.A.), T. Z. Kattamis (Storrs, CT, U.S.A.) and G. R. Lakshminarayan (Arsenal, NJ, U.S.A.) Ceramic coating for valve seats and stems by plasma chemical vapor deposition T. Yoshioka, H. Ukegawa, H. Kawai, N. Fujita and T. Igarashi (Itami, Japan) Silicon coatings on copper by chemical vapor deposition in fluidized bed reactors........... 600 e eee cence eee eee eee A. Sanjurjo, B. J. Wood, K. H. Lau, G. T. Tong, D. K. Choi, M. C. H. McKubre, H. K. Song (Menlo Park, CA, U.S.A.) D. Peters and N. Church (New York, NY, U.S.A.) Titanium-based coatings on copper by chemical vapor deposition in fluidized bed reactors A. Sanjurjo, B. J. Wood, K. H. Lau, G. T. Tong, D. K. Choi, M. C. H. McKubre, H. K. Song (Menlo Park, CA, U.S.A.) and N. Church (New York, NY, U.S.A.) Titanium-based coatings on steel: dip coating and plasma spray J. Chen, G. Craig, E. Farley and A. Sanjurjo (Menlo Park, CA, U.S.A.) HARD COATINGS AND DEPOSITION TECHNOLOGIES PVD technology I: Plasma and magnetic field characterization MoGeling mnencic felis of marnctron sputtering SySIOMS. «<2 oes oss lene so eee weea e e stb elena ble seei eie wes gvegs bowen e tees M. S. Wong, W. D. Sproul and S. L. Rohde (Evanston, IL, U.S.A.) Investigation of partial reactions during magnetron sputtering of TiN coatings by in situ Auger electron spectroscopy analysis and SonesN asT EMR AMEN ecto cra cere tho ccara u guia Sueipia'y seo Sinise la. SAUg IE Me» Meri: ete een Lorp M ears ieee nian favs igS ceretacR oer ear eects N. Eguchi, V. Grajewski, H. H. Uchida and E. Fromm (Stuttgart, F.R.G.) The practical use and application of Monte-Carlo studies in physical vapour deposition technology R. Elsing (Aachen, F.R.G.) PVD technology II: Alternative methods Structural and magnetic properties of Al/Fe multilayers deposited by ion beam sputtering S. B. Qadri, C. Kim, M. Twigg, M. Z. Harford and P. Lubitz (Washington, DC, U.S.A.) Structural, elastic and transport properties of Ag/Al multilayer thin films prepared by ion-beam sputtering C. Kim, S. B. Qadri, T. M. Tritt, A. C. Ehrlich, S. M. Hues, R. L. Jacobsen (Washington, DC, U.S.A.), S. Kumar and M. Grimsditch (Argonne, IL, U.S.A.) Titanium nitride coatings obtained using new apparatus for ion beam assisted deposition M. Bonelli, L. Calliari, M. F! 72, M. A. Ghabashy, L. A. Guzman, A. Miotello (Trento, Italy) and P. M. Ossi (Milano, Italy) Reactive co-sputtering of oxids id nitrides using a C-Mag'™ rotatable cylindrical cathode A. Belkind, W. Gerristead, Z. Orban (Murray Hill, NJ, U.S.A.), D. Dow, J. Felts and R. Laird (Concord, CA, U.S.A.) A new concept for physical vapor deposition coating combining the methods of arc evaporation and unbalanced-magnetron sputtering W.-D. Miinz, F. J. M. Hauzer, D. Schulze and B. Buil (Venlo, The Netherlands) Adherent metallization of plastic composites D. Mann, J. Fessmann, G. Kampschulte (Stuttgart, F.R.G.) and M. Hopkins (Boulder, CO, U.S.A.) CVD I: Silicon carbide and silicon nitride Investigation of interfaces of chemically vapour deposited SiC, SiC-Ti(N,C) multilayer coatings on WC-—Co based cermets G. Giunta, M. Fiorini, V. Vittori (Rome, Italy) and G. Marchesano (Siano, Italy) PVD properties I: Micro and nano structure On picostructural models of physica!ly vapor-deposited films of titanium nitride V. Valvoda (Prague, Czechoslovakia), A. J. Perry (Boulder, CO, U.S.A.), L. Hultman (Linképing, Sweden), J. Musil and S. Kadlec (Prague, Czechoslovakia) A study of the picostructure of sputtered ZrN films A. J. Perry (Boulder, CO, U.S.A.), J. P. Schaffer (Easton, PA, U.S.A.), J. Brunner (Zurich, Switzerland) and W. D. Sproul (Evanston, IL, U.S.A.) Deposition of and annealing effect on Ti(C,N) coatings M. Tamura and H. Kubo (Kanagawa, Japan) Thermal relief of stresses in sputtered refractory metals and compounds B. Window, M. V. Swain and G. L. Harding (Sydney, N.S.W., Australia) A study of TiN coatings on a low alloy high speed steel P. Ding, Z. Ni, S. Zhou and F. Pan (Chongqing, China) CVD II: Deposition methods Thermodynamic analysis and deposition of refractory materials C. Bernard and R. Madar (St. Martin d’Héres, France) Chemical vapor deposition of fine-grained equiaxed tungsten films D. W. Woodruff and J. M. Redwing (Schenectady, NY, U.S.A.) Laser-assisted chemical vapor deposition of hard and refractory binary compounds M. Boman and J.-O. Carlsson (Uppsala, Sweden) Coating particles by chemical vapor deposition in fluidized bed reactors B. J. Wood, A. Sanjurjo, G. T. Tong and S. E. Swider (Menlo Park, CA, U. S.A.) Applications and trends in plasma-enhanced organometallic chemical vapour deposition H. Suhr (Tubingen, F.R.G.) PVD technology III: Cathodic arc methods Deposition of TiN, TiC, and TiO, films by filtered arc evaporation P. J. Martin, R. P. Netterfield, T. J. Kinder (Sydney, N.S.W., Australia) and L. Descétes (Paris, France) Fundamental studies of the steered arc technique M. Ives, J. S. Brooks, J. Cawley (Sheffield, U. K.) and W. Burgmer (Bergisch Gladbach, F.R.G.) A study of the macroparticle distribution in cathodic-arc-evaporated TiN films A. W. Baouchi and A. J. Perry (Boulder, CO, U.S.A.) Improved control of TiN coating properties using cathodic arc evaporation with a pulsed bias W. Olbrich, J. Fessmann, G. Kampschulte (Stuttgart, F.R.G.) and J. Ebberink (Sigmaringen-Laiz, F.R.G.) Ceramic cathodes for arc-physical vapour deposition: development and application O. Knotek, F. Loffler, M. BOhmer, R. Breidenbach and C. St6Bel (Aachen, F.R.G.) CVD III: Titanium carbide and titanium nitride New developments in chemically vapour-deposited coatings from an industrial point of view E. Kibel (Miinsingen, F.R.G.) Design and chemical vapor deposition of graded TiN/TiC coatings S. Eroglu and B. Gallois (Hoboken, NJ, U.S.A.) TiN film formation by plasma chemical vapor deposition and its plasma diagnostics Y. Ishii, H. Ohtsu, T. Adachi, H. Ichimura and K. Kobayashi (Tokyo, Japan) PVD technology IV: Sputter deposition Multi-cathode unbalanced magnetron sputtering systems W. D. Sproul (Evanston, IL, U.S.A.) Low pressure magnetron sputtering using ionized, sputtered species W. Posadowski (Wroclaw, Poland) High rate reactive sputtering of MoN,, coatings P. J. Rudnik, M. E. Graham and W. D. Sproul (Evanston, IL, U.S.A.) Deposition of thick films of oxygen-free high conductivity copper by unbalanced d.c. magnetron sputtering: self-biased and biased conditions D. Monaghan and R. D. Arnell (Salford, U.K.) Preparation of ultrafine Cu and SnO, particles by d.c. magnetron sputtering T.-G. Suh, D. M. Umarjee, S. Prakash, H. J. Doerr, C. V. Deshpandey and R. F. Bunshah (Los Angeles, CA, U.S.A.) Morphology and thickness distribution of sputtered W-C-—Co films deposited on differently shaped substrates A. Cavaleiro and M. T. Vieira (Coimbra, Portugal) PVD technology V: Applied technology Physically vapor deposited coatings on tools: performance and wear phenomena W. Konig, R. Fritsch and D. Kammermeier (Aachen, F.R.G.) Arc-deposited Ti-Zr—N coatings on cemented carbides for use in interrupted cutting O. Knotek, F. Loffler and G. Kramer (Aachen, F.R.G.) Novel low teniperature hard coatings: for latge pate c's oscar caidsin sete ce alecioa Se He Ses oe 8 Se ese ddine Nee cet els belawee D. Hofmann, S. BeiBwenger and A. Feuerstein (Hanau, F.R.G.) PVD properties IIT: Micromechanical and corrosion Effect of contamination reactions on the composition and mechanical properties of magnetron sputtered TiN coatings S. Berg, N. Eguchi, V. Grajewski, S. W. Kim and E. Fromm (Stuttgart, F.R.G.) Mechanical properties of TiN films deposited by changed-pressure r.f. sputtering Y. Kubo and M. Hashimoto (Kawasaki, Japan) Selective steam oxidation of titanium and aluminium in TiN and (Ti,Al)N physically vapour-deposited coatings on dental surgical C. W. Louw, I. LeR. Strydom, K. van den Heever and M. J. van Staden (Pretoria, South Africa) Identification of factors affecting the aqueous corrosion properties of (Ti,Al)N-coated steel J. Aromaa, H. Ronkainen, A. Mahiout and S.-P. Hannula (Espoo, Finland) DIAMOND AND RELATED MATERIALS Industrial applications of diamond and related materials Mechanical applications of thin and thick diamond films M. Murakawa and S. Takeuchi (Saitama, Japan) Effects of surface treatment on the diamond deposition and performance of ceramic cutting tools... C. L. Chang and M. P. Guidoboni (Northboro, MA, U.S.A.) Amorphous carbon physically vapour Geposited coatings... 6 cc. cise conte ote e ca wln ccs eee eeerur rs avsenn esters ccepe ns bas O. Knotek, F. Loffler, J. Brand (Aachen, F.R.G.) and W. Burgmer (Bergisch-Gladbach, F.R.G.) Synthesis and characterization of diamond and related materials Fabrication of diamond films under high density helium plasma formed by electron cyclotron resonance M. Yuasa (Nara, Japan), H. Kawarada (Tokyo, Japan), J. Wei, J. S. Ma (Osaka, Japan), J. Suzuki, S. Okada (Kyoto, Japan) and A. Hiraki (Osaka, Japan) Real time monitoring of filament-assisted chemically vapor deposited diamond by spectroscopic ellipsometry Y. Cong, I. An, H. V. Nguyen, K. Vedam, R. Messier and R. W. Collins (University Park, PA, U.S.A.) Plasma enhanced chemical vapor deposition modeling E. Hyman, K. Tsang, I. Lottati, A. Drobot (McLean, VA, U.S.A.), B. Lane, R. Post and H. Sawin (Woburn, MA, U.S.A.) Raman observation of diamond phase carbon films prepared by ionized deposition E. Heidarpour and Y. Namba (Tokyo, Japan) Effect of temperature on the deposition rate and properties of hydrogenated amorphous carbon films ....................000005- P. Wood, T. Wydeven (Sunnyvale, CA, U.S.A.) and O. Tsuji (Kyoto, Japan) Synthesis and applications of cubic boron nitride Tribological properties of cubic, amorphous and hexagonal boron nitride films S. Watanabe, S. Miyake and M. Murakawa (Saitama, Japan) Magnetron sputter deposition of boron and boron carbide M. A. McKernan (Livermore, CA, U.S.A.) Plasma deposition of cubic boron nitride films from non-toxic material at low temperatures M. Z. Karim, D. C. Cameron, M. J. Murphy and M. S. J. Hashmi (Dublin, Ireland) Preparation of cubic boron nitride films by plasma-enhanced chemical vapour deposition of BF;, N, and H, gas mixtures J. M. Mendez, S. Muhl (Mexico, Mexico), M. Farias, G. Soto and L. Cota-Araiza (Baja California, Mexico) TRIBOLOGICAL COATINGS/SURFACE MODIFICATIONS Reduction of friction through coatings |surface modifications Interpretation of friction and wear of ceramics in terms of surface analysis J. M. Martin and Th. le Mogne (Ecully, France) Relationship of hertzian contact pressure to friction behavior of self-lubricating boric acid films A. Erdemir, R. A. Erck (Argonne, IL, U.S.A.) and J. Robles (Davis, CA, U.S.A.) Ion implantation effects in pulsed laser deposited tungsten carbide films B. G. Wagh, V. P. Godbole and S. B. Ogale (Pune, India) Forces, surface finish and friction characteristics in surface engineered single- and multiple-point cutting edges M. Sarwar, D. Gillibrand and S. R. Bradbury (Sheffield, U.K.) Wear resistance of ceramic metallic-, and composite coatings Abrasion resistance of various thin film coatings on thick film resistor materials H.-J. Krokoszinski (Heidelberg, F.R.G.) Mechanical properties and wear resistance of ion-beam-assisted sputter-deposited NiT(N) coatings K. Bouslykhane, P. Moine, J. P. Villain and J. Grilhé (Poitiers, France) Adhesion improvements in silicon carbide deposited by plasma enhanced chemical vapour deposition V. A. Mernagh, T. C. Kelly, M. Ahern, A. D. Kennedy (Dublin, Ireland), A. P. M. Adriaansen, P. P. J. Ramaekers (Eindhoven, The Netherlands), L. McDonnell (Cork, Ireland) and R. Koekoek (Hoogeveen, The Netherlands) Evaluation of some titanium-based ceramic coatings on high speed steel cutting tools H. Ronkainen, I. Nieminen, K. Holmberg (Espoo, Finland), A. Leyland, A. Matthews (Hull, U.K.), B. Matthes and E. Broszeit (Darmstadt, F.R.G.) Coating resistance to erosion, corrosion, and severe environments A thermochemical model for analyzing low wear-rate materials I. L. Singer (Washington, DC, U.S.A.) Erosion protection of carbon-epoxy composites by plasma-sprayed coatings F. Alonso, I. Fagoaga and P. Oregui (San Sebastian, Spain) Corrosion performance of some titanium-based hard coatings B. Matthes, E. Broszeit (Darmstadt, F.R.G.), J. Aromaa, H. Ronkainen, S.-P. Hannula (Espoo, Finland), A. Leyland and A. Matthews (Hull, U.K.) Effect of the surface roughness of substrates on the corrosion properties of films coated by physical vapour deposition J. Munemasa and T. Kumakiri (Hyogo, Japan) Noble metal implantation to reduce hydrogen embrittlement in steels P. Buckley, B. Placzankis, L. Lowder (Watertown, MA, U.S.A.), I. G. Brown (Berkeley, CA, U.S.A.) and R. Brown (Watertown, MA, U.S.A.) Analysis and micromechanical testing of tribological coatings Modelling the contact response of coated systems P. M. Ramsey, H. W. Chandler and T. F. Page (Newcastle-upon-Tyne, U.K.) Ultramicrohardness and microstructure of Ti-6wt.’%Al—4wt."V alloy nitrided by ion implantation V. C. Nath, D. K. Sood and R. R. Manory (Melbourne, Vic., Australia) Mechanical stability and adhesion of ceramic coatings deposited on steels M. Ignat (St. Martin d’Héres, France), A. Armann, L. Moberg (Stockholm, Sweden) and F. Sibieude (Font-Romeu, France) Thermal instability of the microstructure and surface mechanical properties of hydrogenated amorphous carbon films J. C. Knight, T. F. Page and H. W. Chandler (Newcastle-upon-Tyne, U. K.) Tribological properties of diamond, diamond-like and c-BN coatings Tribological behavior of diamond-like carbon: effects of preparation conditions and annealing A. Grill, V. Patel and B. Meyerson (Yorktown Heights, NY, U.S.A.) The effects of oxygen and humidity on friction and wear of diamond-like carbon films D. S. Kim, T. E. Fischer and B. Gallois (Hoboken, NJ, U.S.A.) Microstructure and wear behavior of metal-containing diamond-like coatings H. Dimigen and C.-P. Klages (Hamburg, F.R.G.) Deposition of hydrogenated B-—C thin films and their mechanical and chemical characterization J. I. Ofiate, A. Garcia, V. Bellido and J. L. Viviente (San Sebastian, Spain) Friction and wear properties of diamonds and diamond ccatings I. P. Hayward (Fort Washington, MD, U.S.A.) Author Index Subject Index