View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by TopSCHOLAR Western Kentucky University TopSCHOLAR® Masters Theses & Specialist Projects Graduate School 5-2014 Removal of Arsenic Using Iron Coated Limestone Anitha Swarna Western Kentucky University, [email protected] Follow this and additional works at:http://digitalcommons.wku.edu/theses Part of theEnvironmental Chemistry Commons, and theInorganic Chemistry Commons Recommended Citation Swarna, Anitha, "Removal of Arsenic Using Iron Coated Limestone" (2014).Masters Theses & Specialist Projects.Paper 1342. http://digitalcommons.wku.edu/theses/1342 This Thesis is brought to you for free and open access by TopSCHOLAR®. It has been accepted for inclusion in Masters Theses & Specialist Projects by an authorized administrator of TopSCHOLAR®. For more information, please contact [email protected]. REMOVAL OF ARSENIC USING IRON COATED LIMESTONE A Thesis Presented to The Faculty of Department of Chemistry Western Kentucky University Bowling Green, Kentucky In partial Fulfillment Of the Requirements for the Degree Master of Science By Anitha Swarna May 2014 I dedicate my thesis to my almighty Sri Shiridi Sai Baba and my family for their encouragement and support during my challenging times. Also, I dedicate this thesis to my research advisor Dr. Cathleen Webb for her guidance and support. Acknowledgements The success and final outcome of this thesis happened because of many people and I am fortunate to have them all along the completion of project. I would like to express my deepest gratitude to my research advisor and associate professor Dr. Cathleen Webb, for her incredible support and advice. Without her guidance and persistent help this thesis would not have been possible. I owe my thanks to my academic adviser Dr. Dakshinamurthy Rajalingam for his help and suggestions throughout the course. I would like to express my sincere gratitude to Ms. Olivia Williams at WATER's Lab who helped a lot with Graphite furnace atomic adsorption spectrometer (GFAA's) and for her constant help and support. I owe my thanks to Ms. Alicia McDaniel for her patience and providing chemicals and materials on time. Thanks to Dr. John Andersland for helping me with SEM images. I acknowledge the faculty members and staff of the Department of Chemistry for their assistance and support. I thank Ms. Haley Smith and Ms. Phyllis Townsend for their support and patience. I owe my special thanks to my almighty Sri Shiridi Sai Baba and to my parents Srinivasarao and Vani for their unconditional love, motivation and dedication. Thanks for your blessings and encouragement. I thank my research group and my friends for their help and support throughout the journey. I thank the Department of chemistry for providing me sufficient funds which are valuable for my research. iv TABLE OF CONTENTS List of Figures.....................................................................................................................vi List of Tables......................................................................................................................ix Abstract...............................................................................................................................xi Introduction..........................................................................................................................1 Materials and Methods.......................................................................................................13 Instrumentation..................................................................................................................21 Results and Discussions.....................................................................................................30 Conclusions........................................................................................................................59 Perspective.........................................................................................................................61 References..........................................................................................................................62 v LIST OF FIGURES Figure 1: Arsenate Speciation Diagram...............................................................................4 Figure 2: Arsenite Speciation Diagram................................................................................5 Figure 3: A comparative graph between the concentration of Arsenic, Iron and Phosphate (ppm) in Ground water of Bangladesh and Vietnam...........................................................8 Figure 4: Photograph of community based arsenic removal unit and reactions at different sections of the unit...............................................................................................................9 Figure 5: Photograph of different iron coated limestone...................................................11 Figure 6: Graphite Furnace Atomic Adsorption Spectrometer..........................................23 Figure 7: Inductively Coupled Plasma - Emission Spectrometer......................................28 Figure 8: Calibration graph for Atomic Adsorption Spectrometer....................................31 Figure 9: Batch experiment with different sample amounts of WKU iron coated limestone............................................................................................................................33 Figure 10: Batch experiment with different sample amounts of 100% DOW™ iron coated limestone............................................................................................................................35 Figure 11: Batch experiment with different sample amounts of 75% DOW™ iron coated limestone............................................................................................................................37 vi Figure 12: Batch experiment with different sample amounts of 50% DOW™ iron coated limestone............................................................................................................................38 Figure 13: Batch experiment for 1 gram iron coated limestone samples..........................40 Figure 14: Batch experiment for 5 gram iron coated limestone samples..........................41 Figure 15: Kinetic studies with 1 gram of uncoated limestone..........................................43 Figure 16: Kinetic studies with 1 gram WKU iron coated limestone................................44 Figure 17: Kinetic studies with 1 gram DOW™ iron coated limestone............................45 Figure 18: Kinetic studies with 1 gram 75% DOW™ iron coated limestone...................46 Figure 19: Kinetic studies with 1 gram 50% DOW™ iron coated limestone...................47 Figure 20: Calibration graph for Inductively Coupled Plasma- Emission Spectrometer......................................................................................................................49 Figure 21: Acid leaching test with different iron coated limestone...................................50 Figure 22: Acid digestion test for different iron coated limestone....................................51 Figure 23: SEM images for 100% DOW™ iron coated limestone...................................52 Figure 24: Analysis report for location 1 of Scanning Electron Microscope (SEM) image for 100% DOW™ iron coated limestone...........................................................................53 Figure 25: SEM images for 75% DOW™ iron coated limestone.....................................54 vii Figure 26: Analysis report for location 2 of SEM images for 75% DOW™ iron coated limestone............................................................................................................................54 Figure 27: SEM images for 50% DOW™ iron coated limestone.....................................56 Figure 28: Analysis report for location 2 of SEM image for 50% DOW™ iron coated limestone............................................................................................................................56 Figure 29: SEM results for WKU iron coated limestone...................................................57 Figure 30: Analysis report for SEM image for WKU iron coated limestone....................58 viii