D ow nloaded from https://onlinelibrary.w iley.com /doi/ by ibrahim ragab - C RechargeableIonBatteries ochrane Germ any , W iley O nline L ibrary on [23/11/2022]. See the T erm s and C onditions (https://onlinelibrary.w iley.com /term s-and-conditions) on W iley O nline L ibrary for rules of use; O A articles are governed by the applicable C reative C om m ons L icense D ow nloaded from https://onlinelibrary.w iley.com /doi/ by ibrahim ragab - C Rechargeable Ion Batteries ochrane G erm any , W MBEdeaiyttoeednridablys,KDaetesriignna,Ea.nAdifAapnptilsi,cRa.tiVoanssanotfKLui-mIoanr,CaenldlsPaunHdu iley Online Library on [23/11/2022]. See the T erm s and C onditions (https://onlinelibrary.w iley.com /term s-and-conditions) on W iley O nline L ibrary for rules of use; O A articles are governed by the applicable C reative C om m ons L icense D ow nloaded from https://onlinelibrary.w iley.com /doi/ by ibrahim Editors pArloldbuocoekds.pNuebvleisrhtheedlebsys,WaIuLtEhYo-VrsC,Hedairteorcsa,raenfudlly ragab - C PDreopf.aKratmtereinntaoEf.MAifeacnhtaisnical&Aerospace pcounbtlaisihneerddinotnhoetsweabroroaknst,tihnecliundfoinrmgtahtiiosnbook, ochrane G Engineering tobefreeoferrors.Readersareadvisedtokeep erm U1F0lno6ir4videCraesinttyeorfDFrliovreida,Gainesville ipinnraomdcevindedrutretahnlatdltyestbtaaeitleisnmoarecncouttshr,aedtreai.ttae,milslumstaryations, any , Wiley O UnitedStates nline L PMU2CU7rBnnoaC3fiit.vtehe0RerdaFir.asrVSKlliasetCiyssnSaaoBcgnmifdateCobbKnmbrauciammedgga+beerrRMidogeatedallurgy LBAfrirobictmraiastrhatyhlLooeigfbBuCrareoirntyrigesCcrheaotsLrasdilbCofragoarurrdiytnhN.gio-si.:nba-oPpoupkblilieiscdaatvfioaorinlaDbaleta ibrary on [23/11/2022]. See the T erm PWSEN4C3crnhoouh0g.if2h2on.i0n0Poaa65nuel,eoWHIGrfnuiuMnusthgaianattungetgreiuaol1fSsTcteireconhacndeoslo&gy BtTtNd<hhaihhabeitsettlaiDtipoopDaengu:reu/reab/utalldsaptbicsncvhihcababiehctli.iildeNoioan-nbNganfrltoabeiiarnot.fimodinoteneaahn;>ltetbdaiho.ileDbbnetlieaiIpbouinulltteitbhsoedlcetrihhksnbheeiebektldailoitbsgytrsaphic s and Conditions (https://onlinelibrary.w Cover:©Black_Kira/Shutterstock ©694260923WWeiInLhEeYim-V,CGHerGmmanbyH,Boschstraße12, iley.com /term Attpmmrhhaleailonsacrtshnbiolgoisapnhotr–ietkiosnnlnmratoienirnasnggetyturr,oabvamneoegsditercmherw(epioinrtirfittoclehlaldmdounuudog,ctiuorenwradtgrgaraietinnnhtsyts)oae.losnnaNetythpeoofedeofprrrimanmrtitos–osaifboyn s-and-conditions) on Wiley O fromthepublishers.Registerednames, nline L tncProroaintndstseipmIdSeeBacriNrefikd:cs9a,u7lenl8typ-c3r.mo-u5tas2erec7kdt-ee3iddn50abt1shy8sil-sua6bcwho.,oakr,eevneonttwohbeen ibrary for rules of use; O eeoTyPPBpuDoeboFskIeISStIBStBiBNnNNg::9:9797S878t-8-r33-a-3-5i5-v252e727,-7-C88-383h636e766n179n-0-0a7-i3,India A articles are governed by the applicable C reative C om m ons L icense D ow nloaded from https://onlinelibrary.w iley.com KthaetierrnineaveAreinfadnintigswsuopuplodrlti,kaentdoFder.dSicyamteeothnisKbraooyikotpoohuelorsp,awrheontws,aMsaasrkiain&ghEelirawshfoern /doi/ by ibrahim shewouldbeginthesecondbookeversincethefirstonegotpublished. ragab - C RPu.VHausawnotuKludmliakerwtooduelddilciakteettohdisebdoicoaktetothhiissbwoiofekPtoinGgialln,Vdihjaisy,dKaauigloh,tearnTdoAnng.astasia. ochrane Germ any , W iley O nline L ibrary on [23/11/2022]. See the T erm s and C onditions (https://onlinelibrary.w iley.com /term s-and-conditions) on W iley O nline L ibrary for rules of use; O A articles are governed by the applicable C reative C om m ons L icense D ow nloaded from vii https://onlinelibrary.w iley.com /doi/ by ibrahim ragab - C Contents ochrane Germ any , W iley O Preface xv nline L 1111...122.1 WQIRVn.outhVlrataoaantsdgtaauientrcietetiKsB4ouCanmthtteaoarrriEaaelcsnet?dcetrTrizo1hicanhpgeamBnaeicettaeSlraCireeaslklosn4sr1i ibrary on [23/11/2022]. See the T erm 1111111.......2222222.......2222222......531246 EEERTOEhxlllateeehatecccemetttTrrrropaooifLcflddRaeeieem:llesPDEKaiAtlcqioiotnnwuuiteotgabaitntnyliFiecogafsrLncao8(taPomTyorea9slErfaerqliu1zC82ialutiibrovrneiuafmonrdaC9CeollpIpmerpEedleacntcroe)de810 s and Conditions (https://onlinelibrary.w 1.2.2.7 TafelCurvesforaBattery 13 iley.com 1.2.3 Capacity 14 /term 1111....2222....7645 SEDSphniseeecclrfhigfiLaycrifDgEeeennCe1suri5gtryyveD/Ce1n6yscilteyLif1e6 15 s-and-conditions) on W 1.2.8 PowerDensity(Whg−1) 17 iley O 1.2.9 ServiceLife/TemperatureDependence 18 nline L 11..43 CRPreoifnmecraleurnysciaeonsndsS2e01c9ondaryBatteries 18 ibrary for rules of use; O A 222222.....12333..12 TTITTPTnhrhhhhitameeeerpoLGEZaaderianaunycresccllseByat/nianCSoBetcanartahrertCabétrkeieo2Ceorln1ilsneesClslre2i2l5a1l22n35d2R5.VasantKumar articles are governed by the applicable C reative C om m ons L icense D ow nloaded from viii 22Co..33n..t33en.1ts ECluercrternocthZeinmci/cCaalrRbeoanctCioenlls 2278 https://onlinelibrary.w 22..33..34.2 CDoismadpvoannetnatgses 2930 iley.com 22..44.1 EAllekcatlrioncehBeamttiecraileRsea3c0tions 31 /doi/ by ibrahim 22..44..23 CDoismadpvoannetnatgses 3334 ragab - C 22..55.1 MBuetrtcounrByaOttxeirdieesBat3te4ry 34 ochrane Germ 2.5.1.1 ElectrochemicalReactions 35 any , W 2.5.2 Zn/Ag2OBattery 36 iley O 2222222.......5655656......322313...211 ALEMLLZiiinlltteeuP/hhtcAmariituuirlimi–ormmnAcBauh//iramSTreytuhmBt/BeliAaforiauctyinttarrteyelDBrlrRi3iaCeie8oetshstaxelcirodt3iir4eeo7i1sdCneseBl4l0sa3t7te4r3ies 42 nline Library on [23/11/2022]. See the T erm 2223...798 OCRABDaeoaxRtfnmyeetrcervailerdiugieneeeswcsiBieonosanftP4stMe9r4iram6i4et6esarriya4Bls3aattnedriCeshem44istryforSecondary s and Conditions (https://onlinelibrary.w R.VasantKumarandThapaneeSarakonsri iley.com 3.1 TheLead–AcidBattery(LAB) 51 /term 3333....2111...312 NETChloeeemwctNprCooioccnkmheeenplm–tosCnicaeadn5lmt4Rsieuam5c6tiBoantstery52 58 s-and-conditions) on W 3.2.1 ElectrochemicalReactions 60 iley O 3.3 Nickel–MetalHydride(Ni–MH)Batteries 61 nline L 3333....5544..11 LSCSeeiotccmhooinnpuddomaan-rreIyynoLAntsilBtkhaai6tlut2ienmreieBBsaatttte6er3riieess 6622 ibrary for rules of use; O A 3333333.......7577556.....31224 LRRDLEBiivaeeet–atcchtPtalyyeiuoiccurlalllysmyiitnnomiM/oggnAneaaortironhrfkBfdLeBeaLetaRStaittaeetdBfecr7e–aryi1teAitcyetslcesiIirnsdysg6u6BM7P8earastotteceerr7iise2asslsofa7Ln3edaCdh–AemciidstBryatte6r9ies 75 articles are governed by the applicable C reative C om m ons L icense D ow nloaded from 3.8 CReofnecrleunscieosns 8080 Contents ix https://onlinelibrary.w 4 ApplicationsofLithiumBatteries 83 iley.com 444...123 PHAHoaeyrorbtokarsuibdpnlaeaDcnEeedlnAegEcptlarpeonlcindtcriaKicctaiDoVteneervshiniicacel9seE4s.A8if38a6ntis /doi/ by ibrahim ragab - C 44..44.1 MHeeadritcaPlaAcepmplaikcaertisons97 97 ochrane G erm 44..45.2 NGreiudroElnoegrigcaylSPtaocraegmeake9r9s 98 any , W 4.6 Conclusions 101 iley O Acknowledgments 101 nline L 555..11.1 LRPCLuaaieCtyfHheeorourOee,dn2dLeciMneMt1saaa0tot5ee1rDr0iioaa2ullss,Tfao1or0LH5iuthainugm,a-nIodnABisahtuteirYieus 105 ibrary on [23/11/2022]. See the Term 5.1.2 Nickel-RichMaterials 107 s and C 5555555.......3331342....3132 FLELPCMSpoaiMxoMecilcnnyctSecPoaheislOnrOlasusinM4Ms4otiioOnOsoaamntIrnl(eimtPsgvrhhiaipoanno1rsl1es2soei2lp0svCi3ehcer1aaOyEt1tseelx6te,iaCcdSltreiSryloitLscrctauaahytcleeetSmsrute)rridFeucarcCaaltnaumPdtreheerIowfnaodtonreerdmrkMcIaaCnanlttaaceetterrhiociooaanfdllsaLMetMiMeo1cXna1hOt3ae4nriiaslm1s21111290 onditions (https://onlinelibrary.wiley.com/term 6 RKNaeetfxeetrr-ieGnnaecnEee.srAaitf1iao2nn3tisA,nUotdkaersshfoArhSuejcao,nYdanarhyonLgi-IWonanBga,tatnedrieHsong12L7i s-and-conditions) on W 6.1 Introduction 127 iley O 6.2 MechanicalInstabilitiesDuringElectrochemicalCycling 130 nline L 6666....3444..12 SSNSnnna---nBBBoaaassssteeerddducCAMtuolalrnoteevydresirAaslins1oo3nd61Re3se3ac1ti3o3nMaterials 134 ibrary for rules of use; O A 6666666.......4455555......341342 SSSSSSSnniiiii-/--M–-FBNCBCiaailaNscmnNseraeoodsandwpnAMoaNiocrnraceoatotoinmAecdmolrepneifispaooBblosdseaiset1risest/4eesN1d7s4aaP15nn5od1o3r4woo0utihrseeErAlSenicotNrdoaednseosc1o4n13fi5g5urations 155 articles are governed by the applicable C reative C om m ons L icense D ow nloaded from x 66Co..55n..t56ents SBii/nPdoelrysme1r6N2anocomposites 159 https://onlinelibrary.w 66..56.7 SOit–hSeiOrA2–nCodCeoMmaptoesriitaelss 116635 iley.com 66..66..21 SMbX-BeanseeEdlAecntoroddeess 116676 /doi/ by ibrahim 66..66..34 ABil--BBaasseeddAAnnooddeess 117609 ragab - C 66..66..56 LMiTetiaOl-OBxaisdeed-BAansoeddeAsno1d7e2s 172 ochrane Germ 6.7 Solid-StateBatteries 173 any , W 6.8 Conclusions 173 iley O 77.1 IRAELCnillectaetfhkruceointdrurdeoiomounwlcycClBteteaieasdopstngitgfme1olri7raey14nL8Pti7esthrfiou1rm7m4Banactteearineds:STahfeetQyue1s8t7forImproving nline Library on [23/11/2022]. See the T erm 77777777........22222222.......3441442...231 LLSTLSNCoaiiihuotttllehhhrntvsriiieaSeuuufnqonommmtultrsiedCNTHPfo-oeeoEuoertrlnxslrlcNeeaaahEccflfloqltltonruueuoorcaoeoraltqorryCrtoouueotoebasle(ryrooLIErstnruoeiealCtesssnteicelaEorOtft(nrla1e4Leoc8)cl(ie8yBtL1rt(Fioe91AS4sl09Ey)s4tFIe)61s1)9931418199914 s and Conditions (https://onlinelibrary.wiley.com 7.2.4.4 LithiumHexafluorophosphate(LiPF6) 195 /term 777...222...444...657 LLLLiiiitttThhhFiiiuuuSImmm):BTBrii1ssifl((9tp5ureioflrrfluouomoreorotmheaethnthyealssnuuellfsfoounnlfayotlen)iy(mLl)iiid(mCeiFd(L3eSi[(ONL3iC)[)N(C(C1FF953SSOO2))2]]oorr s-and-conditions) on W LiBETI) 196 2 5 2 2 iley O 777...222...444...9810 LLLLLiiiiitttTFhhhAFiiiuuuSPMmmm) )TTF1rrl9uii1ss7o9((rpt6roeiaflrlflukuyoolrboroomreaethttehyal()Lntrie[isBfluFulfo3o(rCnoypClhF)mo3sCepFthh2ai)dt]eeo(r(LLLii[i[PFCFA(3CB(FC)3FS31OC92F7)23)]3o]ror nline Library for rules of use; OA 777777......222222......555544.....1231112 RPRALL(Loiieedttildahh[dyNcuiiimtuutc(iimmoCtveirnev4isNBFezAfa9(AoodoSbnrdxdOlaeaNdi2fltliA)ioatuv(itndCveoodaserF)qisbof3tuoboiSvreruOe1aoGts29tyue)r9lfs]aso(upoELrlhrliGfe[oiLBtcrneiat(F-yrCpboBlh2talMrOyisittefle4eSd-)usIb2)oA]a:rsonLo1eroi9mdFLd8BeAeiBtMnhOyoS1BldI9s:e)u9lf1o119n998y89limide articles are governed by the applicable C reative C om m ons L icense D ow nloaded from 77..22..55..45 ASubrsfoarcpetiMonodAifidedritAivdedsiftoivreGsrfaoprhGitrea-pbhaisteed-bAasneoddAeno2d0e2 202 Contents xi https://onlinelibrary.w 77..22..55..67 PLriPoFtecAtivdediAtidvdeistitvoeSstfaobrilCizaethSoadlteDe2c0o2mposition 203 iley.com 77..22..55..89 SShhuutttd6loewAnddAidtidvietsives203203 /doi/ by ibrahim 77..22..55..1101 FAidred-iRtievteasrtdoaRntedAudcdeitLivitehsium20P3lating 204 ragab - C 77..22..55..1123 AAddddiittiivveesstfoorInHcirnedaesreinthgeATlruamnsinpuormtNCuumrrbenertCo2l0le4ctorCorrosion 204 ochrane Germ 7.2.5.14 AdditivestoImprovetheWettingofSeparator 204 any , W 7.3 GelPolymerElectrolytes 205 iley O 7777777.......3344455.....12121 GGFSSSTeooiheercllellsiioddtPPAn---ooGPSddlltoeyy-vaGnlmmatyeenemeerntBrraaeeatgEErriteoalltEeetenailccroenttSicnrredoootslrStllioyyhodlttel-2yeeiS1dtQBwte0-asuSaitttseehaerBt2dyIe1aofo2BtontnraeicrtCttihLeeoersipqiNeousle2iydw1m02Pe12ro00lPy9VmDeFri–cHMFaPteri2a0ls6for nline Library on [23/11/2022]. See the T erm 777777......666656.....12222..12 SNNNPSPooooAAAlllliiyySSSddmmIII-CCCESeetOOOlrraeNNNctCEetlo---reTTTEomcyyylltyepppprctoeeeoetlsrsLLLyiottiiileetttyhhhs2Etiii1euuul9eImmm2cs1strEEEu4oelllleeesyccctttterrrs2ooo2lllyyy0ttt2eee1sss7ffoo2rr2LL1iitthhiiuumm–AAqiureBoauttseries 221 s and Conditions (https://onlinelibrary.w Batteries 222 iley.com 7.6.3 GlassElectrolytes 222 /term 7777....6687..45 GLCSoGolalnPisdcSs-l–SuFCtsaaeimotrenaimBlsyaitct2se22rE26y4leCcotrmolpyatenies223225 s-and-conditions) on W Acknowledgment 227 iley O References 227 nline L 88.1 IDRn.etVvraeosldoaunpctmtiKoeunnmttsaorinLainLthditihuKiamuim–XS–iuSlufulfruBraBtatettreiersies232131 ibrary for rules of use; O A 8888888.......2345555...312 CESPCPGuoolaaretrlarrfecobbputnuoohrrtosnneiUacCnNMhlteaiSealariomnbtzleo2oauirct4nttiuia3iaoobllnsneP2sar4int3n2o2d4c4H2iC6puylercsdleleLs2i3fe4240237 articles are governed by the applicable C reative C om m ons L icense D ow nloaded from xii 88Co..67ntents MPoelytamleOrxside2s50247 https://onlinelibrary.w 88..89 FKueyrthPaerraDmeevteelrospfmoreAntpspalnicdatIinonnoPvraotisvpeecAtsppr2o5a6ches 252 iley.com 88..99..12 FRuednocxtioCnoanlvizeerdsioCnatChaotdaelyMstaster2ia5l8s 257 /doi/ by ibrahim 88..99..34 LMitohdiiufimedMSeeptaalrAatnoorsde262260 ragab - C 8.10 CReofnecrleunscieosns 262464 ochrane Germ 9 Sodium-IonBatteries 269 any , W PuHuandKaterinaE.Aifantis iley O 9.1 Introduction 269 nline L 99999.....22222....1112..12 OPTCPo2ra3altPynhPahshoniadatisiseooeennMCCi-cMaaattCtehehortooiamdadllepeOsoMMfxuoiardnatteNdeesrsraiia-aIl2lo2ss7n726B22a77t43teries 271 ibrary on [23/11/2022]. See the T 9.2.3 PrussianBlueCompounds 279 erm 9.3 AnodeMaterialsforNa-IonBatteries 283 s and C 99999.....33333.....22212...231 VUHCAoalnullrosgubtyemaoibVnnel-ogeBElAuSaxmEsnpeIoaedndEAes2isxno9pno0ad2nCe8sa6iMuosnaetCseraIinuacslsreesaAs2ec8t3tihveeIMmapteedriaanlcFerac2tu8r7e 287 onditions (https://onlinelibrary.w 99..44.1 EElleeccttrroollyytteesCfoomrNpao-nIeonntsBat2te9r0ies 290 iley.com 9999....4455...231 EESIntstadhtteueurrs-s-tBBroaiafassIleeindzddaOutOisrortgngraaianonlfiiiczcSaEIEBtlilesoecncttrro2oof9lly4SytIteBes229921194 /terms-and-conditions) on W 9.5.2 ChallengesoftheIndustrializationofSodium-IonBatteries 296 iley O 91.06 CRAEMleocoefkncdentcerrleolouinwndscigeleoessnIdogsnm22I99en297n9set7srtio2n97forPredictingNext-Generation nline Library for rules of use; O A 111111000000......331322...111.1 MAAITBInnohcnoticetraWdioolaReyaudllotnuniMinlgcctegia,tonioFldtogfeMheniMfelooiSnDerdhg2ceuLi9ffhlaoii9a-unnfInsgogDii,nocoaasnmfDn-iDdIniaffnIgKBSdueasaustUitUecotserenniidrnndiaeSgest3rEFr0.eEr4Asa3lsaci0ftsia0untnirctSeiDisMnegefloecrhPmaanarittciiocslnes303103404 articles are governed by the applicable C reative C om m ons L icense