2 He I 10 Ne I 18 Ar I 36 Kr I 54 Xe I 86 Rn I H/31 ~ 2 5 6 7 8 I I H 9 F 17 Cl 35 Br 53 I 85 At 8 0 3 16 s 9 34 Se 10 52 Te II 84 Po 12 71 Lu 03 Lr 71 1 4 16 17 18 19 71 7 N 15 p 33 As 51 Sb 83 Bi 70 Yb 102 No 6 c 14 14 Si 15 32 Ge45 50 Sn 46 82 Pb 47 69 Tm 101 Md 71 mbers I 5 B 13 13 Al35 31 Ga 36 49 ln 37 81 Tl 38 68 Er 100 Fm 71 Nu 32 33 34 71 melin System I I ' I I . I ! I 29 30 so 57 Cu Zn 47 48 65 Ag 61 Cd 79 80 68 Au 62 Hg 66 67 Dy Ho 98 99 1 Cf 71 Es e G 28 Ni 46 Pd 78 Pt 65 Tb 97 Bk7 thwith 27 Co 58 45 Rh64 77 Ir 67 64 Gd 96 cm71 Table of Elements the I I ! I I ' I ! I 24 25 26 Cr 52 Mn 56 Fe 59 42 43 44 Mo 53 Tc 69 Ru 63 74 75 76 w 54 Os 66 Re 70 61 62 63 Pm Sm Eu 93 94 95 Np 71 Pu 71 Am71 Periodic . l i I I I . i I ' I ! i I i i ' i I 22 23 21 V 48 Sc 39 Ti 41 40 41 39 y 39 Zr 42 Nb49 72 73 57** La 39 Hf 43 Ta 50 104 105 89*** 71 71 Ac 40 60 59 58 Nd Pr Ca 91 92 i~ u 55 44 Pa 51 4 Be 26 12 Mg 27 20 Ca 28 38 Sr 29 56 Ba 30 88 Ra 31 ides n 39 des 2 20 21 * 22 24 25 ntha ctini I H 3 LI II Na 19 K 37 Rb 55 Cs 87 Fr *La **A ~ * ' := "" .:: ö :;. "' C'l 3 !!. :;· "' -< ~ 3 ;;;· .. "" :;:· " 0 " :;. "' ~ ~ "" 01 ,... n n 0 < !!1 Gmelin Handbook of lnorganic Chemistry 8th Edition Gmelin Handbook of lnorganic Chemistry 8th Edition Gmelin Handbuch der Anorganischen Chemie Achte, völlig neu bearbeitete Auflage Prepared Gmelin-lnstitut für Anorganische Chemie and issued by der Max-Planck-Gesellschaft zur Förderung der Wissenschaften Director: Ekkehard Fluck Founded by Leopold Gmelin 8th Edition 8th Edition begun under the auspices of the Deutsche Chemische Gesellschaft by R. J. Meyer Continued by E. H. E. Pietsch and A. Kotowski, and by Margot Becke-Goehring Springer-Verlag Berlin Heidelberg GmbH 1989 Gmelin-lnstitut für Anorganische Chemie der Max-Planck-Gesellschaft zur Förderung der Wissenschaften ADVISORY BOARD Dr. G. Breit, Chairman (Ruhrchemie AG, Oberhausen-Holten), Prof. Dr. K. Dehnicke (Philipps Universität, Marburg), Prof. Dr. N. N. Greenwood (University of Leeds), Prof. Dr. H. Grünewald (Bayer AG, Leverkusen), Prof. Dr. H. Harnisch (Hoechst AG, Frankfurt/Main-Höchst), Prof. Dr. H. Nöth (Universität München), Prof. Dr. H. Ottermanns (Degussa AG, Frankfurt/Main), Prof. Dr. G. zu Putlitz (Universität Heidelberg), Prof. Dr. A. Rabenau (Max-Planck-lnstitut für Fest körperforschung, Stuttgart), Prof. Dr. A. Sirnon (Max-Planck-lnstitut für Festkörperforschung, Stuttgart), Prof. Dr. Dr. A. H. Staab (Präsident der Max-Planck-Gesellschaft, München), Prof. Dr. Dr. h.c. mult. G. Wilke (Max-Planck-lnstitut für Kohlenforschung, Mülheim/Ruhr) DIRECTOR DEPUTY DIRECTOR Prof. Dr. Dr. h.c. Ekkehard Fluck Dr. W. Lippert CHIEF EDITORS Dr. K.-C. Buschbeck - Dr. H. Bergmann, J. Füssel, H. Hartwig, Dr. H. Katscher, Dr. R. Keim, Dr. E. Koch, Dipl.-Phys. D. Koschel, Dr. U. Krüerke, Dr. P. Merlet, Dr. E. Schleitzer-Rust, Dr. F. Schröder, Dr. A. Slawisch, Dr. W. Töpper CORRESPONDENT MEMBERS OF THE SCIENTIFIC STAFF Dr. B. Baker, Dr. P. L. Bayless, Dr. V. Haase, Dr. E. F. Hockings, Dipl.-lng. G. Kirschstein, Dr. W. F. McNamara, Dr. K. Rumpf EMERITUS MEMBER OF THE INSTITUTE Prof. Dr. Dr. E.h. Margot Becke CORRESPONDENT MEMBERS OF THE INSTITUTE Prof. Dr. Hans Bock Prof. Dr. Dr. Alois Haas, Sc. D. (Cantab.) STAFF GMELIN HANDBOCK Dr. G. Bär, D. Barthel, Dr. N. Baumann, Dr. B. Becker, Dr. W. Behrendt, D. Benzaid, Dr. L. Berg, Dipl.-Chem. E. Best, Dr. R. Bohrer, K. D. Bonn, P. Born-Heck, Dipl.-Phys. R. Bost, Dr. R. Braun, Dipl.-lng. V. A. Chavizon, E. Cloos, Dipl.-Phys. G. Czack, I. Deim, Dipl.-Chem. H. Demmer, U. Dietz, Dipl.-Geol. R. Ditz, R. Dowideit, Dipl.-Chem. M. Drößmar, U. Duggen, Dipl. Chem. R. Durban, M. Engels, Dr. H.-J. Fachmann, Dr. J. Faust, B. Fischer, G. Funk, Dipl.-lng. N. Gagel, Dr. D. Germeshausen, Dr. U. W. Gerwarth, Dipl.-Phys. D. Gras, Dipl.-Bibl. W. Grieser, Dr. I. Haas, Dr. R. Haubold, B. Heibel, Dipl.-Min. H. Hein, A. Heise-Schuster, H.-P. Hente, H. W. Herold, U. Hettwer, Dr. R. Heumüller, Dr. G. Hönes, Dr. W. Hoffmann, Dr. W. Huisl, B. Jaeger, R. Jonuschat, Dr. R. Jotter, Dr. J. von Jouanne, Dr. B. Kalbskopf, Dipl.-Chem. W. Karl, H.-G. Karrenberg, Dipl.-Phys. H. Keller-Rudek, B. Kirchner, P. Klauck, A. Klusch, Dipl.-Chem. C. Koeppel, Dipl.-Chem. H. Köttelwesch, R. Kolb, E. Kranz, Dipl.-Chem. I. Kreuzbichler, Dr. A. Kubny, Dr. M. Kunz, Dr. W. Kurtz, M. Langer, Dr. U. Lanzendörfer, Dr. B. Ledüc, Dr. A. Leonard, H. Mathis, E. Meinhard, C. Metz, K. Meyer, Dr. M. Mirbach, Dipl.-Chem. B. Mohsin, Dr. U. Neu Becker, K. Nöring, Dipl.-Chem. R. Nohl, Dipl.-Min. U. Nohl, Dr. U. Ohms-Bredemann, Dr. W. Petz, I. Rangnow, Dr. B. Rempter, Dipl.-Phys. H.-J. Richter-Ditten, Dipl.-Chem. H. Rieger, E. Rieth, A. Rosenberger, E. Rudolph, G. Rudolph, Dipl.-Chem. S. Ruprecht, Dr. B. Sarbas, Dr. H. Schäfer, Dr. D. Schiöberg, V. Schlicht, Dipl.-Chem. D. Schneider, Dipl.-Min. P. Schubert, Dr. K. Schücke, A. Schwärzet, Dr. B. Schwager, Dipl.-lng. H. M. Somer, G. Strauss, Dr. G. Swoboda, Dr. U. Taubald, M. Teichmann, Dr. D. Tille, Dipl.-lng. H. Vanecek, Dipl.-Chem. P. Velic, Dipl. lng. U. Vetter, H.-M. Wagner, Dipl.-Phys. J. Wagner, R. Wagner, Dr. E. Warkentin, Dr. C. Weber, Dr. A. Wietelmann, Dr. M. Winter, Dr. B. Wöbke, K. Wolff STAFF GMELIN ON LI NE DATA SYSTEM Dr. R. Deplanque, Dr. P. Kuhn, Dr. G. Olbrich Organometallic Compounds in the Gmelin Handbook The following listing indicates in which volumes these compounds are discussed or are referred to: Ag Silber B 5 (1975) Au Organagold Garnpounds (1980) Be Organaberyllium Garnpounds 1 (1987) Bi Bismut-Organische Verbindungen (1977) Co Kobalt-Organische Verbindungen 1 (1973), 2 (1973), Kobalt Erg.-Bd. A (1961), B 1 (1963), B 2 (1964) Cr Chrom-Organische Verbindungen (1971) Cu Organacopper Garnpounds 1 (1985), 2 (1983), 3 (1986), 4 (1987), Index (1987) Fe Eisen-Organische Verbindungen A 1 (1974), A 2 (1977), A 3 (1978), A 4 (1980), A 5 (1981), A6 (1977), A 7 (1980), AB (1985), B 1 (partly in English; 1976), Organairan Garnpounds B 2 (1978), Eisen-Organische Verbindungen B 3 (partly in English; 1979), B 4 (1978), B 5 (1978), Organairan Garnpounds B 6 (1981), B 7 (1981), B 8 to B 10 (1985), B 11 (1983), B 12 (1984), B 13 (1988), B 14 (1989), B 15 (1989), Eisen-Organische Verbindungen C 1 (1979), C 2 (1979), Organairan Garnpounds C 3 (1980), C 4 (1981), C5 (1981), C7 (1985), and Eisen B (1929-1932) Ga Organagallium Garnpounds 1 (1986) Ge Organagermanium Garnpounds 1 (1988), 2 (1989) Hf Organahafnium Garnpounds (1973) Nb Niob B 4 (1973) Ni Nickel-Organische Verbindungen 1 (1975), 2 (1974), Register (1975), Nickel B 3 (1966), and C 1 (1968), C 2 (1969) Np, Pu Transurane C (partly in English; 1972) Pb Organalead Garnpounds 1 (1987) Pt Platin C (1939) and D (1957) Re Organarhenium 1 (1989) present volume Ru Ruthenium Erg.-Bd. (1970) Sb Organoantimony Garnpounds 1 (1981), 2 (1981), 3 (1982), 4 (1986) Sc, Y, D 6 (1983) La to Lu Sn Zinn-Organische Verbindungen 1 (1975), 2 (1975), 3 (1976), 4 (1976), 5 (1978), 6 (1979), Organatin Garnpounds 7 (1980), 8 (1981), 9 (1982), 10 (1983), 11 (1984), 12 (1985), 13 (1986), 14 (1987), 15 (1988), 16 (1988) Ta Tantal B 2 (1971) Ti Titan-Organische Verbindungen 1 (1977), 2 (1980), Organotitanium Garnpounds 3 (1984), 4 and Register (1984) u Uranium Suppt. Vol. E 2 (1980) V Vanadium-Organische Verbindungen (1971), Vanadium B (1967) Zr Organozirconium Garnpounds (1973) Gmelin Handbook of lnorganic Chemistry 8th Edition Re Organarhenium Compounds Part 1 With 89 illustrations AUTHOR Manfred Winter FORMULA INDEX Edgar Rudolph EDITOR Adolf Slawisch CHIEF EDITOR Adolf Slawisch Springer-Verlag Berlin Heidelberg GmbH 1989 L1TERATURE CLOSING DATE: 1987 Library 01 Congress CataLog Card Number: Agr 25-1383 ISBN 978-3-662-08846-3 ISBN 978-3-662-08844-9 (eBook) DOI 10.1007/978-3-662-08844-9 This work is subject to copyright. AU rights are reserved, whether the whoLe or pari 01 the materiaL is concerned, specilicaUy those 01 transLation, reprinting, reuse 01 iLLustrations, broadcasting, reproduction by photocopying machine or similar means, and storage in data banks. Under §54 01 the German Copyright Law where copies are made lor other than private use, alee is payabLe to "VerwertungsgeseUschaft Wort", Munich. © by Springer-VerLag Berlin HeideLberg 1988 Originally published by Springer-Verlag, Berlin· HeideLberg . New York· London . Paris· Tokyo in 1988 Softcover reprin! of !he hardcover 8th ed~ion 1988 The use 01 registered names, trademarks, etc., in this pubLication does not impLy, even in the absence 01 a specilic statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Preface The present volume is the first of a series of volumes dealing with organorhenium com pounds. lt covers the Literature completely up to the end of 1987. An empirical formula index and a Ligand formula index provide ready access to the compounds covered. ln accordance with the previous arrangement adopted for organemetallic compounds (cf. volumes covering organocobalt, organonickel, or organotitanium compounds), this volume starts with the mononuclear organorhenium compounds. lt contains compounds in which the organic Ligand is bonded to the Re atom by one C atom CL Ligand) and up to four CO groups. Other mononuclear compounds will be covered in the next volume of this series. A formula like (C0)2Re(2D)s 1L beloenog s to a type of mononuclear rhenium compounds containing three monodentate ligands two-electron donor) such as P(CH3)s and one Ligand bonded by one C atom CL) such as C5H7 (trans-pentadienyl) or C(O)R with R = CH3. Much of the data, particularly in tables, is given in abbreviated form without dimensions; for explanation see p. X. Additional remarks, if necessary, are given in the headings of tl'le tables. Frankfurt am Main Adolf Slawisch November 1988 X Remarks on Abbreviation& and Dimensions Many compounds in this volume are presented in tables in which numerous abbreviations are used, the dimensions are omitted for the sake of conciseness. This necessitates the following clarification. Abbreviations used with temperatures are m.p. for melting point, dec. for decomposition, and b.p. for boiling point. NMR represents nuclear magnetic resonance. Chemical shifts are given as 8 values in ppm and to low field from the following reference substances: Si(CH3)4 for 1H and 13C, BF3 · O(C2H5h for 118, CFCl3 for 19F, H3P04 for 31P, and Sn(CH3)4 for 119Sn. Otherwise, the reference substances and signs are given. Multiplicities of the signals are abbreviated as s, d, t, q, qui, sext, sept (singlet to septet), m (multiplet), and br (broad); terms like d of d (doublet of doublet) arealso used. Assignments referring to labeled structural formulas are given in the form C-4, H-3,5. Coupling constants J in Hz usually appear in parentheses after the 8 value, along with the multiplicity and the assignment, and refer to the respective nucleus. lf a more precise designation is necessary, they are given as, e.g., "J(C,H) or J(H-1 ,3) referring to Labeted formulas. ESR represents electron spin resonance; the hyperfine interactions are given as a(Re) or a(P). Optical spectra are labeled as IR (infrared) and UV (electronic spectrum including the visible region). IR bands and Raman absorptions are given in cm-1. The assigned bands are usually labeled with the symbols v for stretching, 8 for deformation, and Q for rocking vibration with the indexes sym and asym for symmetrical and asymmetrical. The stretching force and interaction constants are denoted k1, k2, and k;, respectively. The UV absorption maxima, "-max• are given in nm followed by the extinction coefficient E (in L · cm-1 · mol-1) or log E in parentheses. Solvents or the physical state of the sample and the temperature (none is given if room temperature applies) are given in parentheses immediately after the spectral symbol, e.g., IR (solid), 1H NMR (C6D6, 50°C}, or at the end of the data if their formula (C6H6 = benzene) or name (acetone-d6) except THF, which represents tetrahydrofuran. Molecular weights are given in the entire volume in g/mol; the abbreviation calc. is used for calculated.