MAURÍCIO SARAIVA PACHECO E SILVA THE ANAEROBIC DIGESTION OF THE ORGANIC PORTION OF HOUSEHOLD WASTE: STUDY CASE DRESDEN Projeto de Formatura apresentado à Escola Politécnica da Universidade de São Paulo, no âmbito do Curso de Engenharia Ambiental São Paulo 2018 MAURÍCIO SARAIVA PACHECO E SILVA THE ANAEROBIC DIGESTION OF THE ORGANIC PORTION OF HOUSEHOLD WASTE: STUDY CASE DRESDEN Projeto de Formatura apresentado à Escola Politécnica da Universidade de São Paulo, no âmbito do Curso de Engenharia Ambiental Orientadora: Prof. Dr. Cristtina Dormack São Paulo 2018 Catalogação-‐na-‐publicação Silva, Maurício THE ANAEROBIC DIGESTION OF THE ORGANIC PORTION OF HOUSEHOLD WASTE: STUDY CASE DRESDEN / M. Silva -- São Paulo, 2017. 94 p. Trabalho de Formatura - Escola Politécnica da Universidade de São Paulo. Departamento de Engenharia de Hidráulica e Ambiental. 1.Waste management 2.Anaerobic digestion 3.Biogas 4.Renewable energy 5.Organic waste I.Universidade de São Paulo. Escola Politécnica. Departamento de Engenharia de Hidráulica e Ambiental II.t. ABSTRACT This work focuses on biogas production by using source-separated organic waste from households as feedstock. The energy use of the produced gas should contribute to the transformation of Dresden into a more sustainable city. Dresden still has an energy matrix that is highly dependent on fossil fuels and musst seek cleaner energy production in order to meet the national targets for renewable energy production defined in recent years. The current work covers, among other things, a bit of the actual treatment, that has been given in Dresden for its domestic waste, the legal background concerning waste management and energy production in Germany, the state-of-the-art of anaerobic digestion in Europe and in Germany, a description of the biological process that occur during the anaerobic digestion of the residue and still, financial aspects of the technology. DEDICATION Dedico este trabalho à minha irmã Laís, meu maior exemplo de luta e de superação! Te amo muito! ACKNOWLEDGEMENTS Agradeço a meu pai e à minha mãe, por toda sua dedicação e por todo seu sacrifício. Vocês são pessoas incríveis! Ich bedanke mich bei denen, Freunden aus Deutschland, die mich während meines Aufenthalts an diesem wundervollen Land irgendwie unterstützt haben! Die letzten Monate waren für mich nicht einfach und ohne deren Unterstützung wäre diese Arbeit nicht möglich. Besonders will ich mich bei der “Gesellschaft von Freunden und Förderern der TU Dresden e. V.” bedanken für die finanzielle Unterstüzung und für das Vertrauen in meine Arbeit. TABLE OF CONTENTS 1 INTRODUCTION ......................................................................................................................... 1 1.1 Purpose .............................................................................................................................................. 1 1.2 Background ...................................................................................................................................... 1 2 OBJECTIVES ................................................................................................................................ 3 3 METHODS .................................................................................................................................... 4 4 OVERVIEW OF THE WASTE MANAGEMENT IN DRESDEN ............................................ 5 4.1 Demographic and geographical data of Dresden ................................................................ 5 4.2 Waste management summary ................................................................................................... 7 4.3 The waste from households and its many ways .................................................................. 8 4.3.1 Door-‐to-‐door colletion ............................................................................................................................ 8 4.3.2 In the residential areas ........................................................................................................................ 10 4.3.3 Bulky waste and domestic appliances .......................................................................................... 12 4.4 Qualitative and quantitative analysis of MSW .................................................................... 13 4.4.1 “Rest” of household waste .................................................................................................................. 15 4.4.2 The organic portion of MSW characteristics and its composition .................................... 17 4.4.3 Recyclable materials ............................................................................................................................. 19 4.5 Existing biogas plants in Dresden ........................................................................................... 21 5 BIOLOGICAL TREATMENT IN EUROPE – ANAEROBIC DIGESTION ......................... 23 5.1 Introduction ................................................................................................................................... 23 5.2 State of the art in Europe ........................................................................................................... 23 5.3 Biogas plants in Germany .......................................................................................................... 26 6 THE POTENTIALS OF RENEWABLE ENERGY ................................................................. 29 6.1 Energiewende – Promotion of renewable energy in Germany ..................................... 32 6.2 The role of public power in the German energy transition and some legal measures .................................................................................................................................................... 32 6.2.1 Renewable Energy Sources Act (Erneuerbare Energien Gesetz – EEG) ......................... 33 6.2.2 Biomass Ordinance ................................................................................................................................ 36 6.2.3 Closure of nuclear power stations .................................................................................................. 38 6.2.4 Taxation on conventional energy .................................................................................................... 39 i 7 LEGAL BACKGROUND CONCERNING WASTE MANAGEMENT AND ENVIRONMENTAL PROTECTION ............................................................................................. 41 7.1 The development of waste policy in Germany ................................................................... 41 7.2 Principles and measure of environmental policy ............................................................. 43 7.2.1 European Union law ............................................................................................................................. 43 7.2.2 German Federal Legislation .............................................................................................................. 44 8 ANAEROBIC DIGESTION – THE TECHNOLOGY AND ITS TECHNICAL ASPECTS .. 47 8.1 Introduction ................................................................................................................................... 47 8.2 Biochemical reaction .................................................................................................................. 48 8.3 Phases of degradation ................................................................................................................ 49 8.3.1 Hydolysis ................................................................................................................................................... 50 8.3.2 Acidogenesis ............................................................................................................................................. 51 8.3.3 Acetogenesis ............................................................................................................................................. 51 8.3.4 Methanogenesis ...................................................................................................................................... 53 8.4 Substrate requirements ............................................................................................................. 54 8.5 Pre-‐treatment ................................................................................................................................ 54 8.6 Process parameters ..................................................................................................................... 55 8.7 Variations of biogas techniques .............................................................................................. 57 8.7.1 Dry and wet fermentation .................................................................................................................. 58 8.7.2 Single and multi-‐stage systems ........................................................................................................ 59 8.7.3 Mesophilic and thermophilic processes ....................................................................................... 59 9 COMPOST .................................................................................................................................. 61 9.1 Use of the compost produced in the digestion process ................................................... 61 9.2 Processing of the compost ......................................................................................................... 63 9.3 Marketing opportunities and application of compost ..................................................... 63 9.4 Conditioning of solid residues and its use as soil amendment ..................................... 64 10 PROPOSAL OF CHANGES IN THE WASTE MANAGEMENT IN DRESDEN .............. 67 10.1 Anaerobic digestion of the organic waste ......................................................................... 68 10.2 Improvement of waste source separation ........................................................................ 70 10.2.1 Public participation and information dissemination ........................................................... 70 10.3 Anaerobic digestion – choice of the most appropriate technology .......................... 72 ii 11 ENERGY YIELD AND PAY BACK OF THE INVESTMENT ............................................ 74 11.1 Energy generation ..................................................................................................................... 78 11.1.1 Estimation of energy generation .................................................................................................. 79 11.1.2 Share of renewable energy in Dresden and the joining in from anaerobic digestion of the organic waste ............................................................................................................................................. 81 11.2 Financial analysis of the plant ............................................................................................... 83 11.2.1 Costs .......................................................................................................................................................... 83 11.2.2 Revenues ................................................................................................................................................. 85 12 CONCLUSION ......................................................................................................................... 89 REFERENCE...........................................................................................................................87 iii LIST OF FIGURES Figure 1: Map of Germany. .............................................................................................................................. 5 Figure 2: Map of Dresden and its districts. .............................................................................................. 6 Figure 3: Waste ways – from households till specific facilities. ...................................................... 8 Figure 4: Recycling center in Kaditz (Dresden). .................................................................................... 9 Figure 5: Waste ways – from residential areas till specific facilities. ........................................ 11 Figure 6: Containers in residential area in Dresden. ........................................................................ 12 Figure 7: Waste ways – bulky waste and domestic appliances. .................................................. 13 Figure 8: Composition of the household waste in 2016. ................................................................ 15 Figure 9: Composition of the “Restmüll” (“Rest waste”) from household in 2016. ............ 17 Figure 10: “Bio-‐Abfall” (Organic waste) bin in Dresden. ................................................................ 18 Figure 11: Composition of valuable material. ..................................................................................... 20 Figure 12: Biogas plants in Dresden. ....................................................................................................... 21 Figure 13: Biogas plant in Klotzsche, Dresden. ................................................................................... 22 Figure 14: Total and average installed capacity per country. ...................................................... 24 Figure 15: Installed capacity per million inhabitants and per country. ................................... 25 Figure 16: Development of the capacity per million inhabitants per country. ..................... 26 Figure 17: Development of biogas installations and its electrical capacity in Germany. . 27 Figure 18: Avoided GHG emissions through the use of renewable sources of energy. ..... 30 Figure 19: Gross electricity generation in Germany in 2016. ....................................................... 34 Figure 20: Development of electricity supply from biomass plants in Germany from 1990 to 2011. ................................................................................................................................................................. 37 Figure 21: Development of biomass use for heat production in Germany in the years 1997 to 2011. ..................................................................................................................................................... 37 Figure 22: “The Smiling Sun”. ..................................................................................................................... 39 Figure 23: Waste hierarchy. ........................................................................................................................ 42 Figure 24: General layout of an AD. ......................................................................................................... 48 Figure 25: Anaerobic decomposition. ..................................................................................................... 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