Zero Ammunition Co.,Inc. PO Box 1188 Cullman, AL 35056 1-800-545-9376 Enclosed you will find a Material Safety Data Sheet (''MSDS'') prepared by Zero to assist its customers in recognizing the potential health or safety hazards, if any, associated with commercial use ofa product. MSDSs include information on the maximum and recommended average exposure levels of chemicals in workplace air. MSDSs also recommend appropriate safety guidelines dealing with accidental product leaks or spills in the workplace and outline workplace handling procedures for products. While MSDSs have proved invaluable in the hands ofhealth and safety professionals as a tool for hazardevaluation ofproducts in the confmes ofthe workplace, cautionmust be exercised against direct extrapolation ofMSDS hazard health data to the community environment, outside of the perimeter of the workplace, or use by the general public. For such purposes, safety, health, and environmental professionals should be consulted to interpret MSDS data for each specific situation. In case of an emergency, contact 1-800­ 255-3924. This MSDS is intended for your use in meeting your requirements under OSHA's Hazard Communication Standard (29 CFR 1910.1200) and Sara Title Ill. Enclosed to further assist you in interpreting the MSDS is a supplement outlining the sections ofthe MSDS and a glossary of common terms. If you have any questions, please contact me at 1-800­ 545-9376 for assistance during working hours. We appreciate the opportunity to be of service to you. Sincerely, Alison Harbison Material Safety Data Sheet Control MSDS Enclosed: Product Name: Centerfire Pistol Loaded Round 1 Zero Ammunition Co.,Inc. PO Box 1188 Cullman, AL 35056 1-800-545-9376 MATERIAL SAFETY DATA This Material Safety Data Sheet (MSDS) has been prepared in compliance with the federal OSHA Hazard communication standard, 29 CFR 1910.1200. This product may be considered to be a hazardous chemical under that standard. (Refer to the OSHA classification in Sec. I.) This information is required to be disclosed for safety in the workplace. The exposure to the community, if any, is quite different. I. Product Identification ProductNarne: Centerf1rePistol Loaded Round Synonyms: Super-X Centerfire PistollRevolver: 25 Automatic (6.35mm) Expanding point and Full metal case; 30 Luger (7.65mm) Full metal case; 30 Carbine Hollow Soft Point and Full metal case; 32 Smith & Wesson Lead Round Nose and Long Lead Round Nose; 32 Short and Long Colt Lead Round Nose; 32 Automatic Silvertip Hollow Point and Full metal case; 38 Smith & Wesson Lead Round Nose, 380 Automatic Silvertip Hollow Point and Full metal case; 38 Special Silvertip Hollow point, Lead round nose, Lead Semi-wadcutter, lead wadcutter, metal point, silvertip hollow point+p, Jacketed hollow point+p, lead hollow point+p, lead semi-wadcutter +p, match lead mid-range match; 9mm Luger(parabellum): Full metal jacket encapsulated, full metal case, silvertip hollow point; 38 Super Automatic Silvertip hollow point+p, full metal case+p; 357 Magnum jacketed hollow point, Silvertip hollow point, Lead Semi-wadcutter, Jacketed soft point; 10mm Automatic silvertip hollow point; 41 Remington Magnum Silvertip hollow point, hollow soft point, Lead Semi-Wadcutter(med. Vel. & gas check); 45 automatic silvertip hollow point +p, Full metal case, Super-Match Full metal case Semi­ Wadcutter; 45 Colt Silvertip hollow point, lead round nose; 45 Winchester magnum: Jacketed soft point, Full metal case; Black Talon; 40 Smith and Wesson: silvertip hollow point, full metal jacket truncated cone, Full metal jacket encapsulated, jacketed hollow point, Full metal jacket, Supreme 357 Magnum 180 gr. Partition Bullet, Supreme 44 Magnum 250 gr. Partition Bullet; Ranger Talon, 40 Cal. 180 gr. JHP ; Ranger Talon, 45 Auto, 230 gr JHP; Ranger Talon, 9mm, 147 gr JHP Chemical Family: Mixture Formula: Not ApplicablelMixture Use Description: Loaded round OSHA Hazard classification: Explosive 2 Zero Ammunition Co.,Inc. PO Box 1188 Cullman, Al 35056 1-800-545-9376 II. Component Data Product Composition Consists ofthe following four components: Component Percent Product Product Code # a) Projectile 30-70% Centerfire Bullets DPE.000022 b) Shell Case 30-60% Brass 2XXX Series BPE.020000 c) Propellant 5-10% Smokeless Powder DPE.090000 d) Centerfrre Primer 1-4% Centerfrre Primer DPE.020000 Additional information may be obtained from Zero by requesting the MSDS for any component ofinterest and quoting the relevant product code number. All percent compositions specified below are based on the entire product. A) Projectile CAS or Chemical name: Lead CAS Number: 7439-92-1 Percentage Range: 30-70% Hazardous per 29 CPR 1910.1200: Yes (as dust or fume) Exposure Standards: See 29 CPR 1910.1025 OSHA(pEL) ACGIH(TLV) ppm mg/cubic-meter ppm mg/cubic-meter TWA: 10 5 Ceiling: None None Ste1: None None 3 Zero Ammunition Co.,Inc. PO Box 1188 Cullman, AL 35056 1-800-545-9376 CAS or Chemical Narne: Copper CAS Number: 7440-50-8 Percentage Ra:nge: 0-25% Hazardous per 29 CFR 1910.1200: Yes (as dust or fume) Exposure Standards: As copper dust OSHA(pEL) ACGIH(fLV) ppm mg/cubic-meter ppm mg/cubic-meter TWA: 1 1 Ceiling: None None Stel: None None CAS or Chemical Name: Zinc CAS Number: 7440-66-6 Percentage Range: 0-6% Hazardous per 29 CFR 1910.1200: Yes (as dust or fume) Exposure Standards: As zinc oxide OSHA(PEL) ACGIH(TLV) ppm mg/cubic-meter ppm mg/cubic-meter TWA: 5(respirable) 10 10 Total Ceiling: None None Stel: None None CAS or Chemical Name: Aluminum CAS Number: 7429-90-5 Percentage Range: 0-6% Hazardous per 29 CFR 1910.1200: Yes (as dust or fume) Exposure Standards: OSHA(PEL) ACGffi(TLV) ppm mg/cubic-meter ppm mg/cubic-meter TWA: 5(respirable) 10 15 Total Ceiling: None None Stel: None None 4 Zero Ammunition Co.,Inc. PO Box 1188 Cullman, AL 35056 1-800-545-9376 CAS or Chemical Name: Antimony CAS Number: 7440-36-0 Percentage Range .2-2% Hazardous per 29 CFR 1910.1200: Yes (as dust or fume) Exposure Standards: OSHA(PEL) ACGIH(TLV) ppm mg/cubic-meter ppm mg/cubic-meter TWA: 0.5 0.5 Ceiling: None None Stel: None None B) Shellcase CAS or Chemical Name: Copper (see above) CAS Number: 7440-50-8 Percentage Range: 30-45% CAS or Chemical Name: Zinc (see above) CAS Number: 7440-66-6 Percentage Range: 10-20% C) Propellant CAS or Chemical Name: Nitrocellulose CAS Number: 9004-70-0 Percentage Range: 5-10% Hazardous per 29 CFR 1910.1200: Yes Exposure Standards: None Established CAS or Chemical Name: Nitroglycerin CAS Number: 55-63-0 Percentage Range: .5-2% Hazardous per 29 CFR 1910.1200: Yes Exposure Standards: OSHA(pEL) ACGIH(TLV) ppm mg/cubic-meter ppm mg/cubic-meter TWA: 0.1(skin) .05 (skin) Ceiling: None None Stel: None None 5 Zero Ammunition Co.,Inc. PO Box 1188 Cullman, AL 35056 1-800-545-9376 CAS or Chemical Name: Dibutyl phthalate CAS Number: 84-74-2 Percentage Range: .5-2% Exposure Standards: OSHA (PEL) ACGIH(TLV) ppm mg/cubic-meter ppm mg/cubic-meter TWA: 5 5 Ceiling: None. None Stel: None None D) Centerfue Primer CAS or Chemical Name: Copper (see above) CAS Number: 7440-50-8 Percentage Range: .5-3% CAS or Chemical Name: Zinc (see above) CAS Number: 7440-66-6 Percentage Range: .1-1% CAS or Chemical Name: Lead styphnate CAS Number: 15245-44-0 Percentage Range: .1-1% Hazardous per 29 CFR 1910.1200: Yes Exposure Standards: aslead (see 29 CFR 1910.1025) OSHA(PEL) ACGIH(TLV) ppm mg/cubic-meter ppm mg/cubic-meter TWA: 0.05 0.15 Ceiling: None None Stel: None None CAS or Chemical Name: Barium Nitrate CAS Number: 10022-31-8 Percentage Range: .I-1% Hazardous per 29 CFR 1910.1200: Yes Exposure Standards: OSHA(PEL) ACGIH(TLV) ppm mg/cubic-meter ppm mg/cubic-meter TWA: 0.5 0.5 Ceiling: None None Stel: None None 6 Zero Ammunition Co.,Inc. PO Box 1188 Cullman, AL 35056 1-800-545-9376 III. PRECAUTIONS FOR SAFE HANDLING AND STORAGE DO NOT TAKE INTERNALLY. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER. STORAGE CONDITIONS: STORE IN A COOL, DRY, WELL-VENTILATED PLACE, AWAY FROM ALL SOURCES OF IGNITION. DO NOT STORE AT TEMPERATURES ABOVE: NOT APPLICABLE DO NOT SUBJECT TO MECHANICAL SHOCK. PRODUCT STABILITY AND COMPATIBILITY SHELF LIFE LIMITATIONS: 25-30 YEARS INCOMPATIBLE MATERIALS FOR STORAGE OR TRANSPORT: ACIDS IV. PHYSICAL DATA APPEARANCE: Finished cartridge FREEZING POINT: Not Applicable BOILING POINT: Not Applicable DECOMPOSITION TENlPERATURE: Not Applicable SPECIFIC GRAVITY: Not Applicable BULK DENSITY: Not Applicable Ph @ 25 DEG.C: Not Applicable VAPOR PRESSURE @ 25 DEG.C: Not Applicable SOLUBILITY IN WATER: Not Applicable VOLATILES, PERCENT BY VOLUME: Not Applicable EVAPORATION RATE: Not Applicable VAPOR DENSITY: Not Applicable MOLECULAR WEIGHT: Not Applicable ODOR: None COEFFICIENT OF OIL/WATER DISTRIBUTION: Not Applicable V. PERSONAL PROTECTIVE EQUIPMENT REQUIREMENTS PERSONAL PROTECTION FOR ROUTINE USE OF PRODUCT: RESPIRATORY PROTECTION: Not normally required VENTILATION: None beyond normal ventilation SKIN AND EYE PROTECTIVE EQUIPMENT: Use safety glasses EQUIPMENT SPECIFICATIONS (WHEN APPLICABLE): RESPIRATOR TYPE: Not normally required PROTECTIVE CLOTHING TYPE (This includes: gloves, boots, apron, protective suit): Not normally required. 7 Zero Ammunition Co.,Inc. PO Box 1188 Cullman, AL 350561-800-545-9376 VI. FIRE AND EXPLOSION HAZARD INFORMATION FLAMMABILITY DATA: EXPLOSIVE: Yes FLAMMABLE: Not Applicable COMBUSTIBLE: Not Applicable PYROPHORIC: No FLASH POINT: Not Applicable AUTOIGNITION TEMPERATURE: No Data FLAMMABLE LIMITS AT NORMAL ATMOSPHERIC TEMPERATURE AND PRESSURE (PERCENT VOLUME IN AIR): LEL - Not Applicable UEL - Not Applicable NFPA RATINGS: Not Established HMIS RATINGS: Health: o Flammability 2 Reactivity 4 EXTINGUISHING MEDIA: Water spray Other: Do not fight fire; if fire reaches cargo, flood with water from unmanned hoses. FIRE FIGHTING TECHNIQUES AND COMMENTS: See section XI for protective equipment for fire fighting. Evacuate all persons including emergency personnel from the area for 1500 feet (1/2 mile) in all directions, iffire reaches cargo. vn. REACTIVITY INFORMATION CONDITIONS UNDER WHICH THIS PRODUCT MAY BE UNSTABLE: TEMPERATURES ABOVE: No Daffi MECHANICAL SHOCK OR IMPACT: Yes - based on primer ELECTRICAL (STATIC) DISCHARGE: Yes - based on primer OTHER: CARTRIDGE MAY DETONATE IF CASE IS PUNCTURED OR SEVERLY DAMAGED HAZARDOUS POLYMERIZATION: Will not occur INCOMPATIBLE MATERIALS: Acids HAZARDOUS DECOMPOSITION PRODUCTS: Nitrogen oxides, Carbon Monoxide, Carbon Dioxide, Lead Oxides, Lead Dust/fume OTHER CONDITIONS TO AVOID: CARTRIDGES PLACED IN A HIGH RADIO FREQUENCY ENERGY FIELD (RADAR STATIONS) 8 Zero Ammunition Co.Jnc, PO Box 1188 Cullman, AL 35056 1-800-545-9376 SUMMARY OF REACTIVITY: EXPLOSIVE: Yes OXIDIZER: No PYROPHORIC: No ORGANIC PEROXIDE: No WATER REACTIVE: No VIII. FIRST AID EYES: Not a likely route of exposure. SKIN: Not a likely route ofexposure. INGESTION: Not a likely route of exposure. INHALATION: Not a likely route ofexposure. IX. TOXICOLOGY AND HEALTH INFORMATION ROUTES OF ABSORPTION The physical nature ofthis product makes absorption from any route unlikely. A small amount ofinhalable particles may be created when projectile is fired. WARNING STATEMENTS AND WARNING PROPERTIES PARTICLES FROM FIRING MAYBE HARMFUL IF INHALED. HUMAN THRESHOLD RESPONSE DATA ODOR THRESHOLD: No Available Data IRRITAION THRESHOLD: No Available Data IMMEDIATELY DANGEROUS TO LIFE OR HEALTH: The IDLH concentration has not been established. SIGNS, SYMPTOMS, AND EFFECTS OF EXPOSURE INHALATION ACUTE: Inhalation of lead dust or metal fume may cause irritation to nose, throat, upper respiratory tract and lung. The irritant effects may lead to bronchitis, headache, a fall in blood pressure, weakness, convulsions and collapse may occur. Severe poisoning may impair vision by damaging the optic nerve. The product is composed ofa solid projectile. It is judged that the physical nature ofthe product, and its use would preclude 9 Zero Ammunition Co.,Inc. PO Box 1188 Cullman, AL 35056 1-800-545-9376 inhalation ofa sufficientamount oflead and the development ofthese symptoms. CHRONIC: Chronic inhalation oflead dust or metal fume may cause damage to central and peripheral nerves, blood, kidneys and the fetus. Male reproductive function may be impaired. Damage to nerves can result in reduction in motor nerve and muscle function. Anemia may result due to interference by lead ofhemoglobin synthesis. Lead has been identified as an animal carcinogen; it may produce cancer in humans. Chronic exposure may lead to lead poisoning, known as "Plumbism", causing gingival lead line and an accumulation in body tissues. The product is composed ofa solid projectile. It isjudgedthatthe physicalnature ofthe product, and its use would preclude inhalation of a sufficient amount of lead and the development ofthese symptoms. SKIN: ACUTE: Lead can be absorbed through the skin to produce effects similar to those listed for acute inhalation exposure. CHRONIC: Lead can be absorbed through the skin to produce effects similar to those listed under chronic inhalation exposure. The product is composed ofa solid projectile. It is judged that the physical nature of the product, and its use would preclude skin absorption ofa sufficient amount oflead and the development ofthese acute and/or chronic symptoms. EYE: Lead dust and fume can irritate the eyes with conjunctival redness and discharge. It is judged that this effect would not occur because ofthe physical nature ofthe product and its use. INGESTION: ACUTE: The effects oflead ingestion would be similar to those listed under acute inhalation exposure in addition to gastrointestinal tract irritation. CHRONIC: The effects oflead ingestion would be similar to those listed under chronic inhalation exposure. The product is composed ofa solid projectile. It is judged that the physical nature ofthe product, and its use would preclude ingestion and the development ofthese acute and/or chronic symptoms. 10