Lithos78(2004)67–99 www.elsevier.com/locate/lithos Magma-mixing in the genesis of Hercynian calc-alkaline granitoids: an integrated petrographic and geochemical study of the Sa´zava intrusion, Central Bohemian Pluton, Czech Republic Vojteˇch Janousˇeka,*,1, Colin J.R. Braithwaiteb, D.R. Bowesb, Axel Gerdesc,2 aInstitutfu¨rMineralogie,Hellbrunnerstrage34,A-5020Salzburg,Austria bDivisionofEarthSciences,UniversityofGlasgow,GlasgowG128QQ,UnitedKingdom cInstituteofMineralogy,J.W.Goethe-University,Senckenberganlage28,60054Frankfurt-am-Main,Germany Received2April2003;accepted23April2004 Availableonline11September2004 Abstract The Devonian–early Carboniferous (354.1F3.5 Ma: conventional zircon U–Pb age) Sa´zava intrusion (biotite-amphibole quartz diorite, tonalite and granodiorite) of the Central Bohemian Pluton (CBP) associated with bodies of (olivine, pyroxene-) amphibole gabbro, gabbrodiorite, (quartz) diorite and rare hornblendite, gives an opportunity for a comparative study of a rather shallow, calc-alkaline magma-mixing zone at two levels, separated by a vertical difference of approximately 1 km. The deeper section (Pˇr´ıbram) displays the direct evidence for the existence of a long-lived, periodically tapped and replenished, floored magma chamber (MASLI). The contacts between the subhorizontal sheet-like basic bodies and the surrounding,commonlycumulus-rich,Sa´zavagranitoid,arearcuate,andcutbyaseriesofveinsandascendingpipes.Shallow- dippingswarmsofstronglyelongatedandflow-alignedmaficmicrogranularenclaves(MME),concordantwiththecontactsof the basic bodies,arecommonplace. The higher level (Telet´ın) section shows relatively independent basic intrusions, some of them distinctly hybrid in character and mainly of quartz dioritic composition, surrounded by relatively homogeneous, nearly cumulus-free Sa´zava tonalite rich in texturally variable MME. Larger quartz microdiorite bodies and the MME, both interpreted as hybrids, contain varying proportions of highly heterogeneous plagioclase megacrysts with complex zoning, particularly well shown by cathodoluminescence (CL). Most often the megacrysts have cores of labradorite-anorthite, partly resorbed and overgrown by andesine rims but some are strongly brecciated and fragments have been annealed by rim growth. Also characteristic are long prisms of apatite, oikocrysts of quartz and K-feldspar and zoned amphibole. The latter has brown pargasite and magnesiohastingsite cores, resorbed and overgrown by magnesiohornblende, compositionally similar * Correspondingauthor.Fax:+436628044622. E-mailaddresses: [email protected](V.Janousˇek)[email protected](C.J.R.Braithwaite)8 [email protected](D.R.Bowes)[email protected](A.Gerdes). 1 Previousaddress:CzechGeologicalSurvey,Kla´rov3,11821Prague1,CzechRepublic. 2 Previousaddress:NERCIsotopeGeosciencesLaboratory(NIGL),Keyworth,NottinghamshireNG125GG,UnitedKingdom. 0024-4937/$-seefrontmatterD2004ElsevierB.V.Allrightsreserved. doi:10.1016/j.lithos.2004.04.046 68 V.Janousˇeketal./Lithos78(2004)67–99 to the amphibole in the Sa´zava tonalite. The brown cores are probably relics of a higher P–T stage, with temperature exceeding 900 8C. Plots of major-element analyses of the Telet´ın quartz microdiorite and the MME fall close to the line joining the compositionsoftheevolvedSa´zavagranodiorite-tonaliteandtheassociatedgabbros.Theestimatedminimalproportionsofthe acidic end-member rangefrom ca. 15%to20%for the quartz microdiorite andca.40%to 60%for theenclaves. Field relationships, macroscopic and mineralogical features and whole-rock geochemistry are consistent with a hybrid origin of the quartz microdiorite masses and enclaves. Unzoned calcic plagioclase cores are interpreted as having crystallized from a basic magma prior to its injection into a high-level acidic magma chamber. The sudden decrease in Ca activity and introduction of water, due to magma-mixing with tonalitic melt, led to their resorption and brecciation. Quartz ocelli that are abundant locally in some basic bodies are most likely xenocrysts introduced from the felsic magma. In the basic melt, they were resorbed and became a substrate for heterogeneous nucleation of the amphibole or pyroxene coronas. Strong undercooling of the basic magma resulted in the growth of long prismatic apatite together with dendritic, boxy cellular plagioclase. Both types of plagioclase cores were subsequently overgrown by more sodic mantles. At the same time, small unzoned plagioclase crystals nucleated in the groundmass. Following thermal re- adjustment, crystallization of the hybrid magma ended with considerably slower growth of quartz and K-feldspar oikocrysts. D2004Elsevier B.V.All rights reserved. Keywords:BohemianMassif;Cathodoluminescencemicroscopy;Hybridization;Maficmicrogranularenclaves;Mineralchemistry;Plagioclase 1. Introduction The products of magma-mixing are commonly preservedinrapidlycooledvolcanicrocks(Anderson, For over a century, vigorous debate has been 1976; Davidson et al., 1998; Tepley et al., 1999), but centred on the role of magma-mixing in the petro- the possibilities for retention of evidence have been a genesis of large and nearly homogeneous I-type major concern in plutonic systems where near-perfect granitoid batholiths of intermediate chemistry, Na O- re-equilibration is possible. The operation of magma- 2 rich, metaluminous to weakly peraluminous rocks mixing has been suggested from a number of lines of with primitive Sr–Nd isotopic signatures. Overviews evidence: oftheissuesareprovidedinClarke(1992)andPitcher (1993).Threegeneralhypotheseshavebeenproposed (1) The coexistence of contrasting magmas may be to explain the genesis of these rocks: indicated by chilling or net veining of the basic mass, the presence of silicic pipes and disrupted (1) dehydration melting of meta-igneous crust, with late syn-plutonic dykes, or an abundance of a variable role attributed to restite unmixing mafic microgranular enclaves (MME: Didier, (Chappell et al., 1987; Chappell and Stephens, 1973; Vernon, 1984; Didier and Barbarin, 1988;ChappellandWhite,1991,1992;Atherton 1991a, b; Wiebe, 1996). and Petford, 1993; Wolf and Wyllie, 1994; (2) The initial quenching and multistage crystalliza- Johannes and Holtz, 1996; White et al., 2001); tionofthepresumedhybridsmaybereflectedin (2) differentiation of primary basic magmas (Pearce dendritic plagioclase crystals, acicular apatite et al., 1984; Whalen, 1985); and blade-like biotite, together with quartz and (3) combined models invoking mixing between K-feldspar oikocrysts enclosing numerous small mantle-derived and crustal melts (Vernon, plagioclase laths (Vernon, 1990; 1991; Hibbard, 1984; Castro et al., 1990a,b, 1991a,b; Didier 1991; 1995). andBarbarin,1991a;PoliandTommasini,1991, (3) An exchange of crystals (xenocrysts), and their 1999; Bateman, 1995; Poli et al., 1996; Wiebe, resorption and overgrowth is indicated by 1996; Wiebe and Collins, 1998; Wilcox, 1999; rapakivi and antirapakivi feldspars, plagio- Perugini et al., 2002 and others). clases with resorption surfaces and thin calcic V.Janousˇeketal./Lithos78(2004)67–99 69 overgrowths, ovoid K-feldspars mantled by et al., 1995). Plagioclase is particularly valuable biotite and/or amphibole, and quartz ocelli due to its resistance to high-temperature recrystal- with amphibole or pyroxene rims (Hibbard, lization (Cherniak and Watson, 1992) and its 1981, 1991, 1995; Barbarin, 1990; Vernon, consequent ability to record changes in the phys- 1990; 1991; Wiebe, 1991, 1996; Janousˇek et icochemical environment during growth (Hibbard, al., 2000a). 1981; Barbarin, 1990; Blundy and Shimizu, 1991; (4) Whole-rock geochemistry: linear arrays in Castro and De la Rosa, 1994; Davidson et al., binary diagrams, joining the compositions of 1998; Janousˇek et al., 2000a; Waight et al., 2000). putative end-members (Castro et al., 1990a, b, The zoning revealed by cathodoluminescence (CL) 1991a,b;Holub,1997;Gerdesetal.,2000),and is especially useful as feldspars can accommodate a correlations of radiogenic isotopic compositions number of activators that trigger contrasting lumi- with independent geochemical parameters (1/Sr, nescence colours. For plagioclase, the most impor- 1/Nd, SiO , MgO) (Faure, 1986; Albare`de, tant is Mn2+ (yellowish-green luminescence), but 2 1995; Dickin, 1995). Ti4+ (blue), Fe3+ (red) and Fe2+ (also yellowish- green) have all been implicated (Marshall, 1988). Unfortunately,mostoftheseargumentsareequivocal. Blue luminescence, that has also been attributed to Whiletheubiquitouspresenceofmaficmicrogranular structural defects (Geake et al., 1977), is typical of enclaves attests to the near contemporaneity of most alkali feldspars (Finch and Klein, 1999; Go¨tze contrastingmagmasandmaypointtotheinvolvement et al., 2000; Pagel et al., 2000). of magma-mixing in the origin of their host (Vernon, The mechanisms of magma-mixing may only be 1984; 1990; Didier and Barbarin, 1991a), in some understood where the incipient stages of the process cases the magma of the enclave could have been canbeobserved.Forthis,selectionoftheappropriate completely unrelated to the surrounding granitoid case study is of prime importance. Recent work (Roberts et al., 2000). Although it is difficult to indicates that magma-mixing was significant in the explain some unusual whole-rock geochemical varia- evolutionoftheCentralBohemianPluton(CBP),one tionsbyanymodelotherthanmagma-mixing(Holub, of the largest composite granitoid complexes in the 1997; Gerdes et al., 2000), many linear trends can be Central European Hercynides. Thiscomplex provides interpreted equally well by alternative petrogenetic a variety of superb examples of magma-mixing that scenarios(DePaolo,1981;Chappelletal.,1987;Wall potentially have wider petrogenetic implications et al., 1987; Albare`de, 1995). Radiogenic isotopes (Holub, 1997; Holub et al., 1997b; Janousˇek et al., maybesensitiveindicatorsofopen-systembehaviour, 1995, 2000a,b). but some variation can be attributed to remelting of Here, we discuss the nature, age and petrogenesis isotopicallyheterogeneous sources(Gerdes, 2001),or of the oldest and geochemically primitive calc- tocrustalcontamination(DePaolo,1981).Evenwhere alkaline Sa´zava suite (Holub, 1992; Janousˇek et al., mixing took place, it could have been a multistage 1995; Holub et al., 1997b; Janousˇek et al., 2000b) in process, or there may have been limited isotopic which the effects of various stages of mixing can be contrast between end-members, or both (Bateman, observed in considerable detail. The main body of 1995). The residual melt within small hybrid masses evidence is derived from the disused Telet´ın quarry and enclaves may finally undergo chemical exchange opened in the 1950s near the contact between the with remaining host magma (Pin et al., 1990; Holden Sa´zava intrusion and the mainly metavolcanic roof et al., 1991; Elburg, 1996; Waight et al., 2000). pendantsoftheJ´ılove´ zone(DudekandFediuk,1957; These uncertainties demonstrate that magma-mix- Dudek and Za´ruba, 1967) (Fig. 1). Additional ing cannot be evaluated merely on geochemical observations and data were made in the course of a grounds. Field relationships and petrographic obser- salvage investigation within the underground gas vations of preserved disequilibrium textures need to reservoir,excavatedrecentlynearthetownofPrˇ´ıbram be linked with mineral chemistry in addition to at a depth of 1000 m (also Holub, 1998; Sokol et al., whole-rock geochemical and isotopic signatures 2000). Comparison of these outcrops provides a (Vernon, 1990; 1991; Hibbard, 1991; 1995; Elburg unique opportunity to reconstruct the three-dimen- 70 V.Janousˇeketal./Lithos78(2004)67–99 Fig.1.MapoftheCentralBohemianPlutonillustratingthedistributionofthefivemainigneoussuitesdefinedmainlyonthebasisoftheirage, petrology,andwhole-rockgeochemistry(Janousˇeketal.,2000b;cf.Holub,1992;Holubetal.,1997b)androofpendants(MetamorphicIslet andJ´ılove´zones,Devonianorthogneisses).ThelocationsofthedisusedquarryatTelet´ınandtheundergroundgasreservoiratPrˇ´ıbram(UGR) describedinthetextarealsoshown. sionalanatomyofaclassicallydevelopedsubvolcanic higher grade Moldanubian (s.s.) unit to the SE magma-mixing zone within the Central European (Orlov, 1935; Palivcova´, 1965; Kodym, 1966; Hercynides. Holub, 1992; Janousˇek et al., 1995; Holub et al., 1997a, b; Do¨rr et al., 1998; Janousˇek et al., 2000b; Janousˇek and Gerdes, 2003). The relationship of 2. Geological setting these units is uncertain (cf. Pitra et al., 1999; Scheuvens and Zulauf, 2000) but the NE–SW 2.1. Central Bohemian Pluton elongation of the CBP appears to follow a first- order tectonic zone, the Central Bohemian Suture, The CBP is a composite late Devonian–early marked by a steep gravity gradient between the Carboniferous granitoid body, intruded at the boun- generally positive, upper crustal Tepla´-Barrandian dary between two major geotectonic units, the low unit and the negative, middle-lower crustal Molda- grade Tepla´-Barrandian unit to the NW and the nubian block (e.g., Holub et al., 1997b). V.Janousˇeketal./Lithos78(2004)67–99 71 2.2. Sa´zava suite tholeiitic andcalc-alkalinemetavolcanicrocks(Wald- hausrova´, 1984; Fediuk, 1992) (Fig. 1), together with Rocks of the Sa´zava suite form much of the late Proterozoic to mid-Devonian metasediments and northern part of the CBP (Fig. 1) and are mainly mainly basic metavolcanic rocks of the Metamorphic representedbythetonaliticandquartzdioriticSa´zava Islet zone (Chaloupsky´ et al., 1995; Kachl´ık, 1999). intrusion and associated more basic bodies (olivine, pyroxene-) amphibole gabbro, gabbrodiorite, (quartz) diorite and rare hornblendite. Felsic rocks, including 3. Analytical techniques the slightly younger Necˇ´ın biotite granodiorite and Pozˇa´ry biotite trondhjemite-quartz leucodiorite are 3.1. Cathodoluminescence/SEM also present (Holub et al., 1997b; Janousˇek et al., 2000b) (Fig. 2a). The CL investigations used a CITL Technosyn Roof pendants of the northern CBP include the model 8200 Mk 4, mounted on a Zeiss Axioplan J´ılove´ zone, a SW-trending belt of Precambrian petrological microscope at typical operating con- Fig.2.(a)Pozˇa´rytrondhjemiteenclosingtwoangularxenolithsoftheSa´zavatonalitewithseveralMME—workingquarryatProsecˇnice;(b) stronglyflow-alignedMMEofquartzdioriticcompositionintheSa´zavatonalite—lowerbenchofdisusedquarryatTelet´ın;(c)bentflow- alignedMMEintheSa´zavatonalite;2ndbenchinthethenworkingquarryatTelet´ın(DudekandFediuk,1957);(d)mantledplagioclase,with partlyresorbedbytownite-anorthitecoreinmatrixofstrainedquartzanddeformedbiotiteinhybridrock,Telet´ınquarry,MME.Theverticalside of the photomicrograph is ca. 2.2 mm; (e) mantled plagioclase with extension of andesine rim into bytownite-anorthite core in quartz microdiorite; (f) mantled plagioclase with patchy compositional variation, lighter andesine and darker bytownite-anorthite, core in quartz microdiorite.Theverticalsideofbothphotomicrographsisca.1mm. 72 V.Janousˇeketal./Lithos78(2004)67–99 ditions of 26 kV, with a gun current of 210 AA, and 3.4. U–Pb dating a vacuum of approximately 1.2 mbar. Images were recorded on a Nikon DN100 digital camera. Zircon crystals recovered from the sample were Element distribution maps were acquired with a hand picked and analysed for U–Pb at the NERC Cambridge Instruments 360 SEM and an Oxford Isotope Geosciences Laboratory (NIGL), Keyworth, Instruments ISIS EDX with an atmospheric thin after standard mineral separation techniques at the window. General operating conditions were 20 kV Czech Geological Survey in Prague. Four fractions at 4 nA and the collection time was approximately consisting of oneto three clear, and as far as possible 16 h. crack-free, grains were selected for analysis. All grainswere abraded for 6–10 husing theair abrasion 3.2. Electron microprobe technique of Krogh (1982) and subsequently washed in4NHNO inanultrasonicbath.Eachfractionwas 3 The mineral analyses were obtained using a weighed and spiked with a mixed 205Pb/233U/235U Cameca SX-50 electron probe microanalyser in the tracer prior to digestion in Parr type PTFE bombs for UniversityofGlasgow.Theapparatuswasoperatedat 3 days at 240 8C (Parrish, 1987). Isotope data were 15kVand20nA,with10scountingtimeonthepeak obtained with a VG 354 mass spectrometer in static and 5 s on each of the positive and negative and dynamic mode (Noble et al., 1993). Repeated backgrounds.Calculationsofbothbiotiteandamphib- analysesoftheNBS982standardwereusedtocorrect oleformulaeweredonebyanunpublishedS-language for Daly detector and mass fractionation. Lead programme MIDAS by C.M. Farrow, University of isotopes were corrected for initial common Pb in Glasgow. Biotite analyses were recalculated on the excess of the laboratory blank Pb using a Stacey and basis of 22 oxygen equivalents, setting the sum of Kramers (1975) evolution model. Laboratory blanks tetrahedral cations (PSi+AlIV) to 8. The Fe3+ con- were 6F2 pg for Pb and b0.5 pg for U. Errors were tents in biotite were assessed using the method of calculated by numerical error propagation (Roddick, Schumacher(1991).Amphiboleformulaewerecalcu- 1987) and discordia was fitted using a modified York lated on the basis of 23 oxygen equivalents, setting (1969) regression. Isotope ratios were plotted using the sum of the tetrahedral cations (PSi+AlIV) to 8. Isoplot/Ex(Ludwig,2001),witherrorellipsesreflect- The Fe3+/Fe2+ ratio was estimated using method 9 ing 2j (95% confidence level) uncertainty. (average Fe3+) of Spear and Kimball (1984). Plagio- clase analyses were recalculated on the basis of 32 oxygen equivalents. 4. Petrography and mineral chemistry 3.3. Whole-rock geochemistry 4.1. Sa´zava intrusion Major-element whole-rock analyses were carried The dominant components of the Sa´zava intrusion out in the laboratories of the Czech Geological are amphibole-biotite to biotite-amphibole quartz Survey (CGS), Prague, using wet analyses (J. Sixta, diorite, tonalite and granodiorite (Fig. 3) consisting Chief Chemist). Most of the trace elements were of about 40–75% plagioclase, 2–35% magnesio- determined by XRF: Bruker AXS at the Institut fqr hornblende, 15–35% quartz, ~10% biotite and 0– Mineralogie, Universit7t Salzburg and Philips PW 12% K-feldspar. Accessory minerals include titanite 1450/20 at the University of Glasgow. The REE and (bothprimaryandsecondary),mainlyprismaticapatite Y were determined by ICP OES Perkin-Elmer (Fig.4a),zircon,allanite,epidoteandopaqueminerals Plasma II in the CGS. Statistical calculations, (magnetite and pyrite). The average grain sizes are plotting and numerical modelling of whole-rock 0.5–1.5 mm and the textures arehypidiomorphic. geochemical data, were made by means of a freeware statistical package R (Ihaka and Gentleman, 4.1.1. Plagioclase 1996; Janousˇek, 2000; Grunsky, 2002; Janousˇek et Plagioclase forms subhedral to almost euhedral al. 2003). prisms, on average 0.7–1.5 mm, but up to 3 mm V.Janousˇeketal./Lithos78(2004)67–99 73 Barbarin,1990)anddullochrerims,ormorecomplex combinations with discontinuous zoning (Fig. 4b). Reversely zoned plagioclases, with sodic cores (~An ) overgrown by calcic rims (An ) occur 40 80–90 sparsely close to partly disintegrated MME (Sokol et al., 1998). 4.1.2. Amphibole Anhedral–subhedral, poikilitic prisms of amphib- oleareonaverage1.2–2mm(upto4.5mm)long.The maximum extinction angle (Ztc) is 20–258. Crystals areusuallystrongly pleochroic: X light yellow-green, Ydarkgreen,Zdarkbluish-green.Theytend toform clotswithassociated biotite and titanite. The amphib- oles typically enclose large numbers of small, sub- Fig. 3. Compositions of the Sa´zava suite in the multicationic hedralplagioclaseandbiotitecrystals,usuallyaligned diagramP–QofDebonandLeFort(1983,1988)(P representing parallel to the cleavage. Commonly, there are also the proportion of K-feldspar to plagioclase and Q the quartz content): gr=granite, ad=adamellite, gd=granodiorite, to=tonalite, numerous apatite inclusions. sq=quartz syenite, mzq=quartz monzonite, mzdq=quartz monzo- Typical Sa´zava amphiboles are magnesiohorn- diorite,dq=quartzdiorite,s=syenite,mz=monzonite,mzgo=monzo- blende (classification of Leake et al., 1997) with gabbro,go=gabbro.DatasourcesfortheSa´zavasuite:Langetal. somecoresstraddlingthetschermakiteboundary(Mg/ (1978),Janousˇeketal.(2000b),Sokoletal.(2000)andthiswork. (Mg+Fe2+)=0.51–0.62, Si=6.4–7.1) (Table 2, Fig. 7). Denotedisafieldofputativehybrids(quartzmicrodiorite:qtzmd, mafic microgranular enclaves: MME); fields for other three main Pressure estimates, based on the aluminium-in-horn- suitesoftheCentralBohemianPluton(Janousˇeketal.,2000b)are blende geobarometer, are given in Table 3. As shown shownforcomparison. byBlundyandHolland(1990)andlaterconfirmedby Anderson and Smith (1995), the total Al content in across, surrounded by interstitial quartz and K- hornblende is both pressure and temperature depend- feldspar. Relatively small (0.2–0.3 mm) subhedral or ent. Temperature effects account for the considerable anhedral plagioclases are often enclosed by large discrepancies between pressures obtained by empiri- amphibole crystals. cal (Hammastrom and Zen, 1986; Hollister et al., Theluminescence colour oftheplagioclasesinthe 1987) and experimental (Johnson and Rutherford, CBP is strongly compositionally dependent, being 1989; Thomas and Ernst, 1990) calibrations. brighterinmorecalcicdomains.Thisperhapsreflects In general the data point to an intrusion level of an increasing Ca2+–Mn2+ substitution in parallel with b10–12 km but the systematic compositional differ- increasing An content (Janousˇek et al., 2000a). Most ences between the hornblende of the eastern (average of the crystals in the Sa´zava mass are unzoned or AlT=1.66 pfu) and western (average AlT=1.35–1.46 normally zoned andesine (An , mainly ~An : pfu) parts of the Sa´zava intrusion are consistent with 32–54 40–45 Table 1) with dull ochre luminescence. However, and either higher temperatures in the east, or a shallower especially in the western part of the intrusion, some intrusion depth (by ca. 3 km) in the west. Following crystals show discontinuous zoning, with brighter Anderson and Smith (1995), the pressures calculated yellow, more calcic cores (labradorite and bytownite (for expected magma temperatures of 750–800 8C) An : cf. Lang et al., 1978) (Fig. 4b). The dull are3.8–2.6kbarfor theeast andless than ca.2.8–1.7 50–76 ochre, normally zoned rims of these mantled crystals kbar for the west. This fits with the suggestion of are of andesine (An ) of similar composition to Scheuvens and Zulauf (2000), on the basis of Al-in- 40–48 small unzoned (optically and in CL) plagioclases of hornblende geobarometry for the Klatovy intrusion thematrix(~An ).IntheTelet´ınquarry,rarelarge (SW part of the CBP), of rather late diapiric upwell- 45–48 plagioclases show narrow bright yellow zones (indi- ing of the Moldanubian relative to the Tepla´- cating marked increases in An content; Wiebe, 1968; Barrandian unit. 74 V.Janousˇeketal./Lithos78(2004)67–99 Fig. 4. Zoning of plagioclase from the Sa´zava tonalite and larger hybrid bodies, Telet´ın quarry, as revealed by cathodoluminescence (CL) photomicrographs(a–e,g)andelectronmicroprobemapsofNadistribution(f,h).(a)Euhedral,stronglyzoned,stubbyapatitecrystalsenclosed inalargebiotite;Sa´zavatonaliteSa-26.(b)PlagioclasewithacalciccoreandseveralprominentbrightyellowCa-richzoneswithinbroadrimof dullochreandesine;Sa´zavatonaliteSa-26.(c)Mantledplagioclasewithshattered,calciccore,overgrownbybroadsodicrim.Brightorange mineralissecondarycalcite;plagioclasemegacryst-richquartzmicrodiorite,largermasstotherightonthebottombench(SaD-6).(d)Mantled plagioclasewithaslightlyresorbedcalciccoreandthinsodicrim.Homogeneousgabbrodiorite,largebodyinthemiddleofthebottombench, ca.1.5mbelowcontactwithtonaliterichinMME(Sas-3).(e)Severallarge,variouslyresorbedplagioclaseswithcalciccores(An ),athin 87–92 intermediatezone(An )andbroader,normallyzonedsodicrims(An ).GabbrodioriteSas-3.(f)AnelectronmicroprobemapofNa 68–82 45–51 distributioninthesameplagioclases.(g)Largeboxy-cellularplagioclasewithlabradorite-anorthitecoreovergrownbyandesinerim,Fig.6a illustratesascanacrossthiscrystal.Quartzmicrodioriterichinplagioclasemegacrysts,largermassestotherightonthebottombench(Sas-4). (h)Nadistributionintheplagioclasein(g). V.Janousˇeketal./Lithos78(2004)67–99 75 Table1 Representativeanalysesofplagioclase Rock Gabbrodioritepoorin Quartzmicrodioriterich (Gabbro-)dioritepoor Sa´zavagranodiorite-tonalite plgmegacrysts inplgmegacrysts inplgmegacrysts Sample Sas-3 Sas-4 Sas-2 Sa-10 Sa-3 Sa-10 Localitya 1 1 1 1 1 1 1 1 2 3 3 3 2 Analysis scan1/01 scan1/05 scan1/12 scan3/01 scan3/15 scan3/18 scan1/03 scan1/04 4 9 8 11 1 Description Largeplgwithcalcicspike Largeplgwithcalciccore Largeplgwithcalcic Largeplg Largeplg Small Large core XXin amph Rb SP C R OC C C OC C C R C R SiO 57.33 48.64 54.85 55.62 47.04 44.10 45.78 47.26 57.34 53.00 53.79 55.82 56.68 2 TiO 0.02 0.04 0.00 0.02 0.00 0.03 0.06 0.07 0.00 0.04 0.00 0.00 0.00 2 AlO 26.62 33.19 28.35 27.69 34.01 35.25 33.63 32.85 26.72 29.50 29.47 28.11 27.53 2 3 FeO 0.11 0.05 0.11 0.11 0.18 0.13 0.15 0.07 0.10 0.12 0.09 0.11 0.25 MnO 0.01 – 0.01 0.01 – 0.01 0.07 – – – – – – CaO 8.52 15.77 10.89 9.65 15.69 19.09 17.56 16.24 6.89 11.30 10.99 9.42 7.55 NaO 6.82 2.31 5.55 6.35 1.86 0.94 1.78 1.86 7.74 5.00 5.28 6.16 7.19 2 KO 0.14 0.22 0.13 0.06 0.90 0.02 0.03 1.23 0.10 0.15 0.17 0.16 0.23 2 P 99.56 100.22 99.88 99.50 99.67 99.57 99.05 99.59 98.89 99.10 99.78 99.78 99.43 Si 10.33 8.88 9.91 10.06 8.67 8.20 8.52 8.75 10.37 9.67 9.74 10.06 10.22 Al 5.65 7.13 6.03 5.90 7.38 7.72 7.38 7.17 5.69 6.39 6.29 5.97 5.85 Ti 0.00 0.01 0.00 0.00 0.00 0.01 0.01 0.01 0.00 0.00 0.00 0.00 0.00 Fe2+ 0.02 0.01 0.02 0.02 0.03 0.02 0.02 0.01 0.01 0.02 0.01 0.02 0.04 Mn 0.00 0.00 0.00 0.00 0.00 0.00 0.01 0.00 0.00 0.00 0.00 0.00 0.00 Ca 1.64 3.08 2.11 1.87 3.10 3.80 3.50 3.22 1.34 2.21 2.13 1.82 1.46 Na 2.38 0.82 1.95 2.23 0.67 0.34 0.64 0.67 2.71 1.77 1.85 2.15 2.51 K 0.03 0.05 0.03 0.02 0.21 0.01 0.01 0.29 0.02 0.03 0.04 0.04 0.05 P 20.05 19.98 20.05 20.10 20.06 20.10 20.09 20.12 20.14 20.09 20.06 20.06 20.13 Ab 58.77 20.76 47.68 54.13 16.83 8.19 15.42 16.03 66.58 44.14 46.02 53.62 62.44 An 40.49 77.97 51.59 45.39 77.89 91.57 84.34 77.03 32.92 55.11 52.99 45.39 36.32 Or 0.74 1.27 0.73 0.49 5.28 0.24 0.24 6.94 0.49 0.75 1.00 1.00 1.24 a Localities:(1)Telet´ın,8kmSofJ´ılove´,disusedquarry,500mSEofbusstop;(2)Prosecˇnice,5kmSEofJ´ılove´,workingquarry,300mN ofrailwaystation;(3)Mracˇ,5kmNofBenesˇov,workingquarry500mESEofrailwaystation. b R:rim,SP:narrowcalciczone(dspikeT),C:core,OC:outercore. 4.1.3. Quartz Fe contents with AlIV ranging between 2.5 and 2.7 Quartz occurs as anhedral, interstitial crystals on pfu and a fairly constant 100dFe*/(Fe*+Mg) ratio average 0.5–2 mm (up to 4 mm) across. Crystals of ~55 (Table 4). show strong undulose extinction and are commonly broken into numerous subgrains (consertal texture) 4.1.5. K-feldspar or appear cataclastic. Where present, slightly perthitic K-feldspar forms interstitial grains, about 1 mm (up to 5 mm) across. 4.1.4. Biotite Myrmekite occurs commonly at the boundary with Biotite forms anhedral flakes on average 0.25–1 plagioclase. The K-feldspar emits a light blue mm (up to 2.5 mm) across. It is strongly luminescence, lacking any apparent variation. It pleochroic: X pale straw yellow, Y=Z dark red- is uniform in composition, with 7–10% albite brown. Analyses show both high AlIVand high total component. 76 V.Janousˇeketal./Lithos78(2004)67–99 Table2 RepresentativeanalysesofamphibolefromtheSa´zavaintrusionandTelet´ınquartzmicrodiorite Sa´zava(eastern) Sa´zava(western) Telet´ınquartzmicrodiorite Sample Sa-3 Sa-3 Sa-7 Sa-10 Sa-10 SaD-1 SaD-1 SaD-1 SaD-1 SaD-1 SaD-1 Locality Mracˇ (3) 4a Telet´ın(1) Telet´ın(1) Analysis 4 5 5 1 3 7 8 Scan4 Scan6 Scan8 Scan14 Description Large Large Large Large Large Scanacrosszonedgreen/brownamphibole Rb C R R C R C OR IR OC IC SiO 43.38 42.49 46.81 43.98 42.93 46.09 41.65 46.72 45.48 40.61 40.22 2 TiO 0.72 0.62 0.79 0.87 0.81 0.93 2.00 0.86 1.12 2.68 3.15 2 AlO 9.85 10.20 7.55 8.17 8.14 7.18 11.10 8.76 8.13 13.16 13.73 2 3 FeO 18.91 20.23 19.22 20.66 20.03 20.47 19.91 10.47 10.55 9.60 12.06 MnO 0.39 0.54 0.46 0.90 0.82 0.62 0.53 0.44 0.44 0.37 0.35 MgO 9.26 9.30 10.60 9.45 9.76 10.65 8.29 11.45 11.54 11.48 11.57 CaO 12.08 11.92 11.67 11.11 10.91 9.28 11.23 17.78 17.83 16.17 12.76 NaO 0.95 1.05 0.80 1.17 1.18 0.79 1.41 0.87 0.83 1.59 1.71 2 KO 1.04 1.17 0.50 0.69 0.63 0.35 0.57 0.50 0.42 0.60 0.50 2 P 96.58 97.52 98.42 97.00 95.21 96.36 96.70 97.84 96.34 96.27 96.05 Si 6.604 6.422 6.909 6.664 6.603 6.950 6.355 6.904 6.837 6.149 5.993 AlIV 1.396 1.578 1.092 1.336 1.397 1.050 1.645 1.096 1.163 1.851 2.007 P(T) 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 AlVI 0.371 0.241 0.223 0.124 0.079 0.226 0.352 0.431 0.278 0.497 0.406 Ti 0.083 0.071 0.088 0.099 0.094 0.105 0.230 0.095 0.127 0.305 0.353 Fe3+ 0.408 0.736 0.535 0.746 0.871 0.546 0.481 0.333 0.460 0.308 0.470 Mg 2.102 2.094 2.331 2.134 2.237 2.393 1.885 2.307 2.364 2.166 2.678 Fe2+ 2.000 1.821 1.824 1.872 1.706 1.730 2.052 1.834 1.771 1.724 1.094 Mn 0.037 0.037 0.000 0.025 0.013 0.000 0.000 0.000 0.000 0.000 0.000 P(C) 5.000 5.000 5.000 5.000 5.000 5.000 5.000 5.000 5.000 5.000 5.000 Fe2+ 0.000 0.000 0.014 0.000 0.000 0.305 0.008 0.031 0.010 0.016 0.027 Mn 0.014 0.032 0.058 0.091 0.094 0.079 0.069 0.056 0.055 0.047 0.044 Mg 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Ca 1.970 1.931 1.846 1.804 1.798 1.499 1.835 1.813 1.859 1.863 1.847 Na(M) 0.016 0.037 0.083 0.105 0.108 0.116 0.088 0.100 0.075 0.074 0.082 4 P(B) 2.000 2.000 2.000 2.000 2.000 2.000 2.000 2.000 2.000 2.000 2.000 Na(A) 0.265 0.272 0.147 0.239 0.244 0.116 0.329 0.148 0.167 0.394 0.412 K 0.203 0.225 0.094 0.133 0.124 0.068 0.111 0.094 0.080 0.116 0.095 P(A) 0.468 0.497 0.241 0.372 0.367 0.184 0.440 0.241 0.247 0.510 0.507 Pcat 15.468 15.497 15.241 15.372 15.367 15.184 15.440 15.241 15.247 15.510 15.507 Mg 0.51 0.53 0.56 0.53 0.57 0.54 0.48 0.55 0.57 0.56 0.71 Fe2þþMg AlTc 1.77 1.82 1.31 1.46 1.48 1.28 2.00 1.53 1.44 2.35 2.41 a LocalitiesasinTable1plus(4)Krhanice,6kmSEofJ´ılove´,workingquarry,1300mNWofrailwaystation. b R:rim,IR:innerrim,OR:outerrim,C:core,IC:innercore,OC:outercore. c AlT:totalaluminium.