Table Of Content

of OoBurAna l Chemistry ee! = matt LSEVIER Journal of Organometallic Chemistry 513 (1996) 291 Author Index of Volume 513 Adams, C.J., 255 Hemling, H., 49 Rath, N.P., 17 Albertin, G., 147 Hidai, M., 231 Rodriguez, J.-G., 71 Antoniutti, S., 147 Hirth, U.-A., 31 Russo, U., 77 Asaro, F., 193 Hitchcock, P.B., 281 Hosomizu, M., 231 Sanchez, A., 63 Bordignon, E., 147 Huhmann, J.L., 17 Santini, C., 137 Bravo, J., 63 Humphrey, M.G., 85, 201 Scherer, M., 135 Bruce, M.I., 255 Schollhammer, P., 181 Kanatzidis, M.G., | Schumann, H., 49 Calogero, S., 137 Kawabata, J.-I., 231 Schwarz, W., 213 Campana, C.F., 17 Kerber, R.C., 277 Shah, D., 239 Casas, J.S., 63 Kruck, T., 135 Sieler, J., 37 Castafio, M.V., 63 Kumar Das, V.G., 105 Sindellari, L., 77 Cecchi, P., 137 Kuwata, S., 231 Skelton, B.W., 201, 255 Chernega, A.N., 247 Sordo, J., 63 Lappert, M.F., 281 Cifuentes, M.P., 85, 201 Stringer, G., 273 Lee, H.-K., 281 Clark, G.R., 107 Sullivan, A.C., 239 Leung, W.-P., 281 Contreras, R., 7 Léw, R., 213 Cordero, M.B., 63 Talarmin, J., 181 Corey, J.Y., 17 Taube, R., 37, 49 Maiwald, S., 37, 49 Corrigan, J.F., 273 Taylor, N.J., 273 Malisch, W., 31 Costa, G., 193 Marder, T.B., 273 Couce, M.D., 77 Uhl, W., 163 Martin-Villamil, R.M., 71 Mehnert, C.P., 247 Dai, C., 273 Valderrama, M., 7 Metzler, M.R., 107 Das, B.K., | Valle, G., 77, 137 Mizobe, Y., 231 De Bellefon, C., 155 Vester, A., 163 Motevalli, M., 239 Deelman, B.-J., 281 Von Philipsborn, W., 193 Muir, K.W., 181 De Felice, V., 97 De Renzi, A., 97 Wagner, F.E., 137 Ng, S.W., 105 Dreos, R., 193 Waldbaum, B.R., 277 Noltemeyer, M., 31 Westerhausen, M., 213 Norman, N.C., 273 Faraglia, G., 77 Whitaker, G., 107 Ferrara, M.L., 97 Olmstead, M.M., 173 White, A.H., 201, 255 Fonseca, I., 71 Ojjate, A., 71 Willis, A.C., 85 Windisch, H., 49 Gerding, R., 163 Panunzi, A., 97 Wong, W.-T., 27 Gioia Lobbia, G., 137 Pellizer, G., 193 Wong, W.-Y., 27 Green, M.L.H., 247 Pétillon, F.Y., 181 Woodgate, P.D., 107 Grenouillet, P., 155 Poder-Guillou, S., 181 Grigsby, W.J., 173 Power, P.P., 173 Yufit, D.S., 181 Grin, K., 31 Elsevier Science S.A. ournal of¢ a metallic emistry Journal of Organometallic Chemistry 513 (1996) 293-299 Subject Index of Volume 513 Ab initio calculations Amine NMR-spektroskopische und strukturelle Charakterisierung der Tri- Reactions of Ru.( ;-C, PPh, u-PPh,XCO),, with functional phos- iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. phines. X-ray structures of Ru;( 5-C,PPh, u-PPh, Xdppm)- (CO),,- CHC], Ru( 5-C,H) u-PPh,)>( u-P,N-PPhC,- Léw und W. Schwarz), 213 H,NH-2X u-COXCO),o, Rug f s24-C, PPh, [Ru( u.-OHXC, P-2- Alkenyls CHMeC,H,PPh,-2(CO),]} (-PPh,XCO),) - CHCl, and Reactions of dinuclear and polynuclear complexes. X VI. Chemistry of Ru,( 4-H)>{ js-PPh,C,CHC,(PPCh ,,-H2) )( 4-PPh, (CO), , hydrido-, thiolato-bridged complexes [Mo,Cp,(-HX-SRXCO), ] (R = Me, Ph): Reactivity and electrochemical behaviour; crystal (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 structure of [Mo,Cp,(y-SPh) {p-o : n?-C(CH ,)=CHCH ,}(CO), ] n-Arene (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, Synthesis and reactions of [Mo(2,6-lutidineX 7-allyl)] derivatives (C.P. K.W. Muir and D.S. Yufit), 181 Mehnert, A.N. Chernega and M.L.H. Green), 247 Alkylidyne cluster Aza-allyl Synthesis of a novel planar hexaosmium carbonyl cluster: crystal Novel monoanionic di-N,N’-centred chelating ligands and their C, structure of [HOs,(CO),.(-n?-NC;H,CH=CH)] (W.-Y. Wong and C, symmetrical zirconium complexes (B.-J. Deelman, P.B. and W.-T. Wong), 27 Hitchcock, M.F. Lappert, H.-K. Lee and W.-P. Leung), 281 Alkylrhodoximes Steric effects in organometallic compounds. A ‘Rh NMR study of Bimetallic alkylrhodoximes (F. Asaro, G. Costa, R. Dreos, G. Pellizer and Structure and reactivity of (Dibenzo[b,e]fulvalene)Mo,(CO), (R.C. W. Von Philipsborn), 193 Kerber and B.R. Waldbaum), 277 Alkynyl compounds Bis(tri-iso-propylsilyl)phosphane Preparation of the alkynyl—hydride complexes MH(C=CR){PPh- NMR-spektroskopische und strukturelle Charakterisierung der Tri- (OEt),}, of iron and ruthenium (G. Albertin, S. Antoniutti and E. iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. Bordignon), 147 Léw und W. Schwarz), 213 Allyl Boron Synthesis and reactions of [Mo(2,6-lutidineX n-allyl)] derivatives (C.P. Organotin(IV) polypyrazolylborates. IX. Tetrakis(4-methyl-1 H-pyra- Mehnert, A.N. Chernega and M.L.H. Green), 247 zol-1-yl)borates. Characterisation, Méssbauer study and X-ray XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- crystal structure of Cl,Sn( u-4-MePz),B(4-MePz) (G. Gioia Lob- neodym(III)-Komplexe als Katalysatoren fiir die stereospezifische bia, P. Cecchi, C. Santini, S. Calogero, G. Valle and F.E. Wagner), Butadienpolymerisation: Li[Nd(n°-C,H,),]- 1,5Dioxan, Li[Nd 137 (7-C,H;Xn°*-C,Hs),] + 2Dioxan und Li[Nd(n°-C,Me,Xn°- Synthesis and molecular structure of the paramagnetic Co(ID bis(boryl) C,H,),]- 3Dimethylglykolether (R. Taube, S. Maiwald und J. complex [Co(PMe,),(Bcat),] (cat= 1,2-0,C,H,) (C. Dai, G. Sieler), 37 Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- man), 273 lanthanoid-Komplexe La(n’-C,H,;),;°1,5 Dioxan und Nd(n?- Boryl C,H,),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- Synthesis and molecular structure of the paramagnetic Co(II) bis(boryl) satoren fiir die stereospezifische Butadienpolymerisation (R. complex [Co(PMe,),(Bcat),] (cat= 1,2-0,C,H,) (C. Dai, G. Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- 49 man), 273 Aluminium—aluminium bond Bridging thiolate The decomposition reaction of the dialane radical anion [R,Al- Reactions of dinuclear and polynuclear complexes. X VI. Chemistry of AIR,]~ in DME(II): crystal structures of the aluminium glyco- hydrido-, thiolato-bridged complexes [Mo,Cp,(-HXp-SRXCO),] lates [R,AKOCH,),]K(DME) and R,AIKOCH,), Al(R)- (R = Me, Ph): Reactivity and electrochemical behaviour; crystal (OCH,), AIR, (R = CH(SiMe,),) (W. Uhl, R. Gerding and A. structure of [Mo,Cp,(y-SPh) {y-o : y?-C(CH ,)=CHCH ,}(CO), ] Vester), 163 (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, (Cyclopentadieny)laluminium complexes K.W. Muir and D.S. Yufit), 181 Cp* AIR, compounds (R = Me, Et, 'Bu): synthesis and structure of Butadiene novel aluminium organyls with a pentamethylcyclopentadienyl XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- substituent as well as structure of analogous Cp’'AIR, compounds neodym(III)-Komplexe als Katalysatoren fur die stereospezifische (Cp’ = Cp, MeCp; R = Me, Et) (M. Scherer and T. Kruck), 135 Butadienpolymerisation: Li[Nd(n°-C,H,),]- 1,5Dioxan, Li[Nd Elsevier Science S.A. Subject Index of Volume 513 (7-Cs;H;Xn?-C3H-s 2)Di3o]xa n und Li[Nd(n°-C;Me,Xn°- Chemical shifts C,H,);]- 3Dimethylglykolether (R. Taube, S. Maiwald und J. Steric effects in organometallic compounds. A '°3Rh NMR study of Sieler), 37 alkylrhodoximes (F. Asaro, G. Costa, R. Dreos, G. Pellizer and XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- W. Von Philipsborn), 193 lanthanoid-Komplexe La(n?-C,H,),-1,5 Dioxan und Nd(n?- Chromium C,H,),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- Synthesis and reactions of [(((n°)-2-acylaryl)-C,O)tetracarbonylman- satoren fiir die stereospezifische Butadienpolymerisation (R. ganese]- tricarbonylchromium complexes: enhancement of di- Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), astereoselection during cyclopentaannulation (G.R. Clark, M.R. 49 Metzler, G. Whitaker and P.D. Woodgate), 107 Cluster Calcium High nuclearity ruthenium carbonyl cluster chemistry. IV. Reactivity NMR-spektroskopische und strukturelle Charakterisierung der Tri- of [Rujo(u-HXp.-CXCO),,]” towards trimethylphosphite or iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. bis(diphenylphosphino)acetylene; X-ray crystal structure of Léw und W. Schwarz), 213 [PPh , [Ru ,o(u-HXp.-CXCO),,{P(OMe),},] (M.P. Cifuentes, Carbonyl M.G. Humphrey and A.C. Willis), 85 High nuclearity ruthenium carbonyl cluster chemistry. IV. Reactivity Reactions of Ru,( us5-C, PPh, u-PPh,XCO),, with functional phos- of [Ru,o(u-HXp.-CXCO),,]> towards trimethylphosphite or phines. X-ray structures of Ru,( u<;-C,PPh,X u-PPh, Xdppm)- (CO),,- CHCl, Ru,(5-C,H -PPh,),( u-P,N-PPh,C,- bis(diphenylphosphino)acetylene; X-ray crystal structure of H,NH-2X u-COXCO),5, Ru,4{ 44-C,PPh,[Ru( p-OHXC, P-2- [PPh , [Ru ,o(j-HXp.-CXCO),,{P(OMe),},] (M.P. Cifuentes, M.G. Humphrey and A.C. Willis), 85 CHMeC,H 4PPh,-2CO),]} (-PPh,XCO),. - CHCl, and Reactions of Ru,( ;-C,PPh, u-PPh,XCO),, with functional phos- Ru,( -H)»{ us-PPh,C ,CHC(C,H ,PPh,-2))( u-PPh, CO), , phines. X-ray structures of Ru.( u;-C,PPh, u-PPh,Xdppm)- (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 (CO),,- CHCl, Ru,(5-C,HX u-PPh,),( u-P,N-PPh,C,H,- Ruthenium clusters with nitrogen ligands. V. Pyridyl ligands on NH-2) u-COXKCO),,, Rug w4-C,PPh,[Ru( .-OHXC, P-2- triruthenium cores. X-ray structures of Ru,( u-H),( u-NC; CHMeC,H,PPh,-2XCO),]} (u-PPh,XCO),, - CHCl, and H,),(CO), and Ru,(3-7?-PPhCH,PPh,) ( u-NC,H,XCO), Ru.( w-H),{ u,PPh,C,CHC(C,H ,PPh,-2)}( u-PPh, CO), , (M.P. Cifuentes, M.G. Humphrey, B.W. Skelton and A.H. White), (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 201 Reaction products of CO with square-planar platinum(II)-(N,N- Cobalt chelate) complexes: synthesis and reactivity (V. De Felice, A. Synthesis and molecular structure of the paramagnetic Co(II) bis(boryl) De Renzi, M.L. Ferrara and A. Panunzi), 97 complex [Co(PMe,),(Bcat),] (cat= 1,2-0,C,H,) (C. Dai, G. Ruthenium clusters with nitrogen ligands. V. Pyridyl ligands on Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- triruthenium cores. X-ray structures of Ru,( u-H),( u-NC,- man), 273 H,),(CO), and Ru,(,-7’-PPhCH,PPh,) ( u-NC.H,)- Complexes (CO), (M.P. Cifuentes, M.G. Humphrey, B.W. Skelton and A.H. Tautomerism in coordinated |-phenyl-5-thione-1,2,3,4-tetrazole (HL). White), 201 Synthesis and crystal structure of [SnMe,(phen)L, ] ( phen = 1,10- Synthesis and reactions of [(((7°)-2-acylaryl)-C,O)tetracarbonylman- phenanthroline) (J. Bravo, M.B. Cordero, J.S. Casas, M.V. ganese]- tricarbonylchromium complexes: enhancement of di- Castafio, A. Sanchez and J. Sordo), 63 astereoselection during cyclopentaannulation (G.R. Clark, M.R. Crystal structure Metzler, G. Whitaker and P.D. Woodgate), 107 High nuclearity ruthenium carbonyl cluster chemistry. IV. Reactivity Carbonyl cluster of [Ru (u-HXp.-CXCO),,]”> towards trimethylphosphite or Synthesis of a novel planar hexaosmium carbonyl! cluster: crystal bis(diphenylphosphino)acetylene; X-ray crystal structure of structure of [HOs,(CO),.(u-n?-NC;H,CH=CH)] (W.-Y. Wong (PPh , [Ru ,o(u-HXp.-CXCO),,.{P(OMe),},] (M.P. Cifuentes, and W.-T. Wong), 27 M.G. Humphrey and A.C. Willis), 85 Catalysis Outer-sphere coordination of o-phenanthroline in bis{aquachloro- XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- tri( p-chloropheny))tin'o-phenanthroline] (S.W. Ng and V.G. Ku- neodym(III)-Komplexe als Katalysatoren fiir die stereospezifische mar Das), 105 Butadienpolymerisation: Li[Nd(n*-C,H,),]- 1,5Dioxan, Li[Nd Polymeric chains from [{Ph,SiOLi - THF),O},] and linear dicoordi- (7-C;H;Xn*-C,H,);]- 2Dioxan und Li[Nd(n°-C,Me,X7?- nating nitrogen bases. Crystal X-ray structures of [{Ph,SiOLi),O- C,H,),]- 3Dimethylglykolether (R. Taube, S. Maiwald und J. THF}, - 2DABCO], DABCO = 1,4-diazabicyclo[2.2.2]Joctane, and Sieler), 37 [{Ph,SiOLi-) T,HFO} , - 2{4,4’}-bipyridine] (M. Motevalli, D. XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- Shah and A.C. Sullivan), 239 lanthanoid-Komplexe La(n*-C,H,),°1,5 Dioxan und Nd(n?- Reactions of Ru,( 45-C, PPh, X u-PPh,XCO),, with functional phos- C,H,),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- phines. X-ray structures of Ru,( 5-C,PPh, u-PPh, Xdppm)- (CO),,- CHCl, Ru,(5-C,H) u-PPh,),( u-P,N-PPh,C,- satoren fiir die stereospezifische Butadienpolymerisation (R. Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), H,NH-2 p-COXCO),5, Ru, w4-PCPh ,,[R u( u-OHXC, P-2- CHMeC,H ,PPh,-2XCO),]} (-PPh,XCO),, - CHCl, and 49 Ru,( u-H),{ ws-PPh,C ,CHC(C,H,PPh ,-2)}( u-PPh, XCO), , Chalcogenides Solvothermal synthesis, molecular structures and spectroscopic char- (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 acterization of the cluster compounds (Ph, P),[Fe ,Te,(CO), ,] and Ruthenium clusters with nitrogen ligands. V. Pyridyl ligands on Cs{HFe ,Te(CO), ] (B.K. Das and M.G. Kanatzidis), | triruthenium cores. X-ray structures of Ru,( u-H),( u-NC,H,),- Chelating amide (CO), and Ru,( 4,-7?-PPhCH,PPh,) ( u-NC;H,XCO), (M.P. Novel monoanionic di-N,N’-centred chelating ligands and their C, Cifuentes, M.G. Humphrey, B.W. Skelton and A.H. White), 201 and C, symmetrical zirconium complexes (B.-J. Deelman, P.B. Synthesis and reactions of [(((n°)-2-acylaryl)-C,O)tetracarbonylman- Hitchcock, M.F. Lappert, H.-K. Lee and W.-P. Leung), 281 ganese]- tricarbonylchromium complexes: enhancement of di- Subject Index of Volume 513 295 astereoselection during cyclopentaannulation (G.R. Clark, M.R. (R = Me, Ph): Reactivity and electrochemical behaviour; crystal Metzler, G. Whitaker and P.D. Woodgate), 107 structure of [Mo,Cp,(y-SPh) {-o : n?-C(CH ,)=CHCH ,K(CO), ] Synthesis and reactions of [Mo(2,6-lutidineX n-allyl)] derivatives (C.P. (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, Mehnert, A.N. Chernega and M.L.H. Green), 247 K.W. Muir and D.S. Yufit), 181 Synthesis of a novel planar hexaosmium carbonyl cluster: crystal Esters of 2-mercaptopyridine-5-carboxylic acid structure of [HOs,(CO),(u-n?-NC,H ,CH=CH)] (W.-Y. Wong Synthesis, characterisation and X-ray crystal structures of diorgano- and W.-T. Wong), 27 tin(IV) complexes with 2-mercaptopyridine derivatives (M.D. (THFMgNPh), as an imide transfer agent: synthesis of titanium and Couce, G. Faraglia, U. Russo, L. Sindellari and G. Valle), 77 zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and P.P. Power), 173 Ferrocenes Cyclic voltammogram A practical synthesis of ethynylferrocene from ferrocene carboxalde- Preparation and properties of diruthenium complexes with bridging disulfide and thiolate ligands [Cp* Ru( u-S,\ u-SR),RuCp* | hyde: structure of 1,4-diferrocenyl-1,3-butadiyne (J.-G. Rodri- (Cp* = n°-C,Me,, R=Pr' and PhCH,) (Y. Mizobe, M. Ho- guez, A. Ofiate, R.M. Martin-Villamil and I. Fonseca), 71 somizu, S. Kuwata, J.-i. Kawabata and M. Hidai), 231 Five-coordinate complexes Reaction products of CO with square-planar platinum(ID-(N,N- [2 + 1]-Cycloadditions chelate) complexes: synthesis and reactivity (V. De Felice, A. Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- a De Renzi, M.L. Ferrara and A. Panunzi), 97 lisierte Phosphametallacyclen C;R ,(OC), W-PH(t-Bu)-X (R = H, Fluxionality Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Grin, Coordination chemistry of mono- and di-nitriles in [Ru,(CO),,_,- U.-A. Hirth und M. Noltemeyer), 31 (RCN),,] (n = 1-3): influence of the CO/ nitrile ratio on fluxion- Cyclopentaannulation ality (P. Grenouillet and C. De Bellefon), 155 Synthesis and reactions of [(((n°)-2-acylaryl)-C,O)tetracarbonylman- Fulvalene ganese]- tricarbonylchromium complexes: enhancement of di- Structure and reactivity of (Dibenzo[b,e]fulvalene)Mo,(CO), (R.C. astereoselection during cyclopentaannulation (G.R. Clark, M.R. Kerber and B.R. Waldbaum), 277 Metzler, G. Whitaker and P.D. Woodgate), 107 Cyclopentadieny] (THFMgNPh), as an imide transfer agent: synthesis of titanium and Glycolate zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and The decomposition reaction of the dialane radical anion [R,Al- P.P. Power), 173 AIR,|~ in DME(ID: crystal structures of the aluminium glyco- XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- lates [R,AMKOCH,),]K(DME) and R,AKOCH,),AKR)- neodym(III)-Komplexe als Katalysatoren fir die stereospezifische (OCH,) ,A IR, (R = CH(SiMe,),) (W. Uhl, R. Gerding and A. Butadienpolymerisation: Li[Nd(m*-C,H,),] - 1,5Dioxan, Vester), 163 Li[Nd(a7-C,H;)(m°-C,H,),] + 2Dioxan und _ Li[Nd(m°- C,Me,7*--C3 D,imeHthy,lg)lyk;ole]the r (R. Taube, S. Mai- wald und J. Sieler), 37 Hafnium Reaction of (POR)M(OAc), (M = Zr, Hf) with "BuLi and solid state Cyclopentadienyl complexes structure of [(TPP)Zr{ u-OH),], (J.L. Huhmann, J.Y. Corey, N.P. Pentamethylcyclopentadienyliridium(III) complexes containing ter- Rath and C.F. Campana), 17 tiary phosphorus chalcogenide ligands: crystal structure of [(n°C., Me, )Ir{POCOMe), }{n?(SPPh,),CH,—S,S'}]BF, - 0.5Me,- Hydrides CO (M. Valderrama and R. Contreras), 7 Preparation of the alkynyl—hydride complexes MH(C=CR)- {PPh(OEt),}, of iron and ruthenium (G. Albertin, S. Antoniutti Dinuclear complexes and E. Bordignon), 147 Reactions of dinuclear and polynuclear complexes. XVI. Chemistry of Hydrothermal synthesis hydrido-, thiolato-bridged complexes [Mo,Cp,(w-HXpp-SRXCO),] Solvothermal synthesis, molecular structures and spectroscopic char- (R = Me, Ph): Reactivity and electrochemical behaviour; crystal acterization of the cluster compounds (Ph ,P).,[Fe,Te,(CO),,] and structure of [Mo,Cp,(-SPh) {-o : n?-C(CH ,)=CHCH ,KCO), ] Cs[HFe ,Te(CO), ] (B.K. Das and M.G. Kanatzidis), | (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, Hydroxy K.W. Muir and D.S. Yufit), 181 Reactions of Ru,( ;-C, PPh, -PPh,XCO),, with functional phos- Diorganotin(IV) phines. X-ray structures of Ru.( u<-C, PPh, u-PPh, Xdppm)- (CO),, - CHC], Ru,( ws-C,H) p-PPh,),( u-P,N-PPh,C,- Synthesis, characterisation and X-ray crystal structures of diorgano- H,NH-2X u-COXCO),, Ru,{ z4-C,PPh,[Ru( 4-OHXC, P-2- tin(IV) complexes with 2-mercaptopyridine derivatives (M.D. Couce, G. Faraglia, U. Russo, L. Sindellari and G. Valle), 77 CHMeC,H ,PPh,-2CO),]}_ (u-PPh,XCO),, - CHCl, and Ru,( -H),{ us-PPh ,C,CHC(,PCPh, ,H-2) }( u-PPh, XCO), , Disulfide Preparation and properties of diruthenium complexes with bridging (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 disulfide and thiolate ligands [Cp* Ru( u-S, u-SR),RuCp* | (Cp* = n°-C;Me,, R=Pr' and PhCH,) (Y. Mizobe, M. Ho- somizu, S. Kuwata, J.-i. Kawabata and M. Hidai), 231 Imido complexes (THFMgNPh), as an imide transfer agent: synthesis of titanium and Diynes zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and A practical synthesis of ethynylferrocene from ferrocene carboxalde- P.P. Power), 173 hyde: structure of 1,4-diferrocenyl-1,3-butadiyne (J.-G. Rodri- guez, A. Ofiate, R.M. Martin-Villamil and I. Fonseca), 71 Iridium Pentamethylcyclopentadienyliridium(1II]) complexes containing ter- Electrochemistry tiary phosphorus chalcogenide ligands: crystal structure of Reactions of dinuclear and polynuclear complexes. X VI. Chemistry of [(n°CMe, )Ir{PO(OMe), }{n?(SPPh, ),CH,—S,S'}]BF, - 0.5Me,CO hydrido-, thiolato-bridged complexes [Mo,Cp,(u-HXp.-SRXCO), | (M. Valderrama and R. Contreras), 7 296 Subject Index of Volume 513 Iron K.W. Muir and D.S. Yufit), 181 Preparation of the alkynyl—hydride complexes MH(C=CR)- Structure and reactivity of (Dibenzo[b,e]fulvalene)Mo,(CO), (R.C. {PPh(OEt),}, of iron and ruthenium (G. Albertin, S. Antoniutti Kerber and B.R. Waldbaum), 277 and E. Bordignon), 147 Synthesis and reactions of [Mo(2,6-lutidineX 7-allyl)] derivatives (C.P. Solvothermal synthesis, molecular structures and spectroscopic char- Mehnert, A.N. Chernega and M.L.H. Green), 247 acterization of the cluster compounds (Ph, P),[Fe ,Te,(CO),,] and Mossbauer Cs[HFe ,Te(CO),] (B.K. Das and M.G. Kanatzidis), | Organotin(IV) polypyrazolylborates. IX. Tetrakis(4-methyl-1 H-pyra- zol-1-yl)borates. Characterisation, Méssbauer study and X-ray Kharasch reaction crystal structure of Cl,Sn( u-4-MePz), B(4-MePz) (G. Gioia Lob- Structure and reactivity of (Dibenzolb,e]fulvalene)Mo,(CO), (R.C. bia, P. Cecchi, C. Santini, S. Calogero, G. Valle and F.E. Wagner), Kerber and B.R. Waldbaum), 277 137 Synthesis, characterisation and X-ray crystal structures of diorgano- Lanthanum tin(IV) complexes with 2-mercaptopyridine derivatives (M.D. XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- Couce, G. Faraglia, U. Russo, L. Sindellari and G. Valle), 77 lanthanoid-Komplexe La(n?-C,H,),-1,5 Dioxan und Nd(n?- C,H,),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- Neodymium satoren fiir die stereospezifische Butadienpolymerisation (R. XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), neodym(III)-Komplexe als Katalysatoren fiir die stereospezifische 49 Butadienpolymerisation: Li[Nd(n*-C,H,),]- 1,5Dioxan, Li[Nd- Lithium (7-Cs;H;sXn°-C,H;);] - 2Dioxan und Li[Nd(°-C,Me,Xn?- Novel monoanionic di-N,N’-centred chelating ligands and their C, C,H,),]- 3Dimethylglykolether (R. Taube, S. Maiwald und J. and C, symmetrical zirconium complexes (B.-J. Deelman, P.B. Sieler), 37 Hitchcock, M.F. Lappert, H.-K. Lee and W.-P. Leung), 281 XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- Polymeric chains from [{Ph,SiOLi- THF),O},] and linear dicoordi- lanthanoid-Komplexe La(n*-C,H,),-°1,5 Dioxan und Nd(n?- nating nitrogen bases. Crystal X-ray structures of [{Ph,SiOLi),O - C,H,;),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- THF}, - 2DABCO], DABCO = 1,4-diazabicyclo{2.2.2]octane, and satoren fiir die stereospezifische Butadienpolymerisation (R. [{Ph, SiOLi),O - THF}, - 2{4,4'}-bipyridine] (M. Motevalli, D. Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), Shah and A.C. Sullivan), 239 49 Nitrile coordination Magnesium Coordination chemistry of mono- and di-nitriles in [Ru,(CO),,_, - (THFMgNPh), as an imide transfer agent: synthesis of titanium and (RCN), ]( mn = 1-3): influence of the CO/ nitrile ratio on fluxion- zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and ality (P. Grenouillet and C. De Bellefon), 155 P.P. Power), 173 NMR Manganese NMR-spektroskopische und strukturelle Charakterisierung der Tri- Synthesis and reactions of [(((7°)-2-acylaryl)-C,O)tetracarbonylman- iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. ganese]- tricarbonylchromium complexes: enhancement of di- Léw und W. Schwarz), 213 astereoselection during cyclopentaannulation (G.R. Clark, M.R. Synthesis, characterisation and X-ray crystal structures of diorgano- Metzler, G. Whitaker and P.D. Woodgate), 107 tin(IV) complexes with 2-mercaptopyridine derivatives (M.D. Mechanisms Couce, G. Faraglia, U. Russo, L. Sindellari and G. Valle), 77 Coordination chemistry of mono- and di-nitriles in [Ru,(CO),,_, - (RCN),,] (nm = 1-3): influence of the CO/ nitrile ratio on fluxion- ality (P. Grenouillet and C. De Bellefon), 155 Olefin—acetylide coupling Reactions of Ru,( 5-C, PPh,X -PPh, XCO),, with functional phos- Metal carbonyls phines. X-ray structures of Ru,( 5-C,PPh,X u-PPh, Xdppm)- Solvothermal synthesis, molecular structures and spectroscopic char- acterization of the cluster compounds (Ph,P),[Fe,Te,(CO),, ] and (CO),, - CHC], Ru,(m>5-C,H) u-PPh,),( u-P,N-PPh,C,- Cs[{HFe,Te(CO),] (B.K. Das and M.G. Kanatzidis), | H,NH-2 uw-COXKCO),,, Rugl w4-C,PPh,[Ru( u.-OHXC, P-2- CHMeC,H,PPh,-2XCO),]} (u-PPh,XCO),, - CHCl, and Metal clusters Solvothermal synthesis, molecular structures and spectroscopic char- Rus( w-H),{ ws-PPh,C,CHC(C,H,PPh,-2)}( u-PPh, XCO), , acterization of the cluster compounds (Ph, P),[Fe,Te,(CO),, ]a nd (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 Cs[HFe,Te(CO),] (B.K. Das and M.G. Kanatzidis), | Organoaluminium compounds . Metallasiloxane Cp*AIR, compounds (R = Me, Et, 'Bu): synthesis and structure of Polymeric chains from [{Ph,SiOLi-: THF),O},] and linear dicoordi- novel aluminium organyls with a pentamethylcyclopentadieny] nating nitrogen bases. Crystal X-ray structures of [{Ph,SiOLi),O - substituent as well as structure of analogous Cp’'AIR, compounds THF}, - 2DABCO], DABCO = 1,4-diazabicyclo{2.2.2]octane, and (Cp’ = Cp, MeCp; R = Me, Et) (M. Scherer and T. Kruck), 135 [{Ph,SiOLi-) T,HFO} , - 2(4,4’}-bipyridine] (M. Motevalli, D. Oxidative addition Shah and A.C. Sullivan), 239 Synthesis and molecular structure of the paramagnetic Co(II) bis(boryl) complex [Co(PMe,),(Bcat),] (cat = 1,2-0,C,H,) (C. Dai, G. Metal vapour synthesis Synthesis and reactions of [Mo(2,6-lutidineX 7-allyl)] derivatives (C.P. Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- Mehnert, A.N. Chernega and M.L.H. Green), 247 man), 273 Molybdeaum Reactions of dinuclear and polynuclear complexes. X VI. Chemistry of Paramagnetic hydrido-, thiolato-bridged complexes [Mo,Cp,(y-HX-SRXCO), | Synthesis and molecular structure of the paramagnetic Co(II) bis(boryl) (R = Me, Ph): Reactivity and electrochemical behaviour; crystal complex [Co(PMe,),(Bcat),] (cat = 1,2-0,C,H,) (C. Dai, G. structure of [Mo,Cp,(w-SPh) {p-o : n?-C(CH ,)=CHCH (CO), ] Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, man), 273 Subject Index of Volume 513 Pentamethylcyclopentadieny] ligand ' Potassium Cp*AIR, compounds (R = Me, Et, 'Bu): synthesis and structure of The decomposition reaction of the dialane radical anion [R,Al- novel aluminium organyls with a pentamethylcyclopentadienyl AIR,]~ in DME(IID): crystal structures of the aluminium glyco- substituent as well as structure of analogous Cp’AIR., compounds lates [R,AKOCH,),]K(DME) and R,AKOCH,),AKR)- (Cp’ = Cp, MeCp; R = Me, Et) (M. Scherer and T. Kruck), 135 (OCH,), AIR, (R = CH(SiMe,),) (W. Uhl, R. Gerding and A. PH-bond Vester), 163 [2 + 1]-Cycloadditions Preparation Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- Preparation of the alkynyl—hydride complexes MH(C=CR)- SSS e lisierte Phosphametallacyclen C;R (OC), W-PH(t-Bu)-X (R = H, {PPh(OEt),}, of iron and ruthenium (G. Albertin, S. Antoniutti Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Grin, and E. Bordignon), 147 U.-A. Hirth und M. Noltemeyer), 31 Protonation Preparation of the alkynyl-hydride complexes MH(C=CR)- Phosphametallacycles {PPh(OEt),}, of iron and ruthenium (G. Albertin, S. Antoniutti Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- aan tape. and E. Bordignon), 147 lisierte Phosphametallacyclen C;R (OC), W-PH(t-Bu)-X (R = H, Pyrazolylborates Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Grin, Organotin(IV) polypyrazolylborates. IX. Tetrakis(4-methyl-1 H-pyra- U.-A. Hirth und M. Noltemeyer), 31 zol-1-yl)borates. Characterisation, Méssbauer study and X-ray Phosphanide crystal structure of Cl,Sn( u-4-MePz),B(4-MePz) (G. Gioia Lob- NMR-spektroskopische und strukturelle Charakterisierung der Tri- bia, P. Cecchi, C. Santini, S. Calogero, G. Valle and F.E. Wagner), iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. 137 Léw und W. Schwarz), 213 Pyridyls Phosphenium complexes Ruthenium clusters with nitrogen ligands. V. Pyridyl ligands on Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- triruthenium cores. X-ray structures of Ru,( u-H),( u-NC;H,)>- eee T oe lisierte Phosphametallacyclen C;R ,(OC), W-PH(t-Bu)-X (R = H, (CO), and Ru,( 43-7?-PPhCH,PPh,) ( u-NC;H,XCO), (M.P. Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Griin, Cifuentes, M.G. Humphrey, B.W. Skelton and A.H. White), 201 U.-A. Hirth und M. Noltemeyer), 31 Phosphine Radical Reactions of Ru,( 45-C, PPh, u-PPh,XCO),, with functional phos- The decomposition reaction of the dialane radical anion [R,Al- phines. X-ray structures of Ru,( 5-C,PPh, u-PPh,Xdppm)- AIR,]~ in DME(II): crystal structures of the aluminium glyco- (CO),, - CHCl, Ru,( mu. -C,H u-PPh,),( u-P,N-PPh,C,- lates [R, A(OCH,) ,J K(DME) and R, AKOCH,),AKRXOCH,)>- H,NH-2X u-COXCO),5, Rugf{ w4-C,PPh,[Ru( u-OHXC, P-2- AIR, (R = CH(SiMe,),) (W. Uhl, R. Gerding and A. Vester), CHMeC,H ,PPh,-2XCO),]} (u-PPh,CO),, - CHCl, and 163 Ru,( u-H),{ w5-PPh,C,CHC(C,H,PPh,-2)}( u-PPh,XCO),, Rh (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 Steric effects in organometallic compounds. A '°>Rh NMR study of Synthesis and molecular structure of the paramagnetic Co(II) bis(bory]) alkylrhodoximes (F. Asaro, G. Costa, R. Dreos, G. Pellizer and complex [Co(PMe,),(Bcat),] (cat= 1,2-0,C,H,) (C. Dai, G. W. Von Philipsborn), 193 Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- '°°Rh NMR man), 273 Steric effects in organometallic compounds. A '°°Rh NMR study of Phosphonate complexes alkylrhodoximes (F. Asaro, G. Costa, R. Dreos, G. Pellizer and Pentamethylcyclopentadienyliridium(III) complexes containing ter- W. Von Philipsborn), 193 tiary phosphorus chalcogenide ligands: crystal structure of Ru [((n°C Me, )Ir{PO(OMe), }{n?(SPPh,, ),CH ,—S,S'}]BF, - 0.5Me,- Coordination chemistry of mono- and di-nitriles in [Ru,(CO),,_, - O (M. Valderrama and R. Contreras), 7 (RCN),,] (n = 1-3): influence of the CO/ nitrile ratio on fluxion- Phosphorus ality (P. Grenouillet and C. De Bellefon), 155 Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- Ruthenium eere e e ee lisierte Phosphametallacyclen C;R,(OC), W-PH(t-Bu)-X (R = H, High nuclearity ruthenium carbonyl cluster chemistry. IV. Reactivity Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Grin, of [Rujo(u-HXp.-CXCO),,]> towards trimethylphosphite or U.-A. Hirth und M. Noltemeyer), 31 bis(diphenylphosphino)acetylene; X-ray crystal structure of Platinum(I1) [PPh , [Ru ,o(u-HXp.-CXCO),,{P(OMe),},] (M.P. Cifuentes, Reaction products of CO with square-planar platinum(II)-(N,N- M.G. Humphrey and A.C. Willis), 85 chelate) complexes: synthesis and reactivity (V. De Felice, A. Preparation and properties of diruthenium complexes with bridging De Renzi, M.L. Ferrara and A. Panunzi), 97 disulfide and thiolate ligands [Cp* Ru( u-S,X u-SR),RuCp* ] Polymerization (Cp* = n°-C,Me,, R=Pr' and PhCH.) (Y. Mizobe, M. Ho- XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- somizu, S. Kuwata, J.-i. Kawabata and M. Hidai), 231 lanthanoid-Komplexe La(n?-C,H,);°1,5 Dioxan und Nd(n?- Reactions of Ru.( 4.-C, PPh, u-PPh, XCO),, with functional phos- C,H,),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- phines. X-ray structures of Ru,( ;-C,PPh, XX u-PPh, Xdppm)- satoren fiir die stereospezifische Butadienpolymerisation (R. (CO),, - CHC], Ru.(>5-C,H\ w-PPh,),( u-P,N-PPh,C,- Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), H,NH-2X u-COXCO),,, Ruf w4-C, PPh,[Ru( u-OHXC, P-2- CHMeC,H ,PPh,-2CO),]} (u-PPh,XCO),, - CHCl, and 49 Porphyrin Ru,( u-H),{ w.-PPh,C,CHC(C,H,PPh,-2)}( u-PPh, XCO),, Reaction of (POR)M(OAc), (M = Zr, Hf) with "BuLi and solid state (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 structure of [(TPP)Zr{ x.-OH),], J.L. Huhmann, J.Y. Corey, N.P. Ruthenium clusters with nitrogen ligands. V. Pyridyl ligands on Rath and C.F. Campana), 17 triruthenium cores. X-ray structures of Ru,( -H),( u-NC;H,)>- Subject Index of Volume 513 (CO), and Ru,( 4-7?-PPhCH,PPh,) (u-NC;H,XCO), (M.P. Thionetetrazoles Cifuentes, M.G. Humphrey, B.W. Skelton and A.H. White), 201 Tautomerism in coordinated 1-phenyl-5-thione-1,2,3,4-tetrazole (HL). Synthesis and crystal structure of [SnMe,(phen)L, ]( phen = 1,10- phenanthroline) (J. Bravo, M.B. Cordero, J.S. Casas, M.V. Silane Castafio, A. Sanchez and J. Sordo), 63 Reaction of (POR)M(OAc), (M = Zr, Hf) with "BuLi and solid state Tin structure of [(TPP)Zr( 4.-OH),]}, (J.L. Huhmann, J.Y. Corey, N.P. NMR-spektroskopische und strukturelle Charakterisierung der Tri- Rath and C.F. Campana), 17 iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. Silicon Léw und W. Schwarz), 213 Polymeric chains from [{Ph,SiOLi- THF),O},] and linear dicoordi- Organotin(IV) polypyrazolylborates. IX. Tetrakis(4-methyl-1 H-pyra- nating nitrogen bases. Crystal X-ray structures of [{Ph, SiOLi),O - zol-1-yl)borates. Characterisation, Méssbauer study and X-ray THF}, - 2DABCO], DABCO = 1,4-diazabicyclo{2.2.2Joctane, and crystal structure of Cl,Sn( u-4-MePz),B(4-MePz) (G. Gioia Lob- [{Ph,SiOLi),O - THF}, - 2{4,4’}-bipyridine] (M. Motevalli, D. bia, P. Cecchi, C. Santini, S. Calogero, G. Valle and F.E. Wagner), Shah and A.C. Sullivan), 239 137 Square-planar complexes Outer-sphere coordination of o-phenanthroline in bis{aquachloro- Reaction products of CO with square-planar platinum(II)-(N,N- tri( p-chloropheny])tin‘o-phenanthroline] (S.W. Ng and V.G. Ku- chelate) complexes: synthesis and reactivity (V. De Felice, A. mar Das), 105 De Renzi, M.L. Ferrara and A. Panunzi), 97 Tautomerism in coordinated 1|-phenyl-5|-, t2,h3,i4-otentreaz-ol e (HL). Stereoselection Synthesis and crystal structure of [SnMe,(phen)L, ] ( phen = 1,10- Synthesis and reactions of [(((°)-2-acylaryl)-C,O)tetracarbonylman- phenanthroline) (J. Bravo, M.B. Cordero, J.S. Casas, M.V. ganese]- tricarbonylchromium complexes: enhancement of di- Castafio, A. Sanchez and J. Sordo), 63 astereoselection during cyclopentaannulation (G.R. Clark, M.R. Titanium Metzler, G. Whitaker and P.D. Woodgate), 107 (THFMgNPh), as an imide transfer agent: synthesis of titanium and Stereospecific polymerization zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- P.P. Power), 173 neodym(III)-Komplexe als Katalysatoren fiir die stereospezifische Tri-iso-propylsilylphosphane Butadienpolymerisation: Li[Nd(n*-C,H,),] + 1,5Dioxan, Li[N- NMR-spektroskopische und strukturelle Charakterisierung der Tri- d(a-C;H;X7°-C,H;),] - 2Dioxan und Li[Nd(n°-C,Me,Xn°- iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. C,H,),]- 3Dimethylglykolether (R. Taube, S. Maiwald und J. Léw und W. Schwarz), 213 Sieler), 37 Trinuclear clusters Steric effects Coordination chemistry of mono- and di-nitriles in [Ru,(CO),,_,- Steric effects in organometallic compounds. A '°3Rh NMR study of (RCN),,] (n = 1-3): influence of the CO/ nitrile ratio on fluxion- alkylrhodoximes (F. Asaro, G. Costa, R. Dreos, G. Pellizer and ality (P. Grenouillet and C. De Bellefon), 155 W. Von Philipsborn), 193 Tungsten Synthesis Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- ny A practical synthesis of ethynylferrocene from ferrocene carboxalde- lisierte Phosphametallacyclen CR ,(OC), W-PH(t-Bu)-X (R = H, hyde: structure of 1,4-diferrocenyl-1,3-butadiyne (J.-G. Rodri- Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Grin, guez, A. Ofiate, R.M. Martin-Villamil and I. Fonseca), 71 U.-A. Hirth und M. Noltemeyer), 31 Reaction products of CO with square-planar platinum(II)-(N,N- Wittig reaction chelate) complexes: synthesis and reactivity (V. De Felice, A. A practical synthesis of ethynylferrocene from ferrocene carboxalde- De Renzi, M.L. Ferrara and A. Panunzi), 97 hyde: structure of 1,4-diferrocenyl-1,3-butadiyne (J.-G. Rodri- Synthesis of a novel planar hexaosmium carbonyl cluster: crystal guez, A. Ofiate, R.M. Martin-Villamil and I. Fonseca), 71 structure of [HOs,(CO)>9(u-n?-NC,H ,CH=CH)] (W.-Y. Wong and W.-T. Wong), 27 X-ray Organotin(IV) polypyrazolylborates. IX. Tetrakis(4-methyl-1 H-pyra- Tautomerism zol-1-yl)borates. Characterisation, Méssbauer study and X-ray Tautomerism in coordinated 1|-phenyl-5-thione-1,2,3,4-tetrazole (HL). crystal structure of Cl ,Sn( z-4-MePz),B(4-MePz) (G. Gioia Lob- Synthesis and crystal structure of [SnMe,(phen)L, ] (phen = 1,10- bia, P. Cecchi, C. Santini, S. Calogero, G. Valle and F.E. Wagner), phenanthroline) (J. Bravo, M.B. Cordero, J.S. Casas, M.V. 137 Castafio, A. Sanchez and J. Sordo), 63 X-ray crystal structure Tellurium A practical synthesis of ethynylferrocene from ferrocene carboxalde- Solvothermal synthesis, molecular structures and spectroscopic char- hyde: structure of 1,4-diferrocenyl-1,3-butadiyne (J.-G. Rodri- acterization of the cluster compounds (Ph, P),[Fe,Te,(CO), ,] and guez, A. Ofiate, R.M. Martin-Villamil and I. Fonseca), 71 Cs[HFe ,Te(CO),] (B.K. Das and M.G. Kanatzidis), | X-ray structure Tertiary chalcogenides NMR-spektroskopische und strukturelle Charakterisierung der Tri- Pentamethylcyclopentadienyliridium(III) complexes containing ter- iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. tiary phosphorus chalcogenide ligands: crystal structure of Léw und W. Schwarz), 213 [(n°C., Me. )Ir{PO(OMe), }{n?(SPPh,,);CH ,-S,S'}]BF, - 0.5Me,- Preparation and properties of diruthenium complexes with bridging CO (M. Valderrama and R. Contreras), 7 disulfide and thiolate ligands [Cp* Ru( u-S,X u-SR),RuCp* J Thiolate (Cp* = n°-C,Me,, R=Pr' and PhCH.) (Y. Mizobe, M. Ho- Preparation and properties of diruthenium complexes with bridging somizu, S. Kuwata, J.-i. Kawabata and M. Hidai), 231 disulfide and thiolate ligands [Cp* Ru( u-S, u-SR),RuCp* | Reactions of dinuclear and polynuclear complexes. XVI. Chemistry of (Cp* = n°-C,Me,, R=Pr' and PhCH,) (Y. Mizobe, M. Ho- hydrido-, thiolato-bridged complexes [Mo,Cp,(-HXp.-SRXCO), ] somizu, S. Kuwata, J.-i. Kawabata and M. Hidai), 231 (R = Me, Ph): Reactivity and electrochemical behaviour; crystal Subject Index of Volume 513 structure of [Mo,Cp,(y-SPh) {p-o : n?-C(CH ;)=CHCH (CO), ] Zirconium (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, Novel monoanionic di-N,N’-centred chelating ligands and their C, K.W. Muir and D.S. Yufit), 181 and C, symmetrical zirconium complexes (B.-J. Deelman, P.B. Synthesis, characterisation and X-ray crystal structures of diorgano- Hitchcock, M.F. Lappert, H.-K. Lee and W.-P. Leung), 281 tin(IV) complexes with 2-mercaptopyridine derivatives (M.D. Reaction of (POR)M(OAc), (M = Zr, Hf) with "BuLi and solid state Couce, G. Faraglia, U. Russo, L. Sindellari and G. Valle), 77 structure of [(TPP)Zr{ u-OH),], (J.L. Huhmann, J.Y. Corey, N.P. Tautomerism in coordinated 1-phenyl-5-thione-1,2,3,4-tetrazole (HL). Rath and C.F. Campana), 17 Synthesis and crystal structure of [SnMe,(phen)L, ] (phen = 1,10- (THFMgNPh), as an imide transfer agent: synthesis of titanium and phenanthroline) (J. Bravo, M.B. Cordero, J.S. Casas, M.V. zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and Castafio, A. Sanchez and J. Sordo), 63 P.P. Power), 173

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Preview Journal of Organometallic Chemistry 1996: Vol 513 Index

of OoBurAna l Chemistry ee! = matt LSEVIER Journal of Organometallic Chemistry 513 (1996) 291 Author Index of Volume 513 Adams, C.J., 255 Hemling, H., 49 Rath, N.P., 17 Albertin, G., 147 Hidai, M., 231 Rodriguez, J.-G., 71 Antoniutti, S., 147 Hirth, U.-A., 31 Russo, U., 77 Asaro, F., 193 Hitchcock, P.B., 281 Hosomizu, M., 231 Sanchez, A., 63 Bordignon, E., 147 Huhmann, J.L., 17 Santini, C., 137 Bravo, J., 63 Humphrey, M.G., 85, 201 Scherer, M., 135 Bruce, M.I., 255 Schollhammer, P., 181 Kanatzidis, M.G., | Schumann, H., 49 Calogero, S., 137 Kawabata, J.-I., 231 Schwarz, W., 213 Campana, C.F., 17 Kerber, R.C., 277 Shah, D., 239 Casas, J.S., 63 Kruck, T., 135 Sieler, J., 37 Castafio, M.V., 63 Kumar Das, V.G., 105 Sindellari, L., 77 Cecchi, P., 137 Kuwata, S., 231 Skelton, B.W., 201, 255 Chernega, A.N., 247 Sordo, J., 63 Lappert, M.F., 281 Cifuentes, M.P., 85, 201 Stringer, G., 273 Lee, H.-K., 281 Clark, G.R., 107 Sullivan, A.C., 239 Leung, W.-P., 281 Contreras, R., 7 Léw, R., 213 Cordero, M.B., 63 Talarmin, J., 181 Corey, J.Y., 17 Taube, R., 37, 49 Maiwald, S., 37, 49 Corrigan, J.F., 273 Taylor, N.J., 273 Malisch, W., 31 Costa, G., 193 Marder, T.B., 273 Couce, M.D., 77 Uhl, W., 163 Martin-Villamil, R.M., 71 Mehnert, C.P., 247 Dai, C., 273 Valderrama, M., 7 Metzler, M.R., 107 Das, B.K., | Valle, G., 77, 137 Mizobe, Y., 231 De Bellefon, C., 155 Vester, A., 163 Motevalli, M., 239 Deelman, B.-J., 281 Von Philipsborn, W., 193 Muir, K.W., 181 De Felice, V., 97 De Renzi, A., 97 Wagner, F.E., 137 Ng, S.W., 105 Dreos, R., 193 Waldbaum, B.R., 277 Noltemeyer, M., 31 Westerhausen, M., 213 Norman, N.C., 273 Faraglia, G., 77 Whitaker, G., 107 Ferrara, M.L., 97 Olmstead, M.M., 173 White, A.H., 201, 255 Fonseca, I., 71 Ojjate, A., 71 Willis, A.C., 85 Windisch, H., 49 Gerding, R., 163 Panunzi, A., 97 Wong, W.-T., 27 Gioia Lobbia, G., 137 Pellizer, G., 193 Wong, W.-Y., 27 Green, M.L.H., 247 Pétillon, F.Y., 181 Woodgate, P.D., 107 Grenouillet, P., 155 Poder-Guillou, S., 181 Grigsby, W.J., 173 Power, P.P., 173 Yufit, D.S., 181 Grin, K., 31 Elsevier Science S.A. ournal of¢ a metallic emistry Journal of Organometallic Chemistry 513 (1996) 293-299 Subject Index of Volume 513 Ab initio calculations Amine NMR-spektroskopische und strukturelle Charakterisierung der Tri- Reactions of Ru.( ;-C, PPh, u-PPh,XCO),, with functional phos- iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. phines. X-ray structures of Ru;( 5-C,PPh, u-PPh, Xdppm)- (CO),,- CHC], Ru( 5-C,H) u-PPh,)>( u-P,N-PPhC,- Léw und W. Schwarz), 213 H,NH-2X u-COXCO),o, Rug f s24-C, PPh, [Ru( u.-OHXC, P-2- Alkenyls CHMeC,H,PPh,-2(CO),]} (-PPh,XCO),) - CHCl, and Reactions of dinuclear and polynuclear complexes. X VI. Chemistry of Ru,( 4-H)>{ js-PPh,C,CHC,(PPCh ,,-H2) )( 4-PPh, (CO), , hydrido-, thiolato-bridged complexes [Mo,Cp,(-HX-SRXCO), ] (R = Me, Ph): Reactivity and electrochemical behaviour; crystal (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 structure of [Mo,Cp,(y-SPh) {p-o : n?-C(CH ,)=CHCH ,}(CO), ] n-Arene (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, Synthesis and reactions of [Mo(2,6-lutidineX 7-allyl)] derivatives (C.P. K.W. Muir and D.S. Yufit), 181 Mehnert, A.N. Chernega and M.L.H. Green), 247 Alkylidyne cluster Aza-allyl Synthesis of a novel planar hexaosmium carbonyl cluster: crystal Novel monoanionic di-N,N’-centred chelating ligands and their C, structure of [HOs,(CO),.(-n?-NC;H,CH=CH)] (W.-Y. Wong and C, symmetrical zirconium complexes (B.-J. Deelman, P.B. and W.-T. Wong), 27 Hitchcock, M.F. Lappert, H.-K. Lee and W.-P. Leung), 281 Alkylrhodoximes Steric effects in organometallic compounds. A ‘Rh NMR study of Bimetallic alkylrhodoximes (F. Asaro, G. Costa, R. Dreos, G. Pellizer and Structure and reactivity of (Dibenzo[b,e]fulvalene)Mo,(CO), (R.C. W. Von Philipsborn), 193 Kerber and B.R. Waldbaum), 277 Alkynyl compounds Bis(tri-iso-propylsilyl)phosphane Preparation of the alkynyl—hydride complexes MH(C=CR){PPh- NMR-spektroskopische und strukturelle Charakterisierung der Tri- (OEt),}, of iron and ruthenium (G. Albertin, S. Antoniutti and E. iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. Bordignon), 147 Léw und W. Schwarz), 213 Allyl Boron Synthesis and reactions of [Mo(2,6-lutidineX n-allyl)] derivatives (C.P. Organotin(IV) polypyrazolylborates. IX. Tetrakis(4-methyl-1 H-pyra- Mehnert, A.N. Chernega and M.L.H. Green), 247 zol-1-yl)borates. Characterisation, Méssbauer study and X-ray XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- crystal structure of Cl,Sn( u-4-MePz),B(4-MePz) (G. Gioia Lob- neodym(III)-Komplexe als Katalysatoren fiir die stereospezifische bia, P. Cecchi, C. Santini, S. Calogero, G. Valle and F.E. Wagner), Butadienpolymerisation: Li[Nd(n°-C,H,),]- 1,5Dioxan, Li[Nd 137 (7-C,H;Xn°*-C,Hs),] + 2Dioxan und Li[Nd(n°-C,Me,Xn°- Synthesis and molecular structure of the paramagnetic Co(ID bis(boryl) C,H,),]- 3Dimethylglykolether (R. Taube, S. Maiwald und J. complex [Co(PMe,),(Bcat),] (cat= 1,2-0,C,H,) (C. Dai, G. Sieler), 37 Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- man), 273 lanthanoid-Komplexe La(n’-C,H,;),;°1,5 Dioxan und Nd(n?- Boryl C,H,),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- Synthesis and molecular structure of the paramagnetic Co(II) bis(boryl) satoren fiir die stereospezifische Butadienpolymerisation (R. complex [Co(PMe,),(Bcat),] (cat= 1,2-0,C,H,) (C. Dai, G. Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- 49 man), 273 Aluminium—aluminium bond Bridging thiolate The decomposition reaction of the dialane radical anion [R,Al- Reactions of dinuclear and polynuclear complexes. X VI. Chemistry of AIR,]~ in DME(II): crystal structures of the aluminium glyco- hydrido-, thiolato-bridged complexes [Mo,Cp,(-HXp-SRXCO),] lates [R,AKOCH,),]K(DME) and R,AIKOCH,), Al(R)- (R = Me, Ph): Reactivity and electrochemical behaviour; crystal (OCH,), AIR, (R = CH(SiMe,),) (W. Uhl, R. Gerding and A. structure of [Mo,Cp,(y-SPh) {y-o : y?-C(CH ,)=CHCH ,}(CO), ] Vester), 163 (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, (Cyclopentadieny)laluminium complexes K.W. Muir and D.S. Yufit), 181 Cp* AIR, compounds (R = Me, Et, 'Bu): synthesis and structure of Butadiene novel aluminium organyls with a pentamethylcyclopentadienyl XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- substituent as well as structure of analogous Cp’'AIR, compounds neodym(III)-Komplexe als Katalysatoren fur die stereospezifische (Cp’ = Cp, MeCp; R = Me, Et) (M. Scherer and T. Kruck), 135 Butadienpolymerisation: Li[Nd(n°-C,H,),]- 1,5Dioxan, Li[Nd Elsevier Science S.A. Subject Index of Volume 513 (7-Cs;H;Xn?-C3H-s 2)Di3o]xa n und Li[Nd(n°-C;Me,Xn°- Chemical shifts C,H,);]- 3Dimethylglykolether (R. Taube, S. Maiwald und J. Steric effects in organometallic compounds. A '°3Rh NMR study of Sieler), 37 alkylrhodoximes (F. Asaro, G. Costa, R. Dreos, G. Pellizer and XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- W. Von Philipsborn), 193 lanthanoid-Komplexe La(n?-C,H,),-1,5 Dioxan und Nd(n?- Chromium C,H,),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- Synthesis and reactions of [(((n°)-2-acylaryl)-C,O)tetracarbonylman- satoren fiir die stereospezifische Butadienpolymerisation (R. ganese]- tricarbonylchromium complexes: enhancement of di- Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), astereoselection during cyclopentaannulation (G.R. Clark, M.R. 49 Metzler, G. Whitaker and P.D. Woodgate), 107 Cluster Calcium High nuclearity ruthenium carbonyl cluster chemistry. IV. Reactivity NMR-spektroskopische und strukturelle Charakterisierung der Tri- of [Rujo(u-HXp.-CXCO),,]” towards trimethylphosphite or iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. bis(diphenylphosphino)acetylene; X-ray crystal structure of Léw und W. Schwarz), 213 [PPh , [Ru ,o(u-HXp.-CXCO),,{P(OMe),},] (M.P. Cifuentes, Carbonyl M.G. Humphrey and A.C. Willis), 85 High nuclearity ruthenium carbonyl cluster chemistry. IV. Reactivity Reactions of Ru,( us5-C, PPh, u-PPh,XCO),, with functional phos- of [Ru,o(u-HXp.-CXCO),,]> towards trimethylphosphite or phines. X-ray structures of Ru,( u<;-C,PPh,X u-PPh, Xdppm)- (CO),,- CHCl, Ru,(5-C,H -PPh,),( u-P,N-PPh,C,- bis(diphenylphosphino)acetylene; X-ray crystal structure of H,NH-2X u-COXCO),5, Ru,4{ 44-C,PPh,[Ru( p-OHXC, P-2- [PPh , [Ru ,o(j-HXp.-CXCO),,{P(OMe),},] (M.P. Cifuentes, M.G. Humphrey and A.C. Willis), 85 CHMeC,H 4PPh,-2CO),]} (-PPh,XCO),. - CHCl, and Reactions of Ru,( ;-C,PPh, u-PPh,XCO),, with functional phos- Ru,( -H)»{ us-PPh,C ,CHC(C,H ,PPh,-2))( u-PPh, CO), , phines. X-ray structures of Ru.( u;-C,PPh, u-PPh,Xdppm)- (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 (CO),,- CHCl, Ru,(5-C,HX u-PPh,),( u-P,N-PPh,C,H,- Ruthenium clusters with nitrogen ligands. V. Pyridyl ligands on NH-2) u-COXKCO),,, Rug w4-C,PPh,[Ru( .-OHXC, P-2- triruthenium cores. X-ray structures of Ru,( u-H),( u-NC; CHMeC,H,PPh,-2XCO),]} (u-PPh,XCO),, - CHCl, and H,),(CO), and Ru,(3-7?-PPhCH,PPh,) ( u-NC,H,XCO), Ru.( w-H),{ u,PPh,C,CHC(C,H ,PPh,-2)}( u-PPh, CO), , (M.P. Cifuentes, M.G. Humphrey, B.W. Skelton and A.H. White), (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 201 Reaction products of CO with square-planar platinum(II)-(N,N- Cobalt chelate) complexes: synthesis and reactivity (V. De Felice, A. Synthesis and molecular structure of the paramagnetic Co(II) bis(boryl) De Renzi, M.L. Ferrara and A. Panunzi), 97 complex [Co(PMe,),(Bcat),] (cat= 1,2-0,C,H,) (C. Dai, G. Ruthenium clusters with nitrogen ligands. V. Pyridyl ligands on Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- triruthenium cores. X-ray structures of Ru,( u-H),( u-NC,- man), 273 H,),(CO), and Ru,(,-7’-PPhCH,PPh,) ( u-NC.H,)- Complexes (CO), (M.P. Cifuentes, M.G. Humphrey, B.W. Skelton and A.H. Tautomerism in coordinated |-phenyl-5-thione-1,2,3,4-tetrazole (HL). White), 201 Synthesis and crystal structure of [SnMe,(phen)L, ] ( phen = 1,10- Synthesis and reactions of [(((7°)-2-acylaryl)-C,O)tetracarbonylman- phenanthroline) (J. Bravo, M.B. Cordero, J.S. Casas, M.V. ganese]- tricarbonylchromium complexes: enhancement of di- Castafio, A. Sanchez and J. Sordo), 63 astereoselection during cyclopentaannulation (G.R. Clark, M.R. Crystal structure Metzler, G. Whitaker and P.D. Woodgate), 107 High nuclearity ruthenium carbonyl cluster chemistry. IV. Reactivity Carbonyl cluster of [Ru (u-HXp.-CXCO),,]”> towards trimethylphosphite or Synthesis of a novel planar hexaosmium carbonyl! cluster: crystal bis(diphenylphosphino)acetylene; X-ray crystal structure of structure of [HOs,(CO),.(u-n?-NC;H,CH=CH)] (W.-Y. Wong (PPh , [Ru ,o(u-HXp.-CXCO),,.{P(OMe),},] (M.P. Cifuentes, and W.-T. Wong), 27 M.G. Humphrey and A.C. Willis), 85 Catalysis Outer-sphere coordination of o-phenanthroline in bis{aquachloro- XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- tri( p-chloropheny))tin'o-phenanthroline] (S.W. Ng and V.G. Ku- neodym(III)-Komplexe als Katalysatoren fiir die stereospezifische mar Das), 105 Butadienpolymerisation: Li[Nd(n*-C,H,),]- 1,5Dioxan, Li[Nd Polymeric chains from [{Ph,SiOLi - THF),O},] and linear dicoordi- (7-C;H;Xn*-C,H,);]- 2Dioxan und Li[Nd(n°-C,Me,X7?- nating nitrogen bases. Crystal X-ray structures of [{Ph,SiOLi),O- C,H,),]- 3Dimethylglykolether (R. Taube, S. Maiwald und J. THF}, - 2DABCO], DABCO = 1,4-diazabicyclo[2.2.2]Joctane, and Sieler), 37 [{Ph,SiOLi-) T,HFO} , - 2{4,4’}-bipyridine] (M. Motevalli, D. XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- Shah and A.C. Sullivan), 239 lanthanoid-Komplexe La(n*-C,H,),°1,5 Dioxan und Nd(n?- Reactions of Ru,( 45-C, PPh, X u-PPh,XCO),, with functional phos- C,H,),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- phines. X-ray structures of Ru,( 5-C,PPh, u-PPh, Xdppm)- (CO),,- CHCl, Ru,(5-C,H) u-PPh,),( u-P,N-PPh,C,- satoren fiir die stereospezifische Butadienpolymerisation (R. Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), H,NH-2 p-COXCO),5, Ru, w4-PCPh ,,[R u( u-OHXC, P-2- CHMeC,H ,PPh,-2XCO),]} (-PPh,XCO),, - CHCl, and 49 Ru,( u-H),{ ws-PPh,C ,CHC(C,H,PPh ,-2)}( u-PPh, XCO), , Chalcogenides Solvothermal synthesis, molecular structures and spectroscopic char- (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 acterization of the cluster compounds (Ph, P),[Fe ,Te,(CO), ,] and Ruthenium clusters with nitrogen ligands. V. Pyridyl ligands on Cs{HFe ,Te(CO), ] (B.K. Das and M.G. Kanatzidis), | triruthenium cores. X-ray structures of Ru,( u-H),( u-NC,H,),- Chelating amide (CO), and Ru,( 4,-7?-PPhCH,PPh,) ( u-NC;H,XCO), (M.P. Novel monoanionic di-N,N’-centred chelating ligands and their C, Cifuentes, M.G. Humphrey, B.W. Skelton and A.H. White), 201 and C, symmetrical zirconium complexes (B.-J. Deelman, P.B. Synthesis and reactions of [(((n°)-2-acylaryl)-C,O)tetracarbonylman- Hitchcock, M.F. Lappert, H.-K. Lee and W.-P. Leung), 281 ganese]- tricarbonylchromium complexes: enhancement of di- Subject Index of Volume 513 295 astereoselection during cyclopentaannulation (G.R. Clark, M.R. (R = Me, Ph): Reactivity and electrochemical behaviour; crystal Metzler, G. Whitaker and P.D. Woodgate), 107 structure of [Mo,Cp,(y-SPh) {-o : n?-C(CH ,)=CHCH ,K(CO), ] Synthesis and reactions of [Mo(2,6-lutidineX n-allyl)] derivatives (C.P. (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, Mehnert, A.N. Chernega and M.L.H. Green), 247 K.W. Muir and D.S. Yufit), 181 Synthesis of a novel planar hexaosmium carbonyl cluster: crystal Esters of 2-mercaptopyridine-5-carboxylic acid structure of [HOs,(CO),(u-n?-NC,H ,CH=CH)] (W.-Y. Wong Synthesis, characterisation and X-ray crystal structures of diorgano- and W.-T. Wong), 27 tin(IV) complexes with 2-mercaptopyridine derivatives (M.D. (THFMgNPh), as an imide transfer agent: synthesis of titanium and Couce, G. Faraglia, U. Russo, L. Sindellari and G. Valle), 77 zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and P.P. Power), 173 Ferrocenes Cyclic voltammogram A practical synthesis of ethynylferrocene from ferrocene carboxalde- Preparation and properties of diruthenium complexes with bridging disulfide and thiolate ligands [Cp* Ru( u-S,\ u-SR),RuCp* | hyde: structure of 1,4-diferrocenyl-1,3-butadiyne (J.-G. Rodri- (Cp* = n°-C,Me,, R=Pr' and PhCH,) (Y. Mizobe, M. Ho- guez, A. Ofiate, R.M. Martin-Villamil and I. Fonseca), 71 somizu, S. Kuwata, J.-i. Kawabata and M. Hidai), 231 Five-coordinate complexes Reaction products of CO with square-planar platinum(ID-(N,N- [2 + 1]-Cycloadditions chelate) complexes: synthesis and reactivity (V. De Felice, A. Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- a De Renzi, M.L. Ferrara and A. Panunzi), 97 lisierte Phosphametallacyclen C;R ,(OC), W-PH(t-Bu)-X (R = H, Fluxionality Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Grin, Coordination chemistry of mono- and di-nitriles in [Ru,(CO),,_,- U.-A. Hirth und M. Noltemeyer), 31 (RCN),,] (n = 1-3): influence of the CO/ nitrile ratio on fluxion- Cyclopentaannulation ality (P. Grenouillet and C. De Bellefon), 155 Synthesis and reactions of [(((n°)-2-acylaryl)-C,O)tetracarbonylman- Fulvalene ganese]- tricarbonylchromium complexes: enhancement of di- Structure and reactivity of (Dibenzo[b,e]fulvalene)Mo,(CO), (R.C. astereoselection during cyclopentaannulation (G.R. Clark, M.R. Kerber and B.R. Waldbaum), 277 Metzler, G. Whitaker and P.D. Woodgate), 107 Cyclopentadieny] (THFMgNPh), as an imide transfer agent: synthesis of titanium and Glycolate zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and The decomposition reaction of the dialane radical anion [R,Al- P.P. Power), 173 AIR,|~ in DME(ID: crystal structures of the aluminium glyco- XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- lates [R,AMKOCH,),]K(DME) and R,AKOCH,),AKR)- neodym(III)-Komplexe als Katalysatoren fir die stereospezifische (OCH,) ,A IR, (R = CH(SiMe,),) (W. Uhl, R. Gerding and A. Butadienpolymerisation: Li[Nd(m*-C,H,),] - 1,5Dioxan, Vester), 163 Li[Nd(a7-C,H;)(m°-C,H,),] + 2Dioxan und _ Li[Nd(m°- C,Me,7*--C3 D,imeHthy,lg)lyk;ole]the r (R. Taube, S. Mai- wald und J. Sieler), 37 Hafnium Reaction of (POR)M(OAc), (M = Zr, Hf) with "BuLi and solid state Cyclopentadienyl complexes structure of [(TPP)Zr{ u-OH),], (J.L. Huhmann, J.Y. Corey, N.P. Pentamethylcyclopentadienyliridium(III) complexes containing ter- Rath and C.F. Campana), 17 tiary phosphorus chalcogenide ligands: crystal structure of [(n°C., Me, )Ir{POCOMe), }{n?(SPPh,),CH,—S,S'}]BF, - 0.5Me,- Hydrides CO (M. Valderrama and R. Contreras), 7 Preparation of the alkynyl—hydride complexes MH(C=CR)- {PPh(OEt),}, of iron and ruthenium (G. Albertin, S. Antoniutti Dinuclear complexes and E. Bordignon), 147 Reactions of dinuclear and polynuclear complexes. XVI. Chemistry of Hydrothermal synthesis hydrido-, thiolato-bridged complexes [Mo,Cp,(w-HXpp-SRXCO),] Solvothermal synthesis, molecular structures and spectroscopic char- (R = Me, Ph): Reactivity and electrochemical behaviour; crystal acterization of the cluster compounds (Ph ,P).,[Fe,Te,(CO),,] and structure of [Mo,Cp,(-SPh) {-o : n?-C(CH ,)=CHCH ,KCO), ] Cs[HFe ,Te(CO), ] (B.K. Das and M.G. Kanatzidis), | (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, Hydroxy K.W. Muir and D.S. Yufit), 181 Reactions of Ru,( ;-C, PPh, -PPh,XCO),, with functional phos- Diorganotin(IV) phines. X-ray structures of Ru.( u<-C, PPh, u-PPh, Xdppm)- (CO),, - CHC], Ru,( ws-C,H) p-PPh,),( u-P,N-PPh,C,- Synthesis, characterisation and X-ray crystal structures of diorgano- H,NH-2X u-COXCO),, Ru,{ z4-C,PPh,[Ru( 4-OHXC, P-2- tin(IV) complexes with 2-mercaptopyridine derivatives (M.D. Couce, G. Faraglia, U. Russo, L. Sindellari and G. Valle), 77 CHMeC,H ,PPh,-2CO),]}_ (u-PPh,XCO),, - CHCl, and Ru,( -H),{ us-PPh ,C,CHC(,PCPh, ,H-2) }( u-PPh, XCO), , Disulfide Preparation and properties of diruthenium complexes with bridging (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 disulfide and thiolate ligands [Cp* Ru( u-S, u-SR),RuCp* | (Cp* = n°-C;Me,, R=Pr' and PhCH,) (Y. Mizobe, M. Ho- somizu, S. Kuwata, J.-i. Kawabata and M. Hidai), 231 Imido complexes (THFMgNPh), as an imide transfer agent: synthesis of titanium and Diynes zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and A practical synthesis of ethynylferrocene from ferrocene carboxalde- P.P. Power), 173 hyde: structure of 1,4-diferrocenyl-1,3-butadiyne (J.-G. Rodri- guez, A. Ofiate, R.M. Martin-Villamil and I. Fonseca), 71 Iridium Pentamethylcyclopentadienyliridium(1II]) complexes containing ter- Electrochemistry tiary phosphorus chalcogenide ligands: crystal structure of Reactions of dinuclear and polynuclear complexes. X VI. Chemistry of [(n°CMe, )Ir{PO(OMe), }{n?(SPPh, ),CH,—S,S'}]BF, - 0.5Me,CO hydrido-, thiolato-bridged complexes [Mo,Cp,(u-HXp.-SRXCO), | (M. Valderrama and R. Contreras), 7 296 Subject Index of Volume 513 Iron K.W. Muir and D.S. Yufit), 181 Preparation of the alkynyl—hydride complexes MH(C=CR)- Structure and reactivity of (Dibenzo[b,e]fulvalene)Mo,(CO), (R.C. {PPh(OEt),}, of iron and ruthenium (G. Albertin, S. Antoniutti Kerber and B.R. Waldbaum), 277 and E. Bordignon), 147 Synthesis and reactions of [Mo(2,6-lutidineX 7-allyl)] derivatives (C.P. Solvothermal synthesis, molecular structures and spectroscopic char- Mehnert, A.N. Chernega and M.L.H. Green), 247 acterization of the cluster compounds (Ph, P),[Fe ,Te,(CO),,] and Mossbauer Cs[HFe ,Te(CO),] (B.K. Das and M.G. Kanatzidis), | Organotin(IV) polypyrazolylborates. IX. Tetrakis(4-methyl-1 H-pyra- zol-1-yl)borates. Characterisation, Méssbauer study and X-ray Kharasch reaction crystal structure of Cl,Sn( u-4-MePz), B(4-MePz) (G. Gioia Lob- Structure and reactivity of (Dibenzolb,e]fulvalene)Mo,(CO), (R.C. bia, P. Cecchi, C. Santini, S. Calogero, G. Valle and F.E. Wagner), Kerber and B.R. Waldbaum), 277 137 Synthesis, characterisation and X-ray crystal structures of diorgano- Lanthanum tin(IV) complexes with 2-mercaptopyridine derivatives (M.D. XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- Couce, G. Faraglia, U. Russo, L. Sindellari and G. Valle), 77 lanthanoid-Komplexe La(n?-C,H,),-1,5 Dioxan und Nd(n?- C,H,),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- Neodymium satoren fiir die stereospezifische Butadienpolymerisation (R. XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), neodym(III)-Komplexe als Katalysatoren fiir die stereospezifische 49 Butadienpolymerisation: Li[Nd(n*-C,H,),]- 1,5Dioxan, Li[Nd- Lithium (7-Cs;H;sXn°-C,H;);] - 2Dioxan und Li[Nd(°-C,Me,Xn?- Novel monoanionic di-N,N’-centred chelating ligands and their C, C,H,),]- 3Dimethylglykolether (R. Taube, S. Maiwald und J. and C, symmetrical zirconium complexes (B.-J. Deelman, P.B. Sieler), 37 Hitchcock, M.F. Lappert, H.-K. Lee and W.-P. Leung), 281 XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- Polymeric chains from [{Ph,SiOLi- THF),O},] and linear dicoordi- lanthanoid-Komplexe La(n*-C,H,),-°1,5 Dioxan und Nd(n?- nating nitrogen bases. Crystal X-ray structures of [{Ph,SiOLi),O - C,H,;),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- THF}, - 2DABCO], DABCO = 1,4-diazabicyclo{2.2.2]octane, and satoren fiir die stereospezifische Butadienpolymerisation (R. [{Ph, SiOLi),O - THF}, - 2{4,4'}-bipyridine] (M. Motevalli, D. Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), Shah and A.C. Sullivan), 239 49 Nitrile coordination Magnesium Coordination chemistry of mono- and di-nitriles in [Ru,(CO),,_, - (THFMgNPh), as an imide transfer agent: synthesis of titanium and (RCN), ]( mn = 1-3): influence of the CO/ nitrile ratio on fluxion- zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and ality (P. Grenouillet and C. De Bellefon), 155 P.P. Power), 173 NMR Manganese NMR-spektroskopische und strukturelle Charakterisierung der Tri- Synthesis and reactions of [(((7°)-2-acylaryl)-C,O)tetracarbonylman- iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. ganese]- tricarbonylchromium complexes: enhancement of di- Léw und W. Schwarz), 213 astereoselection during cyclopentaannulation (G.R. Clark, M.R. Synthesis, characterisation and X-ray crystal structures of diorgano- Metzler, G. Whitaker and P.D. Woodgate), 107 tin(IV) complexes with 2-mercaptopyridine derivatives (M.D. Mechanisms Couce, G. Faraglia, U. Russo, L. Sindellari and G. Valle), 77 Coordination chemistry of mono- and di-nitriles in [Ru,(CO),,_, - (RCN),,] (nm = 1-3): influence of the CO/ nitrile ratio on fluxion- ality (P. Grenouillet and C. De Bellefon), 155 Olefin—acetylide coupling Reactions of Ru,( 5-C, PPh,X -PPh, XCO),, with functional phos- Metal carbonyls phines. X-ray structures of Ru,( 5-C,PPh,X u-PPh, Xdppm)- Solvothermal synthesis, molecular structures and spectroscopic char- acterization of the cluster compounds (Ph,P),[Fe,Te,(CO),, ] and (CO),, - CHC], Ru,(m>5-C,H) u-PPh,),( u-P,N-PPh,C,- Cs[{HFe,Te(CO),] (B.K. Das and M.G. Kanatzidis), | H,NH-2 uw-COXKCO),,, Rugl w4-C,PPh,[Ru( u.-OHXC, P-2- CHMeC,H,PPh,-2XCO),]} (u-PPh,XCO),, - CHCl, and Metal clusters Solvothermal synthesis, molecular structures and spectroscopic char- Rus( w-H),{ ws-PPh,C,CHC(C,H,PPh,-2)}( u-PPh, XCO), , acterization of the cluster compounds (Ph, P),[Fe,Te,(CO),, ]a nd (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 Cs[HFe,Te(CO),] (B.K. Das and M.G. Kanatzidis), | Organoaluminium compounds . Metallasiloxane Cp*AIR, compounds (R = Me, Et, 'Bu): synthesis and structure of Polymeric chains from [{Ph,SiOLi-: THF),O},] and linear dicoordi- novel aluminium organyls with a pentamethylcyclopentadieny] nating nitrogen bases. Crystal X-ray structures of [{Ph,SiOLi),O - substituent as well as structure of analogous Cp’'AIR, compounds THF}, - 2DABCO], DABCO = 1,4-diazabicyclo{2.2.2]octane, and (Cp’ = Cp, MeCp; R = Me, Et) (M. Scherer and T. Kruck), 135 [{Ph,SiOLi-) T,HFO} , - 2(4,4’}-bipyridine] (M. Motevalli, D. Oxidative addition Shah and A.C. Sullivan), 239 Synthesis and molecular structure of the paramagnetic Co(II) bis(boryl) complex [Co(PMe,),(Bcat),] (cat = 1,2-0,C,H,) (C. Dai, G. Metal vapour synthesis Synthesis and reactions of [Mo(2,6-lutidineX 7-allyl)] derivatives (C.P. Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- Mehnert, A.N. Chernega and M.L.H. Green), 247 man), 273 Molybdeaum Reactions of dinuclear and polynuclear complexes. X VI. Chemistry of Paramagnetic hydrido-, thiolato-bridged complexes [Mo,Cp,(y-HX-SRXCO), | Synthesis and molecular structure of the paramagnetic Co(II) bis(boryl) (R = Me, Ph): Reactivity and electrochemical behaviour; crystal complex [Co(PMe,),(Bcat),] (cat = 1,2-0,C,H,) (C. Dai, G. structure of [Mo,Cp,(w-SPh) {p-o : n?-C(CH ,)=CHCH (CO), ] Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, man), 273 Subject Index of Volume 513 Pentamethylcyclopentadieny] ligand ' Potassium Cp*AIR, compounds (R = Me, Et, 'Bu): synthesis and structure of The decomposition reaction of the dialane radical anion [R,Al- novel aluminium organyls with a pentamethylcyclopentadienyl AIR,]~ in DME(IID): crystal structures of the aluminium glyco- substituent as well as structure of analogous Cp’AIR., compounds lates [R,AKOCH,),]K(DME) and R,AKOCH,),AKR)- (Cp’ = Cp, MeCp; R = Me, Et) (M. Scherer and T. Kruck), 135 (OCH,), AIR, (R = CH(SiMe,),) (W. Uhl, R. Gerding and A. PH-bond Vester), 163 [2 + 1]-Cycloadditions Preparation Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- Preparation of the alkynyl—hydride complexes MH(C=CR)- SSS e lisierte Phosphametallacyclen C;R (OC), W-PH(t-Bu)-X (R = H, {PPh(OEt),}, of iron and ruthenium (G. Albertin, S. Antoniutti Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Grin, and E. Bordignon), 147 U.-A. Hirth und M. Noltemeyer), 31 Protonation Preparation of the alkynyl-hydride complexes MH(C=CR)- Phosphametallacycles {PPh(OEt),}, of iron and ruthenium (G. Albertin, S. Antoniutti Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- aan tape. and E. Bordignon), 147 lisierte Phosphametallacyclen C;R (OC), W-PH(t-Bu)-X (R = H, Pyrazolylborates Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Grin, Organotin(IV) polypyrazolylborates. IX. Tetrakis(4-methyl-1 H-pyra- U.-A. Hirth und M. Noltemeyer), 31 zol-1-yl)borates. Characterisation, Méssbauer study and X-ray Phosphanide crystal structure of Cl,Sn( u-4-MePz),B(4-MePz) (G. Gioia Lob- NMR-spektroskopische und strukturelle Charakterisierung der Tri- bia, P. Cecchi, C. Santini, S. Calogero, G. Valle and F.E. Wagner), iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. 137 Léw und W. Schwarz), 213 Pyridyls Phosphenium complexes Ruthenium clusters with nitrogen ligands. V. Pyridyl ligands on Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- triruthenium cores. X-ray structures of Ru,( u-H),( u-NC;H,)>- eee T oe lisierte Phosphametallacyclen C;R ,(OC), W-PH(t-Bu)-X (R = H, (CO), and Ru,( 43-7?-PPhCH,PPh,) ( u-NC;H,XCO), (M.P. Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Griin, Cifuentes, M.G. Humphrey, B.W. Skelton and A.H. White), 201 U.-A. Hirth und M. Noltemeyer), 31 Phosphine Radical Reactions of Ru,( 45-C, PPh, u-PPh,XCO),, with functional phos- The decomposition reaction of the dialane radical anion [R,Al- phines. X-ray structures of Ru,( 5-C,PPh, u-PPh,Xdppm)- AIR,]~ in DME(II): crystal structures of the aluminium glyco- (CO),, - CHCl, Ru,( mu. -C,H u-PPh,),( u-P,N-PPh,C,- lates [R, A(OCH,) ,J K(DME) and R, AKOCH,),AKRXOCH,)>- H,NH-2X u-COXCO),5, Rugf{ w4-C,PPh,[Ru( u-OHXC, P-2- AIR, (R = CH(SiMe,),) (W. Uhl, R. Gerding and A. Vester), CHMeC,H ,PPh,-2XCO),]} (u-PPh,CO),, - CHCl, and 163 Ru,( u-H),{ w5-PPh,C,CHC(C,H,PPh,-2)}( u-PPh,XCO),, Rh (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 Steric effects in organometallic compounds. A '°>Rh NMR study of Synthesis and molecular structure of the paramagnetic Co(II) bis(bory]) alkylrhodoximes (F. Asaro, G. Costa, R. Dreos, G. Pellizer and complex [Co(PMe,),(Bcat),] (cat= 1,2-0,C,H,) (C. Dai, G. W. Von Philipsborn), 193 Stringer, J.F. Corrigan, N.J. Taylor, T.B. Marder and N.C. Nor- '°°Rh NMR man), 273 Steric effects in organometallic compounds. A '°°Rh NMR study of Phosphonate complexes alkylrhodoximes (F. Asaro, G. Costa, R. Dreos, G. Pellizer and Pentamethylcyclopentadienyliridium(III) complexes containing ter- W. Von Philipsborn), 193 tiary phosphorus chalcogenide ligands: crystal structure of Ru [((n°C Me, )Ir{PO(OMe), }{n?(SPPh,, ),CH ,—S,S'}]BF, - 0.5Me,- Coordination chemistry of mono- and di-nitriles in [Ru,(CO),,_, - O (M. Valderrama and R. Contreras), 7 (RCN),,] (n = 1-3): influence of the CO/ nitrile ratio on fluxion- Phosphorus ality (P. Grenouillet and C. De Bellefon), 155 Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- Ruthenium eere e e ee lisierte Phosphametallacyclen C;R,(OC), W-PH(t-Bu)-X (R = H, High nuclearity ruthenium carbonyl cluster chemistry. IV. Reactivity Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Grin, of [Rujo(u-HXp.-CXCO),,]> towards trimethylphosphite or U.-A. Hirth und M. Noltemeyer), 31 bis(diphenylphosphino)acetylene; X-ray crystal structure of Platinum(I1) [PPh , [Ru ,o(u-HXp.-CXCO),,{P(OMe),},] (M.P. Cifuentes, Reaction products of CO with square-planar platinum(II)-(N,N- M.G. Humphrey and A.C. Willis), 85 chelate) complexes: synthesis and reactivity (V. De Felice, A. Preparation and properties of diruthenium complexes with bridging De Renzi, M.L. Ferrara and A. Panunzi), 97 disulfide and thiolate ligands [Cp* Ru( u-S,X u-SR),RuCp* ] Polymerization (Cp* = n°-C,Me,, R=Pr' and PhCH.) (Y. Mizobe, M. Ho- XLVIII. Synthese und Struktur der ersten neutralen Tris(allyl)- somizu, S. Kuwata, J.-i. Kawabata and M. Hidai), 231 lanthanoid-Komplexe La(n?-C,H,);°1,5 Dioxan und Nd(n?- Reactions of Ru.( 4.-C, PPh, u-PPh, XCO),, with functional phos- C,H,),-Dioxan und ihre Eignung als ‘‘single site’’-Kataly- phines. X-ray structures of Ru,( ;-C,PPh, XX u-PPh, Xdppm)- satoren fiir die stereospezifische Butadienpolymerisation (R. (CO),, - CHC], Ru.(>5-C,H\ w-PPh,),( u-P,N-PPh,C,- Taube, H. Windisch, S. Maiwald, H. Hemling und H. Schumann), H,NH-2X u-COXCO),,, Ruf w4-C, PPh,[Ru( u-OHXC, P-2- CHMeC,H ,PPh,-2CO),]} (u-PPh,XCO),, - CHCl, and 49 Porphyrin Ru,( u-H),{ w.-PPh,C,CHC(C,H,PPh,-2)}( u-PPh, XCO),, Reaction of (POR)M(OAc), (M = Zr, Hf) with "BuLi and solid state (C.J. Adams, M.I. Bruce, B.W. Skelton and A.H. White), 255 structure of [(TPP)Zr{ x.-OH),], J.L. Huhmann, J.Y. Corey, N.P. Ruthenium clusters with nitrogen ligands. V. Pyridyl ligands on Rath and C.F. Campana), 17 triruthenium cores. X-ray structures of Ru,( -H),( u-NC;H,)>- Subject Index of Volume 513 (CO), and Ru,( 4-7?-PPhCH,PPh,) (u-NC;H,XCO), (M.P. Thionetetrazoles Cifuentes, M.G. Humphrey, B.W. Skelton and A.H. White), 201 Tautomerism in coordinated 1-phenyl-5-thione-1,2,3,4-tetrazole (HL). Synthesis and crystal structure of [SnMe,(phen)L, ]( phen = 1,10- phenanthroline) (J. Bravo, M.B. Cordero, J.S. Casas, M.V. Silane Castafio, A. Sanchez and J. Sordo), 63 Reaction of (POR)M(OAc), (M = Zr, Hf) with "BuLi and solid state Tin structure of [(TPP)Zr( 4.-OH),]}, (J.L. Huhmann, J.Y. Corey, N.P. NMR-spektroskopische und strukturelle Charakterisierung der Tri- Rath and C.F. Campana), 17 iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. Silicon Léw und W. Schwarz), 213 Polymeric chains from [{Ph,SiOLi- THF),O},] and linear dicoordi- Organotin(IV) polypyrazolylborates. IX. Tetrakis(4-methyl-1 H-pyra- nating nitrogen bases. Crystal X-ray structures of [{Ph, SiOLi),O - zol-1-yl)borates. Characterisation, Méssbauer study and X-ray THF}, - 2DABCO], DABCO = 1,4-diazabicyclo{2.2.2Joctane, and crystal structure of Cl,Sn( u-4-MePz),B(4-MePz) (G. Gioia Lob- [{Ph,SiOLi),O - THF}, - 2{4,4’}-bipyridine] (M. Motevalli, D. bia, P. Cecchi, C. Santini, S. Calogero, G. Valle and F.E. Wagner), Shah and A.C. Sullivan), 239 137 Square-planar complexes Outer-sphere coordination of o-phenanthroline in bis{aquachloro- Reaction products of CO with square-planar platinum(II)-(N,N- tri( p-chloropheny])tin‘o-phenanthroline] (S.W. Ng and V.G. Ku- chelate) complexes: synthesis and reactivity (V. De Felice, A. mar Das), 105 De Renzi, M.L. Ferrara and A. Panunzi), 97 Tautomerism in coordinated 1|-phenyl-5|-, t2,h3,i4-otentreaz-ol e (HL). Stereoselection Synthesis and crystal structure of [SnMe,(phen)L, ] ( phen = 1,10- Synthesis and reactions of [(((°)-2-acylaryl)-C,O)tetracarbonylman- phenanthroline) (J. Bravo, M.B. Cordero, J.S. Casas, M.V. ganese]- tricarbonylchromium complexes: enhancement of di- Castafio, A. Sanchez and J. Sordo), 63 astereoselection during cyclopentaannulation (G.R. Clark, M.R. Titanium Metzler, G. Whitaker and P.D. Woodgate), 107 (THFMgNPh), as an imide transfer agent: synthesis of titanium and Stereospecific polymerization zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and XLVII. Darstellung und Charakterisierung einiger anionischer Allyl- P.P. Power), 173 neodym(III)-Komplexe als Katalysatoren fiir die stereospezifische Tri-iso-propylsilylphosphane Butadienpolymerisation: Li[Nd(n*-C,H,),] + 1,5Dioxan, Li[N- NMR-spektroskopische und strukturelle Charakterisierung der Tri- d(a-C;H;X7°-C,H;),] - 2Dioxan und Li[Nd(n°-C,Me,Xn°- iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. C,H,),]- 3Dimethylglykolether (R. Taube, S. Maiwald und J. Léw und W. Schwarz), 213 Sieler), 37 Trinuclear clusters Steric effects Coordination chemistry of mono- and di-nitriles in [Ru,(CO),,_,- Steric effects in organometallic compounds. A '°3Rh NMR study of (RCN),,] (n = 1-3): influence of the CO/ nitrile ratio on fluxion- alkylrhodoximes (F. Asaro, G. Costa, R. Dreos, G. Pellizer and ality (P. Grenouillet and C. De Bellefon), 155 W. Von Philipsborn), 193 Tungsten Synthesis Phosphenium-Ubergangsmetallkomplexe. XXVIII. PH-funktiona- ny A practical synthesis of ethynylferrocene from ferrocene carboxalde- lisierte Phosphametallacyclen CR ,(OC), W-PH(t-Bu)-X (R = H, hyde: structure of 1,4-diferrocenyl-1,3-butadiyne (J.-G. Rodri- Me; X = S, Se, Te) mit Dreiringstruktur (W. Malisch, K. Grin, guez, A. Ofiate, R.M. Martin-Villamil and I. Fonseca), 71 U.-A. Hirth und M. Noltemeyer), 31 Reaction products of CO with square-planar platinum(II)-(N,N- Wittig reaction chelate) complexes: synthesis and reactivity (V. De Felice, A. A practical synthesis of ethynylferrocene from ferrocene carboxalde- De Renzi, M.L. Ferrara and A. Panunzi), 97 hyde: structure of 1,4-diferrocenyl-1,3-butadiyne (J.-G. Rodri- Synthesis of a novel planar hexaosmium carbonyl cluster: crystal guez, A. Ofiate, R.M. Martin-Villamil and I. Fonseca), 71 structure of [HOs,(CO)>9(u-n?-NC,H ,CH=CH)] (W.-Y. Wong and W.-T. Wong), 27 X-ray Organotin(IV) polypyrazolylborates. IX. Tetrakis(4-methyl-1 H-pyra- Tautomerism zol-1-yl)borates. Characterisation, Méssbauer study and X-ray Tautomerism in coordinated 1|-phenyl-5-thione-1,2,3,4-tetrazole (HL). crystal structure of Cl ,Sn( z-4-MePz),B(4-MePz) (G. Gioia Lob- Synthesis and crystal structure of [SnMe,(phen)L, ] (phen = 1,10- bia, P. Cecchi, C. Santini, S. Calogero, G. Valle and F.E. Wagner), phenanthroline) (J. Bravo, M.B. Cordero, J.S. Casas, M.V. 137 Castafio, A. Sanchez and J. Sordo), 63 X-ray crystal structure Tellurium A practical synthesis of ethynylferrocene from ferrocene carboxalde- Solvothermal synthesis, molecular structures and spectroscopic char- hyde: structure of 1,4-diferrocenyl-1,3-butadiyne (J.-G. Rodri- acterization of the cluster compounds (Ph, P),[Fe,Te,(CO), ,] and guez, A. Ofiate, R.M. Martin-Villamil and I. Fonseca), 71 Cs[HFe ,Te(CO),] (B.K. Das and M.G. Kanatzidis), | X-ray structure Tertiary chalcogenides NMR-spektroskopische und strukturelle Charakterisierung der Tri- Pentamethylcyclopentadienyliridium(III) complexes containing ter- iso-propylsilylphosphanide des Calciums (M. Westerhausen, R. tiary phosphorus chalcogenide ligands: crystal structure of Léw und W. Schwarz), 213 [(n°C., Me. )Ir{PO(OMe), }{n?(SPPh,,);CH ,-S,S'}]BF, - 0.5Me,- Preparation and properties of diruthenium complexes with bridging CO (M. Valderrama and R. Contreras), 7 disulfide and thiolate ligands [Cp* Ru( u-S,X u-SR),RuCp* J Thiolate (Cp* = n°-C,Me,, R=Pr' and PhCH.) (Y. Mizobe, M. Ho- Preparation and properties of diruthenium complexes with bridging somizu, S. Kuwata, J.-i. Kawabata and M. Hidai), 231 disulfide and thiolate ligands [Cp* Ru( u-S, u-SR),RuCp* | Reactions of dinuclear and polynuclear complexes. XVI. Chemistry of (Cp* = n°-C,Me,, R=Pr' and PhCH,) (Y. Mizobe, M. Ho- hydrido-, thiolato-bridged complexes [Mo,Cp,(-HXp.-SRXCO), ] somizu, S. Kuwata, J.-i. Kawabata and M. Hidai), 231 (R = Me, Ph): Reactivity and electrochemical behaviour; crystal Subject Index of Volume 513 structure of [Mo,Cp,(y-SPh) {p-o : n?-C(CH ;)=CHCH (CO), ] Zirconium (P. Schollhammer, F.Y. Pétillon, S. Poder-Guillou, J. Talarmin, Novel monoanionic di-N,N’-centred chelating ligands and their C, K.W. Muir and D.S. Yufit), 181 and C, symmetrical zirconium complexes (B.-J. Deelman, P.B. Synthesis, characterisation and X-ray crystal structures of diorgano- Hitchcock, M.F. Lappert, H.-K. Lee and W.-P. Leung), 281 tin(IV) complexes with 2-mercaptopyridine derivatives (M.D. Reaction of (POR)M(OAc), (M = Zr, Hf) with "BuLi and solid state Couce, G. Faraglia, U. Russo, L. Sindellari and G. Valle), 77 structure of [(TPP)Zr{ u-OH),], (J.L. Huhmann, J.Y. Corey, N.P. Tautomerism in coordinated 1-phenyl-5-thione-1,2,3,4-tetrazole (HL). Rath and C.F. Campana), 17 Synthesis and crystal structure of [SnMe,(phen)L, ] (phen = 1,10- (THFMgNPh), as an imide transfer agent: synthesis of titanium and phenanthroline) (J. Bravo, M.B. Cordero, J.S. Casas, M.V. zirconium imido complexes (W.J. Grigsby, M.M. Olmstead and Castafio, A. Sanchez and J. Sordo), 63 P.P. Power), 173

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