C27 JOURNAL OF ORGANOMETALLIC CHEMISTRY, VOL. 419 (1991) AUTHOR INDEX Abel, E.W., (419) 375 Floris, C., (419) 1 Laporterie, A., (419) 57 Aizpurua, J.-M., (419) Cl Fortier, S., (419) 403 Li, H.-j., (419) 245 Alcock, N.W., (419) C23 Fulwood, R., (419) 269 Liao, F.-L., (419) 325 Alt, H.G., (419) 101 Lin, Y., (419) 293 Andriamizaka, J.-D., (419) 57 Galamb, V., (419) 205 Lis, T., (419) 391 Arce, A.J., (419) 63 Gales, S.L., (419) C10 Lobkovsky, E.B., (419) 311 Arena, C.G., (419) 399 Gelli, G., (419) 1 Long, N.J., (419) 375 Giannoccaro, P., (419) 251 Lott, K.A., (419) 113 Baird, M.C., (419) 403 Glidewell, C., (419) 283 Machado, R., (419) 63 Barker, J., (419) C23 Gomez-Sal, P., (419) 77 MacHale, D., (419) C18 Bartik, T., (419) 205 Green, J.C., (419) 27 Mahmoud, K.A., (419) 101 Batsanov, A.S., (419) 277 Greene, T.M., (419) 151 Battaglia, G., (419) 399 Manning, A.R., (419) C18 Grelier, S., (419) Cl Manuel, G., (419) 57 Belsky, V.K., (419) 299, 311 Gun’ko, Y.K., (419) 299 Martin, A., (419) 77 Benedetti, A., (419) 205 Mascetti, J., (419) 113 Bitterwolf, T.E., (419) 113 Haasz, F., (419) 205 Mashima, K., (419) 181 Blacker, N.C., (419) C23 Happ, B., (419) 205 Mastrorilli, P., (419) 251 Brown, S.J., (419) 403 Heim, B., (419) 43 McArdle, P., (419) C18 Bulychev, B.M., (419) 299, 311 Herberhold, M., (419) 85 Mehta, V.D., (419) 9 Hirva, P., (419) 193 Melis, S., (419) 1 Cabiddu, S., (419) 1 Hooker, R.H., (419) 101 Mena, M., (419) 77 Carreno, R., (419) 163 Howard, P.W., (419) C14 Cavell, K.J., (419) 259 Huang, J., (419) 337 Nagy, A., (419) 27 Chattopadhyay, T.K., (419) 277 Huang, Y.-Z., (419) 337 Nobile, C.F., (419) 251 Chelain, E., (419) CS Huttner, G., (419) 43 Cheng, Y., (419) 293 Hwu, C.-C., (419) 341 Orrell, K.G., (419) 375 Cooke, K.M., (419) 171 Osborne, A.G., (419) 375 Corriu, R.J.P., (419) 9 Jeannin, Y., (419) 43 Couret, C., (419) 57 Jiang, H.-X., (419) 337 Pakkanen, T.A., (419) 193, 219 Cunningham, D., (419) C18 Jin, H., (419) 259 Pakkanen, T.T., (419) 219 Palomo, C., (419) Cl Daran, J.C., (419) 43, C5 Kaim, W., (419) 233 Palyi, G., (419) 205 Davidson, J.L., (419) 137 Kaitner, B., (419) 283 Parker, D., (419) 269 Deeming, A.J., (419) 63 Kallinen, K., (419) 219 Parlier, A., (419) C5 De Sanctis, Y., (419) 63 Kaltner, B., (419) 269 Pauson, P.L., (419) 383 Downs, A.J., (419) 151 Kee, T.P., (419) 171 Pennington, W.T., (419) C10 Dunn, J.A., (419) 383 Kelland, M.A., (419) 127 Picard, J.-P., (419) Cl Dunogués, J., (419) Cl Knjazhanski, S.Y., (419) 311 Pidrko, A., (419) 357 Kolis, J.W., (419) C10 Poli, R., (419) 127 Eber, B., (419) 43 Kozima, S., (419) 181 Pursiainen, J., (419) 193, 219 Emmerich, C., (419) 43 Kriimm!ing, T., (419) 205 Ravasio, N., (419) 251 Escudié, J., (419) 57 Kumar, A.K., (419) 277 Regitz, M., (419) 57 Faraone, F., (419) 399 Ladwig, M., (419) 233 Renaud, E., (419) 403 Fattuoni, C., (419) 1 Langton, A.L., (419) 171 Rest, A.J., (419) 101, 113 Ferguson, G., (419) 269, 283 Lanneau, G.F., (419) 9 Riera, V., (419) 163 C28 Rivas, C., (419) 63 Smith, S., (419) 283 Vaissermann, J., (419) C5 Rossi, S., (419) 219 Soloveichik, G.L., (419) 299, Rotondo, E., (419) 399 311 Wallbridge, M.G.H., (419) C23 Roy, A., (419) 277 Somlyai-Haasz, J., (419) 205 Wang, S.-L., (419) 325 Royo, P., (419) 77 Stephenson, G.R., (419) C14 Wang, Y.-P., (419) 325 Rudler, H., (419) C5 Struchkov, Yu.T., (419) 277 Wood, M.A.K., (419) 151 Ruiz, M.A., (419) 163 Sutherland, R.G., (419) 357 Russell, R.B., (419) 403 Szepes, L., (419) 27 Yamaguchi, R., (419) 181 Szymanska-Buzar, T., (419) 151 Yang, Y.-H., (419) 325 Sakai, N., (419) 181 Yeh, M.-C.P., (419) 341 Schrepfermann, M., (419) 85 Takaya, H., (419) 181 Serrano, R., (419) 77 Taylor, $.C., (419) C14 Zanathy, L., (419) 27 Shamuratov, E.B., (419) 277 Thornton-Pett, M., (419) 171 Zhang, C., (419) 357 Shen, Q., (419) 293 Trzeciak, A.M., (419) 391 Zidtkowski, J.J., (419) 391 Sik, V., (419) 375 Turnbull, M.M., (419) 245 Zucchi, C., (419) 205 C29 JOURNAL OF ORGANOMETALLIC CHEMISTRY, VOL. 419 (1991) SUBJECT INDEX Aluminium Coordinationally oversaturated metallocene derivatives, crystal and molecular structure of [(n°- C H.),Sm(z ,-H)],[(A4IH,: -N(HC,H).),,] , and [(m°-CH,'Bu),Sm),- (4 5-H)u4--H){, (Alu(n ,- H),-Me,NC,H,NMe,] complexes (V.K. Belsky, Y.K. Gun’ko, B.M. Bulychev and G.L. Solo- veichik), (419) 299 Homo- and heteronuclear hydrido lutetiecene complexes with bulky 1,3-di(tert-butyl)cyclopentadienyl (C,H,'Bu,) ligands, molecular structure of [(‘Bu,C;H,)LuH],[AIH,-Et,O),[AIH,], (S.Y. Knjazhanski, E.B. Lobkovsky, B.M. Bulychev, V.K. Belsky and G.L. Soloveichik), (419) 311 Antimony Group 15 organometallics, high metal coordination numbers in; crystal structures of triphenylbismuth- bis(trifluoroacetate) and triphenylantimonybis(trifluoroacetate) (G. Ferguson, B. Kaitner, C. Glidewell and S. Smith), (419) 283 Bismuth Group 15 organometallics, high metal coordination numbers in; crystal structures of triphenylbismuth- bis(trifluoroacetate) and triphenylantimonybis(trifluoroacetate) (G. Ferguson, B. Kaitner, C. Glidewell and S. Smith), (419) 283 Chromium Enaminoketene and arenetricarbonyl nitrogen ylid chromium complexes, successive formation during intramolecular alkyne insertions into aminocarbene complexes (E. Chelain, A. Parlier, H. Rudler, J.C. Daran and J. Vaissermann), (419) CS (7°-Cyclopentadieny|)tricarbonylmethylchromium, photochemistry in gas matrices and polymer films at 12-298 K; infrared spectroscopic evidence for reversible carbon monoxide ejection and a-H elimination from the methyl group (R.H. Hooker, K.A. Mahmoud, A.J. Rest and H.G. Alt), (419) 101 Group VI metal carbonyls, (m°-C,H,)Cr(CO),, (n°-C;H.)Mn(CO),, (n°-CH ,C;H,)Mn(CO), and (n°-C.H.)Re(CO),, photolysis in Nujol at 77 K (T.E. Bitterwolf, K.A. Lott, A.J. Rest and J. Mascetti), (419) 113 [m°4(C,H ,COOCH ,)JCr(NO),L (L=Cl, 1, CH,), syntheses and spectra of; crystal structures of [n°4(C;H,COOCH ,)JCr(NO),L (L = Cl, 1) CY.-P. Wang, Y.-H. Yang, S.-L. Wang and F.-L. Liao), (419) 325 Tricarbonyl(benzene chromium and ferrocene containing unsaturated amides and nitriles, preparation of (J. Huang, H.-X. Jiang and Y.-Z. Huang), (419) 337 Cobalt [RuCo,H(CO),,], disordered crystal structure of (J. Pursiainen, P. Hirva and T.A. Pakkanen), (419) 193 Alkylcobalt carbonyls, ligand-assisted carbonylation—decarbonylation reactions of (J. Somlyai-Haasz, F. Haasz, V. Galamb, A. Benedetti, C. Zucchi, G. Palyi, T. Krimmling, B. Happ and T. Bartik), (419) 205 Some chiral alkyne-cobalt complexes (J.A. Dunn and P.L. Pauson), (419) 383 Gadolinium Methylbis(t-butyl-cyclopentnaedoidyemniyulm and -gadolinium, preparation and molecular structure of (Q. Shen, Y. Cheng and Y. Lin), (419) 293 ‘ C30 Gallium Mono- and di-methyl gallium tetraaza macrocycles [MeGa(C,,H,,N,)] and [Me,Ga(C,,H,,N,)j, synthesis of; molecular structure of the dimethyl derivative (N.W. Alcock, N.C. Blacker, M.G.H. Wallbridge and J. Barker), (419) C23 Germanium A new spirogermole: its synthesis, and some aspects of its reactivity (J.-D. Andriamizaka, C. Couret, J. Escudié, A. Laporterie, G. Manuel and M. Regitz), (419) 57 Iron Opening of cluster frameworks, increase in skeletal electrons via amino substituents (B. Eber, G. Huttner, C. Emmerich, J.C. Daran, B. Heim and Y. Jeannin), (419) 43 Tricarbonyliron complex of tricyclo[5.3.1.0*” Jundeca-2,5-diene, a strongly homo-conjugated nonparallel 1,4-diene; preparation, structure, and reaction of (N. Sakai, K. Mashima, H. Takaya, R. Yamaguchi and S. Kozima), (419) 181 Alkyl-Fp [Fp =(C;H.)Fe(CO),] complexes, preparation via organometallic reagents; reactions of RMgX and RLi with Fp-I and Fp-THF* BF, (H.-j. Li and M.M. Turnbull), (419) 245 Tricarbonyl(benzene)chromium and ferrocene containing unsaturated amides and nitriles, preparation of (J. Huang, H.-X. Jiang and Y.-Z. Huang), (419) 337 Tricarbonyl( y',n?-but-3-en-1-yDiron(0) anion complexes, bromination and alkylation of (M.-C.P. Yeh and C.-C. Hwu), (419) 341 Cyclopentadienyliron-mediated introduction of functionalized alkyl or alkynyl groups to arenes in an addition—demetallation sequence (R.G. Sutherland, C. Zhang and A. Pidrko), (419) 357 Tricarbonyliron complexes, regioselective access to; controlled preparation and reactions of trifluo- romethyl-substituted complexes (G.R. Stephenson, P.W. Howard and S.C. Taylor), (419) C14 [((m°-C..Me,)Fe(CO),|[BF,], direct observation of ion pair formation in dichloromethane solution and the crystal structure of (P. McArdle, D. MacHale, D. Cunningham and A.R. Manning), (419) C18 Lithium (Alkylthio)fluorobenzenes, regioselective metalation of (S. Cabiddu, C. Fattuoni, C. Floris, G. Gelli and S. Melis), (419) 1 Lutetium Homo- and heteronuclear hydrido lutetiecene complexes with bulky 1,3-di(tert-butyl)cyclopentadieny| (C;H,'Bu,) ligands, molecular structure of [(‘Bu,C;H,)LuH),[AIH,-Et,O],[AIH,], (S.Y. Knjazhanski, E.B. Lobkovsky, B.M. Bulychev, V.K. Belsky and G.L. Soloveichik), (419) 311 Manganese Group VI metal carbonyls, (m°-C,H,)Cr(CO),, (m°-C;Hs)Mn(CO),, (m°-CH,C,;H,)Mn(CO), and (n°-C;H,)Re(CO),, photolysis in Nujol at 77 K (T.E. Bitterwolf, K.A. Lott, A.J. Rest and J. Mascetti), (419) 113 Unsaturated dihydrides [Mn .(u-H)(CO),(u-L,)] (L, = (EtO), POP(OEt),, Ph, PCH , PPh,), reactions with phosphines containing P—H bonds (R. Carreno, V. Riera and M.A. Ruiz), (419) 163 Silylphosphinites and their complexation to manganese, crystal structure of cis-MnBr(CO),[P(4- CH ,C,H,),OSiMe,] (K.M. Cooke, T.P. Kee, A.L. Langton and M. Thornton-Pett), (419) 171 Metallocenes Homo- and heteronuclear hydrido lutetiecene complexes with bulky 1,3-di(tert-butyl)cyclopentadienyl (C;H,'Bu,) ligands, molecular structure of [(‘Bu,C;H,)LuH),[AIH,-Et,O],[AIH,], (S.Y. Knjazhanski, E.B. Lobkovsky, B.M. Bulychev, V.K. Belsky and G.L. Soloveichik), (419) 311 Tricarbonyl(benzene)chromium and ferrocene containing unsaturated amides and nitriles, preparation of (J. Huang, H.-X. Jiang and Y.-Z. Huang), (419) 337 C31 Molybdenum Group VI metal carbonyls, (7°-C,H,)Cr(CO);, (7°-C;H,)Mn(CO),, (n°-CH,C;H,)Mn(CO), and (n°-C;H,)Re(CO),, photolysis in Nujol at 77 K (T.E. Bitterwolf, K.A. Lott, AJ. Rest and J. Mascetti), (419) 113 Cyclopentadienyltrichloromolybdenum(IV), synthesis, characterization, and reactivity of; X-ray struc- ture of CpMoCl,[P(OCH ,),CEt], (Cp = n°-C;H.) (R. Poli and M.A. Kelland), (419) 127 Alkyne, cyclobutadiene and cyclopentadienone complexes of molybdenum and tungsten (J.L. Davidson), (419) 137 Organometallic compounds, oxidation with polychalcogenides; preparation and structure of ((Me,;C,)Mo(S,XS,CO)]~ containing a dithiocarbonate ligand (S.L. Gales, W.T. Pennington and J.W. Kolis), (419) C10 Neodymium Methylbis(t-butyl-cyclopentadienyl)neodymium and -gadolinium, preparation and molecular structure of (Q. Shen, Y. Cheng and Y. Lin), (419) 293 Nickel Oxidative carbonylation of aliphatic amines catalysed by nickel-complexes (P. Giannoccaro, C.F. Nobile, P. Mastrorilli and N. Ravasio), (419) 251 Osmium Trisulphur- and triselenium-bridged [3}metallocenophanes, comparison of the energy barriers to bridge reversal in (E.W. Abel, N.J. Long, K.G. Orrell, A.G. Osborne and V. Sik), (419) 375 Palladium o-Alkyl diketonato and monothio B-diketonato complexes of platinum(II) and palladium(I), synthesis of (H. Jin and K.J. Cavell), (419) 259 Phosphorus Opening of cluster frameworks, increase in skeletal electrons via amino substituents (B. Eber, G. Huttner, C. Emmerich, J.C. Daran, B. Heim and Y. Jeannin), (419) 43 New family of water-soluble tertiary phosphine ligands and their rhodium(1) complexes, synthesis of; olefin hydrogenation in aqueous and biphasic media (E. Renaud, R.B. Russell, S. Fortier, S.J. Brown and M.C. Baird), (419) 403 Platinum Chiral derivatising agent n*-ethene platinum-DIOP, crystal structure and further applications of (R. Fulwood, D. Parker, G. Ferguson and B. Kaltner), (419) 269 Rhenium Group VI metal carbonyls, (m°-C,H,)Cr(CO);, (m°-CsHs)Mn(CO),, (n°-CH,C;H,)Mn(CO), and (m°-C;H,)Re(CO),, photolysis in Nujol at 77 K (T.E. Bitterwolf, K.A. Lott, AJ. Rest and J. Mascetti), (419) 113 Rhodium Dimethylsulfide derivatives of [Rh,(CO),,], crystal structures of [Rh,(CO),,(SMe,)] and [Rh,(CO),(SMe,),] (S. Rossi, K. Kallinen, J. Pursiainen, T.T. Pakkanen and T.A. Pakkanen), (419) 219 Isomeric bidiazine complexes [((C;Me,)CIRh(bdz)]* and (C;Me,)Rh(bdz), spectroscopic and electro- chemical properties of; their relevance to the catalysis of the 2 H* — H, reaction by 2,2’-bipyridine analogues (M. Ladwig and W. Kaim), (419) 233 RhCKCOXP,R) ,, substitution of CO by picolines and amines in; synthesis and crystal structure of cis-RhCK(3-pic{P(OPh),}, (A.M. Trzeciak, J.J. Zi6tkowski and T. Lis), (419) 391 C32 Rh! square planar derivative, fast olefin site interchange of cycloocta-1,5-diene in (E. Rotondo, G. Battaglia, C.G. Arena and F. Faraone), (419) 399 New family of water-soluble tertiary phosphine ligands and their rhodium(1) complexes, synthesis of; olefin hydrogenation in aqueous and biphasic media (E. Renaud, R.B. Russell, S. Fortier, S.J. Brown and M.C. Baird), (419) 403 Ruthenium Selenium and tellurium atoms from selenophene and tellurophene by reaction with trinuclear iron, ruthenium, and osmium clusters, extrusion of; crystal structures of [Os,(u-HMy,-SeXu,- C,H,XCO),,)] and of [Ru,(u 4-Se)u-C,H,XCO),,] (AJ. Arce, R. Machado, C. Rivas, Y. De Sanc- tis and A.J. Deeming), (419) 63 [RuCo,H(CO),,], disordered crystal structure of (J. Pursiainen, P. Hirva and T.A. Pakkanen), (419) 193 Trisulphur- and triselenium-bridged [3}metallocenophanes, comparison of the energy barriers to bridge reversal in (E.W. Abel, N.J. Long, K.G. Orrell, A.G. Osborne and V. Sik), (419) 375 Samarium Coordinationally oversaturated metallocene derivatives, crystal and molecular structure of [(°- C sH.<),Sm(y5,-H-), HA)IH:] N,(C[,H(.)u;] , and [((m°-C,H,'Bu),Sm],- (45-H)u3--H){, (Al(un >- H),-Me,NC,H,NMe,] complexes (V.K. Belsky, Y.K. Gun’ko, B.M. Bulychev and G.L. Solove- ichik), (419) 299 Selenium Selenium and tellurium atoms from selenophene and tellurophene by reaction with trinuclear iron, ruthenium, and osmium clusters, extrusion of; crystal structures of [Os,(upy-4 -SHeXXp, - C,H,XCO),,] and of [Ru,(u4-Se)u-C,H,XCO),,] (AJ. Arce, R. Machado, C. Rivas, Y. De Sanc- tis and A.J. Deeming), (419) 63 Silicon Heterocumulenes, aminosilylation of; intramolecular decomposition of their silyl-functionalized adducts (R.J.P. Corriu, G.F. Lanneau and V.D. Mehta), (419) 9 Aminosilanes, Hel and Hell photoelectron spectroscopic investigation of substituent effects in (A. Nagy, J.C. Green, L. Szepes and L. Zanathy), (419) 27 Opening of cluster frameworks, increase in skeletal electrons via amino substituents (B. Eber, G. Huttner, C. Emmerich, J.C. Daran, B. Heim and Y. Jeannin), (419) 43 Bis(trimethylsily))methylamine, handy preparation of (J.-P. Picard, S. Grelier, J. Dunogués, J.-M. Aizpurua and C. Palomo), (419) Cl Silylphosphinites and their complexation to manganese, crystal structure of cis-MnBr(CO),[P(4- CH ,C,H,),OSiMe,] (K.M. Cooke, T.P. Kee, A.L. Langton and M. Thornton-Pett), (419) 171 Tellurium Selenium and tellurium atoms from selenophene and tellurophene by reaction with trinuclear iron, ruthenium, and osmium clusters, extrusion of; crystal structures of [Os,(u-HXy,-SeXp,- C,H,XCO),))] and of [Ru4(y4-Se)u-C,H,XCO),,] (A.J. Arce, R. Machado, C. Rivas, Y. De Sanc- tis and A.J. Deeming), (419) 63 Tin Me,SnCl,-(2-MeOC,H,N=CHC,<H,N-2), synthesis and crystal structure of (T.K. Chattopadhyay, A.K. Kumar, A. Roy, A.S. Batsanov, E.B. Shamuratov and Yu.T. Struchkov), (419) 277 Titanium Monopentamethylcyclopentadienyltitanium(1V) halo-alkoxides, alkyl-alkoxides and acetylacetonates (P. Gomez-Sal, A. Martin, M. Mena, P. Royo and R. Serrano), (419) 77 C33 Tungsten Group VI metal carbonyls, (n°-C,H,)Cr(CO),, (m°-C;Hs)Mn(CO),, (7°-CH,C;H,)Mn(CO), and (n°-C;H,)Re(CO),, photolysis in Nujol at 77 K (T.E. Bitterwolf, K.A. Lott, A.J. Rest and J. Mascetti), (419) 113 Alkyne, cyclobutadiene and cyclopentadienone complexes of molybdenum and tungsten (J.L. Davidson), (419) 137 W(CO),, photochemical reaction with CCl,; matrix-isolation studies of intermediates in (T. Szymanska-Buzar, A.J. Downs, T.M. Greene and M.A.K. Wood), (419) 151 Vanadium Binuclear pentamethylcyclopentadienylvanadium complexes with tellurium bridges; use of °'V NMR spectroscopy for identification of new vanadium complexes with different chalcogenes in the bridging system (M. Herberhold and M. Schrepfermann), (419) 85