इंटरनेट मानक Disclosure to Promote the Right To Information Whereas the Parliament of India has set out to provide a practical regime of right to information for citizens to secure access to information under the control of public authorities, in order to promote transparency and accountability in the working of every public authority, and whereas the attached publication of the Bureau of Indian Standards is of particular interest to the public, particularly disadvantaged communities and those engaged in the pursuit of education and knowledge, the attached public safety standard is made available to promote the timely dissemination of this information in an accurate manner to the public. “जान1 का अ+धकार, जी1 का अ+धकार” “प0रा1 को छोड न’ 5 तरफ” Mazdoor Kisan Shakti Sangathan Jawaharlal Nehru “The Right to Information, The Right to Live” “Step Out From the Old to the New” IS 14249 (1995): Etofenprox, Technical [FAD 1: Pesticides and Pesticides Residue Analysis] “!ान $ एक न’ भारत का +नम-ण” Satyanarayan Gangaram Pitroda ““IInnvveenntt aa NNeeww IInnddiiaa UUssiinngg KKnnoowwlleeddggee”” “!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता हहहहै””ै” Bhartṛhari—Nītiśatakam “Knowledge is such a treasure which cannot be stolen” IS 14249 : 1995 v7dklm T’\ ‘\ JrJ[l+) r L&-#-J- t (-Jq),+-& -m Indian Standard ETOFENPROX, TECHNICAL - SPECIFICATION UDC 632.951 El-H 0 BIS 1995 BUREAU OF INDIAN STANDARDS MANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARG NEW DELHI 110002 March 19% PriceGroup 2 sedicitseP lanoitceS ,eettimmoC DAF 1 FOREWORD sihT naidnI dradnatS saw detpoda yb eht uaeruB fo naidnI ,sdradnatS retfa eht tfard dezilanif yb eht sedicitseP lanoitceS ,eettimmoC dah neeb devorppa yb eht dooF dna erutlucirgA noisiviD .licnuoC ,xorpnefotE lacinhcet si deyolpme ni eht noitaraperp fo ladicitcesni .snoitalumrof xorpnefotE si eht nommoc eman desoporp yb eht lanoitanretnI noitazinagrO rof noitazidradnatS )OSI( rof lyznebyxonehp-3 )lynehpyxohte-lr(-Z lyhtem-2 lyporp ,rehte eht laciripme dna larutcurts ealumrof dna ralucelom ssam fo xorpnefote are nevig :woleb Empirical Formula StructuralF ormula Molecular Mass -0 0 \/ -3\5 -o 5H2C Cl CH2 30312Hs2C 74.673 nI eht noitaraperp fo siht ,dradnats eud noitaredisnoc sah neeb nevig ot eht snoisivorp fo eht Insecticides 1968 dna eht demarf rednuereht dna Act, Rules Standards of Weights and Measures (Packaged Com- ,revewoH siht dradnats si tcejbus ot eht snoitcirtser desopmi rednu eseht reverehw modties) Rules, 1977. .elbacilppa roF eht esoprup fo gnidiced rehtehw a ralucitrap tnemeriuqer fo siht dradnats si deilpmoc ,htiw eht lanif ,eulav devresbo ro ,detaluclac gnisserpxe eht tluser fo a tset ro ,sisylana llahs eb dednuor ffo ni ecnadrocca htiw SI 2 : lXX!l seluR‘ rof gnidnuor ffo laciremun seulav (revised)‘. The rebmun fo tnacifingis secalp deniater ni eht dednuor ffo eulav dluohs eb eht emas as taht fo eht deificeps eulav ni siht .dradnats Is 14249 : 1995 Indian Standard ETOFENPROX, TECHNICAL - SPECIFICATION EPOCS 4 GNIKCAP 1 sihT dradnats sebircserp eht stnemeriuqer dna eht ehT lairetam llahs eb dekcap ni edarg ’A‘ .S.M sdohtem fo gnilpmas dna tset rof ,xorpnefote -hcet sreniatnoC ylbatius dereuqcal moFf edisni dna .lacin dedivorp htiw reflip foorp resolc .metsys ehT -ixam mum yticipac fo eht .S.M sreniatnoC llahs eb 2 SECNEREFER 200 .gk tI llahs osla mrofnoc ot eht lareneg re- ehT naidnI sdradnatS detsil woleb are yrassecen tnemeriuq nevig ni SI 8190 (Part 1) : 1988. stcnujda ot siht :dradnats 5 GNIKRAM SI .oN eltiT 5.1 ehT sreniatnoc llahs eb dekram ylbigel dna 6940 : 1982 sdohteM fo tset rof sedicitsep dna ylbiledni htiw eht gniwollof :noitamrofni rieht snoitalumrof (jirst revision) a) emaN fo eht ;lairetam 8190 (Part 1) : tnemeriuqeR rof gnikcap fo b) emaN fo eht ;rerutcafunam 1988 sedicitsep : Part 1 diloS sedicitsep )c etaD fo ;erutcafunam dnoces( revision) )d etaD fo ;yripxe 10946 : 1984 sdohteM fo gnilpmas rof -inhcet )e hctaB ;rebmuN lac edarg sedicitsep )f teN ssam ni ;smargolik 3 STNEMERIUQER )g xorpnefotE tnetnm ,)m/m( ;muminim dna )h ynA rehto noitamrofni deriuqer rednu eht 3.1 noitpircseD sedicitcesnI Act, 1968 and Rules demarf rednuereht dna eht &radna&S fo Weights xorpnefotE lacinhcet llahs eb hsinworb etihw ni and Measures (Packaged Commodities) ruoloc dna llahs eb eerf morf suoenartxe seitirupmi Rules, 1977. dna dedda gniyfidom .stnega tI llahs eb ni eht mrof fo dilos ro dilos-imes ssam woleb WC .erutarepmet 5.2 SIB Certifkation Marking 3.2 ehT lairetam llahs ylpmoc htiw eht -eriuqer tcudorp yam osla eb dekram htiw eht dradnatS The stnem deificeps ni elbaT 1. .kraM Table 1 Requirements for Etofenprox, Technical ( Clause 3.2 ) Sl Characlerhic Requirement NO. )1( )2( (3) (4) (5) i) Etofenprox content, percent by mart (M), 96.3 A Min ii) Moisture omtenl, tnecrep yb Uram ,)hm( 0.2 4 Max iii) Material iusolubk in acetone, percent by 0.5 9 4lass (mk), h@ iv) Acidity (8s HzS04) or AkiIinity (a NaoH), a1 11.3 percent by mass (mha), Mu 1 SI 94241 : 5991 fo eht dradnatS Mark is denrevog yb morf eht uaeruB fo naidnI Standards. 5.2.1 The use eh’t snoisivorp fo uaeruB fo naidnI Standards ,tcA 1986 and eht seluR and snoitalugeR edam -ereht 6 GNILPMAS .rednu ehT sliated fo snoitidnoc rednu .hcihw eht ecnecil rof eht esu fo dradnatS Mark yam eb detnarg evitatneserpeR samples fo eht lairetam shall eb ot srerutcafunam ro srecudorp yam eb deniatbo drawn as debircserp ni SI 10946 : 1984. ANNEX A [ Table 1, Item )i( ] NOITANIMRETED FO XORPNEFOTE TNETNOC l-A LARENEG A-2.4 Procedure rehtiE fo eht owt ,sdohtem ,yleman hgih -rofrep A-2.4.1 Preparation of Mobile Phase ecnam diuqil yhpargotamorhc )CLPH( dohtem xiM 850 lm lonahtem and 150 lm fo elpirt dellitsid ees( )2-A ro gas yhpargotamorhc )CLG( dohtem ,retaw saged erofeb .esu ees( )3-A shall eb desu rof noitanimreted fo xorpnefotE .tnetnoc ehT CLPH dohtem shall eb 2.4.2-A Preparation of Internal Standard.Solution eht eerfer .dohtem hgieW tuoba 2 g fo lyxehid etalahtp otni a lm-OOl 2-A CLPH .DOHTEM cirtemulov ksalf and ekam up eht emulov ot eht kram htiw lonahtem and xim .llew i.2-A Principle 3.4.2-A Preparation of Reference Standard Solution xorpnefotE is devlossid ni lonahtem gnola htiw lanretni standard and denimreted yb CLPH no hgieW a ytitnauq fo eht ecnerefer standard os as ot acilis deifidom htiw C-8 niahc nmuloc htiw -artlu niatnoc tuoba 100 gm xorpnefote otni a 10 lm teloiv rotceted at 275 .mn cirtemulov ksalf and add lm-5 lanretni standard .noitulos ekaM up eht emulov htiw lonahtem and 2.2-A Reagents xim .llew A-2.2.1 Etofenprox Reference Standard fo( Known 4.4.2-A Preparation of Sample Solution P&y hgieW a ytitnauq fo elpmas os as ot niatnoc tuoba A-2.2.2 Internal Standard - lyxehiD etalahtp (AR 100 gm xorpnefote otni a 10 lm cirtemulov ksalf and .)edarg add 5 lm lanretni standard .noitulos ekaM up eht 3.2.2-A CLPH .edarg emulov htiw lonahtem and xim .llew Methanol - 4.2.2-A Water - elpirT .dellitsid 5.4.2-A Estimation tcejnI 1 ot 2~1 fo eht ecnerefer standard noitulos ni A-2.3 Apparatus ot eht hgih ecnamrofrep diuqil hpargotamorhc A-2.3.1 High Peformance Liquid Chromatograph )CLPH( dewollof yb eht elpmas noitulos htiw eht deppiuqE htiw a elbanut htgnelevaw UV rotceted pleh fo egnirys and erusaem kaep saera fo standard and an rotargetni and .redrocer ehT evitseggus and elpmas .snoitulos etupmoC eht egatnecrep fo sretemarap era nevig woleb and eseht nac eb deirav xorpnefote tnetnoc ni eht .elpmas dedivorp noitazidradnats is :enod 5.2-A Calculation nmuloC 7-xabroZ C8 ro tnelaviuqe 250 xorpnefotE ,tnetnoc mm x 4.6 mm ;DI stainless leets 3AxZAxlM px tnecrep yb mass ylbareferp htiw nmulocerp = M2xAl xAq eliboM esahp lonahteM : retaw 58( : )51 )v/v( erehw rotceteD teloiv-artlU tes at 275 mn mass, ni g, fo xorpnefote ni eht -refer Ml = wolP etar 1.2 etunim/lm ecne standard ;noitulos 2.3.2-A Micro Syringe - 10 .lu, M2 = mass, ni g, fo xorpnefote ni eht elpmas nekat rof ;tset NOTE - rednU zht debircsed snoitidnoc eht noitneter kaep aera fo xorpnefote ecnerefer semit fo lyxehid etalahthp dna xorpnefote era tuoba 11.5 dna A1 = 19.0 setunim .ylevitcepser standard ;noitulos 2 IS 14249 : 5991 kaep area fo xorpnefote ni eht elpmas A2 = A-3.4.1 Preparation of Internal Standard Solution ;noitulos hgieW tuoba 800 gm fo lyhthpanid rehte otni a A3 = kaep area fo lanretni dradnats ni eht lm-OOl cirtemulov ksalf dna ekam pu emuloveht ot ecnerefer dradnats ;noitulos eht kram htiw .enoteca kaep area fo lanretni dradnats ni elpmas A4 = 2.4.3-A ;noitulos dna Preparation of Reference Standard Solution hgieW a ytitnauq fo eht ecnerefer dradnais ot -noc tnecrep ytirup fo xorpnefote ecnerefer P = niat tuoba 100 gm xorpnefote otni a 10 lm .dradnats cirtemulov ksalf dna dda 5 lm lanretni dradnats 3-A CLG DOHTEM .noitulos ekaM pu eht emulov ot eht kram htiw .enoteca 1.3-A elpicnirP 3.4.3-A Preparation of Sample Solution xorpnefotE si devlossid ni enoteca gnola htiw -retni hgieW a ytitnauq fo elpmas ot niatnoc tuoba 100 lan dradnats dna denimreted yb CLG deppiuqe gm xorpnefote ni ot a 10 lm cirtemulov ksalf dna htiw emalf noitasinoi .rotceted dda 5 lm lanretni dradnats .noitulos ekaM pu eht 2.3-A stnegaeR emulov ot eht kram htiw .enoteca 1.2.3-A 4.4.3-A Etofenpox Standard of Known Purity Estimation A-3.2.2 Internal Standard - lyhthpaniD .rehte tcejnI 1 ot 2~1 fo eht ecnerefer dradnats noitulos ni ot eht sag hpargotamorhc dewollof yb eht elpmas 3.2.3-A .edarG Acetone - AR noitulos htiw eht pleh fo egnirys dna erusaem kaep 3.3-A sutarappA areas fo dradnats dna elpmas .snoitulos etupmoC eht egatnecrep fo xorpnefote tnetnoc ni eht .elpmas 1.3.3-A Gas Liquid Chromatograph 5.3-A noitaluclaC deppiuqE htiw a emalf noitasinoi rotceted dna na rotargetni ro .redrocer ehT detseggus gnitarepo xorpnefotE ,tnetnoc tM x 2A x 3A snoitidnoc are: tnecrep yb ssam = x.2M XP AI x A4 nmuloC Glass dekcap htiw 3 tnecrep enociliS DC-11 no Gas morhC erehw Q 100 mc htgnel x 3 mm DI ,ssam ni ,g fo xorpnefote ni eht -refer Ml = ecne dradnats ;noitulos Gas wolf Carrier sag (N2) : 50 niM/lm leuF sag (HZ) : 50 niMllm M2 = ,ssam ni ,g fo xorpnefote ni eht elpmas riA : 450 niM/lm nekat rof ;tset xorppa kaep area fo xorpnefote ni ecnerefer A1 = dradnats ;noitulos erutarepmeT nmuloC nevo : C°032 rotceteD : C°032 A2 = kaep area fo xorpnefote ni eht elpmas noitcejnI trop : C°072 ;noitulos kaep area fo lanretni dradnats ni eht NOTE - rednU eht debircsed ,snoitidnoc eht noitneter A3 = ecnerefer dradnats ;noitulos semit fo xorpnefote dna lyhthpanid rehte era tuoba 7.0 dna 3.4 setunim .ylevitcepser kaep area fo lanretni dradnats ni elpmas A4 = 2.3.3-A -10 .lu, ;noitulos dna Micro syringe tnecrep ytirup fo xorpnefote ecnerefer P = 4.3-A erudecorP .dradnats 3 Bureau of Indian Standards SIB si a yrotutats noitutitsni dehsilbatse rednu eht uaeruB naidn1fo Standurds Act, I986 ot etomorp suoinomrah tnempoleved fo eht seitivitca fo ,noitazidradnats gnikram dna ytilauq noitacifitrec fo sdoog dna gnidnetta ot detcennoc srettam ni eht .yrtnuoc CoPyrlght SIB sah eht thgirypoc fo all sti .snoitacilbup oN trap fo eseht snoitacilbup yam eb decudorper ni yna mrof tuohtiw eht roirp noissimrep ni gnitirw fo .SIB sihT seod ton edulcerp eht eerf ,esu ni eht esruoc fo gnitnemelpmi eht ,dradnats fo yrassecen ,sliated hcus as slobmys dna ,sezis epyt ro edarg .snoitangised seiriuqnE gnitaler ot thgirypoc eb desserdda ot eht rotceriD ,)snoitacilbuP( .SIB Review of Indian Standards stnemdnemA are deussi ot sdradnats as eht deen sesira no eht basis fo .stnemmoc sdradnatS are osla deweiver ;yllacidoirep a dradnats gnola htiw stnemdnema si demriffaer nehw hcus weiver setacidni taht on segnahc are ,dedeen fi eht weiver setacidni taht segnahc are ,dedeen ti si nekat pu rof .noisiver sresU fo naidnI sdradnatS dluohs niatrecsa taht yeht are ni noissessop fo eht tsetal stnemdnema ro noitide yb gnirrefer ot eht tsetal eussi fo SIB‘ ’koobdnaH dna sdradnatS‘ ylhtnoM .’snoitiddA sihT naidnI dradnatS sah neeb depoleved morf toD : .oN DAF 1 ( 268 ). Amendments Issued Since Publication dnemA .oN etaD fo eussI txeT detceffA UAERUB FO NAIDNI SDRADNATS :sretrauqdaeH kanaM ,navahB 9 rudahaB hahS rafaZ ,graM weN ihleD 11OOO2 smargeleT : ahtsnaskanaM senohpeleT : 3310131,33113 75 nommoC( ot all )seciffo lanoigeR seciffO : enohpeleT lartneC : kanaM ,navahB 9 rudahaB hahS rafaZ graM 3310131 NEW IHLED 1 20ool 33113 75 { nretsaE : 41/l .C .TL emehcS IIV ,M .V .I .P ,daoR alotkinaM 378499,378561 ATTUCLAC 700054 1 378626378662 nrehtroN : 0CS 335-336, rotceS A-43 HRAGIDNAHC 160022 603843 602025 { nrehtuoS : .C .I .T ,supmaC VI ssorC ,daoR SARDAM 600113 2350216,2350442 1 235 15 19,235 23 15 nretseW : ,ayalakanaM E9 ,CDIM ,loraM irehdnA (East) 632 92 95,632 78 58 YABMOB 40093 632 78 91,632 78 92 sehcnarB : .DABADAMHA .EROLAGNAB .LAPOHB .RAWHSENABUHB .EROTABMIOC .DABADIRAF .DABAIZAHG .ITAHAWUG .DABAREDYH .RUPIAJ .RUPNAK .WONKCUL .ANTAP .MARUPAHTNANAVURIHT yhpargorpeR ,tinU ,SIB weN ,ihleD aidnI