इंटरनेट मानक Disclosure to Promote the Right To Information Whereas the Parliament of India has set out to provide a practical regime of right to information for citizens to secure access to information under the control of public authorities, in order to promote transparency and accountability in the working of every public authority, and whereas the attached publication of the Bureau of Indian Standards is of particular interest to the public, particularly disadvantaged communities and those engaged in the pursuit of education and knowledge, the attached public safety standard is made available to promote the timely dissemination of this information in an accurate manner to the public. “जान1 का अ+धकार, जी1 का अ+धकार” “प0रा1 को छोड न’ 5 तरफ” Mazdoor Kisan Shakti Sangathan Jawaharlal Nehru “The Right to Information, The Right to Live” “Step Out From the Old to the New” IS 13403 (1992): Pesticide - Anilophos EC [FAD 1: Pesticides and Pesticides Residue Analysis] “!ान $ एक न’ भारत का +नम-ण” Satyanarayan Gangaram Pitroda ““IInnvveenntt aa NNeeww IInnddiiaa UUssiinngg KKnnoowwlleeddggee”” “!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता हहहहै””ै” Bhartṛhari—Nītiśatakam “Knowledge is such a treasure which cannot be stolen” IS 13403: 1992"· ~JiI'1q) Cfi"'R:'lTWCf) - t1:f~(1Ttnrn ~ ij"T -... f~ Indian Standard PESTICIDE -- ANILOPHOSEC~ SPECIFICATIO·N UDC 632-951 ANI :}o .'.'-\ s,» <0 DIS 1992 BUREAU OF INDIAN STANDARDS MANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARG NEW DELHI 110002 May 1992 Price Group 1 AMENDMENT NO.1 JULY 1993 TO IS13403: 1"2 PESTICIDE- ANILOPHOS EC SPECIFICATION c..... (P.,e1, 3.2.1)- SubstitutetilefoUowiDgfortheexistingmatter: '3.Z.1 DacriptiIM 'I1Ie malCriallbaU beia 1beformof. liable liquid. Sometulbidity/s.peDded _lIerDIIy bep-. It Mall readllyform I.emulsioDondilutioDwithwlter IUilibieforIplly.· ('ADO!) AMENDMENT NO. 2 JULY 1994 TO IS 13403: 1992 PESTICIDE-ANILOPHOS EC SPECIFICATION (Page 1,clause 3.%.5 )- Delete. (FAD1) ReproaraphyUBit,BIS,NewDelhi,IDdia Pesticides Sectional Committee, FAD 1 FOREWORD This Indian Standard wasadopted bythe Bureauof Indian Standards, after the draft finalized by the Pesticides Sectional Committee had been approved by the Food and Agriculture Division Council. Anilophos ECisgenerallyusedas a herbicide. Anilophos EC isgenerallymanufactured to contain 30 percent (mlm )ofanilophos. In the preparation of this standard, due consideration has been given to the provisrons of the Insecticides Act, 1968 and the Rulesframedthereunder. However,this standard is subject to the restrictionsimposedunder the Actand Rules, whereverapplicable. For the purpose of decidingwhethera particular requirement of this standard iscompliedwith, the finalvalue, observedor calculated, expressingthe result of a test or analysis, shall be rounded off in accordancewith IS 2: 1960'Rules for rounding offnumerical values (revised)'. The number of significantplacesretained in the rounded offvalueshould be the same as that of the specified valuein this standard. • IS 13413: 1992 Indian Standard PESTICIDE - ANILOPHOS EC SPECIFICATION 1 SC..P. PI: 3.2.3 Flash Point (Abel) This standard prescribes therequirements and the When determined by the method prescribed in naethodsof sampliDI and testfor anilophosEe. IS 1448 [P : 20] : 1982, the flash point of the materialshall beabove24SoC. 2 RUEIlENCES 3.1.4 Emulsion Stability The IndianStandards listed below are necessary Anyseparationincludingcreamingat the top and adjunctsto thisstandard: sedimentation at the bottom of 100 ml of emulsionprepared in standard hard water with IS No. T;t/~ 2·0 ml of Be, shall not exceed 2°0 ml when tested by the method prescribed in 13.3 of 1070 : 1977 Waterforgenerallaboratory use IS 6940 : 1982. (secondreYislon ) 1448 Methodsof test for determina 3.2.5 HeatSlability [P:20]: tion of flash point by Abel 1982 apparatus (first revision) The materialafter being treated by the method prescribed in 13.4ofIS 6940: 1982 shall comply 6940: 1982 Methods of test for pesticides with the requirementsliven in 3.2.1 to 3.2.4, 3.3.1 and their formulations (first and 3.3.2of thisstandard. revision) NOTE- The material need not be put to heat 8190 Requirements for packing of stabilitytestafter the expiry of half of its shelf-hfe, ( Part 2) : pesticides: Part 2 Liquid pesti as ascertained from the dates of manufacture and 1988 cides(second revision) expirydeclared on thecontainer. 10627 : 1983 Method of sampling of pesti- 3.3 Cbemical eida! formulations 3.3.1 Anilophos Content 13402 : 1992 Anilophos,technical When determined by the method prescribed in 3 REQUIREMENTS Annex B of IS 13402 : 1992 the observed anilophoscontent ( m/m) ofany of the samples shall not differ from the declared nominal value 3.1 COD.tltuentl bymore than the tolerancelimits givenbelow: 3.1.1 The material shall consist of anilophos, Nomina/ Value, Percent Tolerance Limits, technicaldissolved in suitable solventts) together Percent withemulsifying agent(s) and with or without stabilizer(s) and/or couplers. Up109 +101 ofthe -5 I ±S ~ nominal 3.1.2 Anilophostechnical, employed in the manu Above9andbelowSO I value facture of the material, shall conform to +S IS 13402 : 1992. SO and above JI -3 3.2 PIiJaleal 3.3.1 Acidity/Alkalinity 3.2.1 Delcription Whentestedbythe methodprescribed in 13.5 of IS 6940 : 1982, the acidity (as H.SO.) or The materialshallbe a clear, homogeneous and alkalinity(as NaOH) of the material shall be stable liquid,freefromsedimentand/or suspended not more than 0'3 and 0·2 percent by mass matter. It shall readily form an emulsion on r~spectively. dilutionwithwater,suitableforspray. 4 PACKING 3.3.2 ColdTeJI The material sball be packed in rectangular/ No turbidity or separationoflolidor oily matter round tinplate containers. 4-litres quantity of sballoccur When the material is subjected to the the material shall be packed in round tin cOld telt at IO·e u prescribed in 13.1 of containcr.shallbefurther packed in corrugated IS 6940 : 1982. flbro"'board boxes. 1 IS 13403: 1m S MARKING 7 TESTS man 5.1 Thecontainersshall be securely closed and 7.1 Test. becarriedout by the appropriate shall bear legibly and indelibly tbe follo"ina method. referred to in3.21Dd3.3. in addition to any other information as is necessary under the Insecticide, Act. 1968 and 7.2 Weilh 7S0 rna of lample iato a 50-ml Rulesframed thereunder: volumetricflast and make up tbe volume with the mobile pbase. Mix well. Take out 10ml a) Nameof thematerial; of thosolutionwitha pipetteinto anotber 5Q-ml b) Indicationofthesourceofmanufacture; volumetric flask and add 10 ml of internal standard solution, mix well and make up tbe c) Batch number; volume withthemobile phase. Alain mix well. d) Dateofmanufacture; Theconcentrationof anilophos Ihall be around e) Dateofexpiry; 0-9malml. DetermineanilophOicOlltent by the hiBb performanceliquid chromatolrapby method f) Netmaslofcontents; described in A-2 of IS 13402: 1992. s> Nominalanilopholcontent,percent(mlm); and 7.3 Weiah 360rna of the sample into a 2S-ml b) A cautionary notice worded as in the volumetric flask. add 10ml of internal standard Insect;cld,s Act, 1968 and Rules. solutionandmake up the volume with toluene to the mark. Mix well. The concentration of anilophosshallbearound4'3 malml. Determine 6 SAMPLING theanilopbOicontentbythe g8S chromat08rapby '.1 methoddescribedinA-3 ofIS 13402 : 1992. Representative samplesofthematerialshallbe drawn as prescribed in IS 10627: 1983 and 7.4 QualityofRealfDt. testedwithin90day. ofit. manufacturing. When thematerialisoffered forinspection after90 days Unless specified otherwise, pure chemicals and ofitsmanufacturing, sampling shall alsobedone distilled water (see IS 1070: 1977) sball be accordingto IS 10627: 1983. However. in the employed intests. latter case the criteria for conformity of the material when tested, shall be the limits of NOTE - "ureChemicals'shall mean chemicals that tolerances, as applicable over the declared do notcontainimpurities,which affect the results of nominalvalueandgiven in thisstandard. analysis. 2 Staadard Mark The useof the Standard Mark isgoverned by the provisions ot' the Bur~au of Indian StandardsAct, /986 and tho Rulesand Regulations made thereunder. The Standard Mark on products covered byan Indian Standard conveys the assurance that they have been produced to comply with the requirements of that standard under a well defined system of inspection, testing and quality control which is devised and .supervised by BISand operated bythe producer. Standard marked products are also 'ccntinuouslychecked by BISfor conformity to that standard as a further safeguard. Details of conditions under which a licence for tbe uee of the Standard Mark may begranted to manufacturers or producers Dlay beobtained from the Bureauof Indian Standardl.