इंटरनेट मानक Disclosure to Promote the Right To Information Whereas the Parliament of India has set out to provide a practical regime of right to information for citizens to secure access to information under the control of public authorities, in order to promote transparency and accountability in the working of every public authority, and whereas the attached publication of the Bureau of Indian Standards is of particular interest to the public, particularly disadvantaged communities and those engaged in the pursuit of education and knowledge, the attached public safety standard is made available to promote the timely dissemination of this information in an accurate manner to the public. “जान1 का अ+धकार, जी1 का अ+धकार” “प0रा1 को छोड न’ 5 तरफ” Mazdoor Kisan Shakti Sangathan Jawaharlal Nehru “The Right to Information, The Right to Live” “Step Out From the Old to the New” IS 1068 (1993): Eletroplated coatings of nickle plus chromium and copper plus nickel plus chromium [MTD 7: Light Metals and their Alloys] “!ान $ एक न’ भारत का +नम-ण” Satyanarayan Gangaram Pitroda ““IInnvveenntt aa NNeeww IInnddiiaa UUssiinngg KKnnoowwlleeddggee”” “!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता हहहहै””ै” Bhartṛhari—Nītiśatakam “Knowledge is such a treasure which cannot be stolen” IS 1068:1993 ( Superseding Is 4827, I8 4828 and IS 4842 ) Indian Standard ELECTROPLATED COATINGS OF NICKEL PLUS CHROMIUM AND COPPER PLUS NICKEL PLUS CHROMIUM-SPECIFICATION (, Third Revision ) Second Reprint APRIL 1998 669’248’7’26 + 669’387’24’25 : 621’357’7 8 BIS 1993 BUREAU OF INDIAN STANDARDS MANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARG NEW DELHI 110002 July 1993 Price Group 7 Metallic and Non-Metallic Sectional Commi(tee, MTD 20 FOREWORD This Indian Standard (Third Revision) was adopted by the Bureau of Indian Standards, after the draft finalized by the M,etallic and Non-Metallic Firlis!les Sectional Committee had been approved by the Metallurgical Engineering Division Council. This standard was first published in 1958 and subsequently revised in 1968 and 1985, respectively. Electrodeposited coatings of Ni plus Cr and Cu + Ni + Cr that are applied to zinc alloys, copper and copper alloys, and aluminium and aluminium alloys which are presently covered in IS 4827, IS 4828 and IS 4942 respectively, have now been incorporated in this revision to have unification of the requirements of these coatings on line with International Standards. After the publication of this standard, IS 4827 : 1983 ‘Electroplated coatings of nickel and chromium on copper and copper alloys (jirst revision )‘, IS 4828 : 1983 ‘Electroplated coatings of copper, nickel and chromium on zinc alloys (first revision )’ and IS 4942 : 1983 ‘Electroplating coating of nickel and chromium on aluminium and aluminium alloys (Jim revision )’ shall be withdrawn. In the preparation of this standard considerable assistance has been derived from IS0 1456 : 1988 Metallic coatings - Electroplated coatings of nickel plus chromium and of copper plus nickel PIUS chromium. For the purpose of deciding whether a particular requirement of this standard is complied with, the final value, observed or calculated, expressing the result of a test or analysis, shall be rounded off in accordance with IS 2 : 1960 ‘Rules for rounding off numerical values ( revised )‘. The number of significant places retained in the rounded off value should be the same as that of the specified value in this standard. IS 1068: . 1993 Indian Standard ELECTROPLATED COATINGS OF NICKEL PLUS CHROMIUM AND COPPER PLUS NICKEL PLUS CHROMIUM -SPECIFICATION ( Third Revision ) 1 SCOPE 3 SIGNIFICANT SURFACE 1.1 This standard covers requirements for nickel plus 3.1 For the purpose of this standard, a significant chromium and for copper plus nickel plus chromium surface is defined as the part of surface of an article electrodeposited coatings that are applied to iron, which being essential to the appearance or service- steel, zinc alloys, copper and copper alloys, and ability of that article is required to be coated by a aluminium and aluminium alloys to provide an specil”red thickness of copper, nickel and chromium, attractive appearance and corrosion resistance. Several in the stipulated combinations as specified in classes of coatings are provided that differ in thickness Tables 1A to 4. and type and guidance is given in selecting the coating class appropriate to the service conditions to which 3.1.1 When necessary, the significant surface should the coated product will be exposed. be the subject of agreement, and should be indicated on drawings, or by the provision of suitably marked 1.2 This standard does not specify the surface samples. condition required by the basis metal prior to the coating process. 4 INFORMATION TO BE SUPPLIED BY THE PURCHASER TO THE ELECTROPLATER 1.3 This standard is not applicable to coatings on sheet, strip or wire in the unfabricated form nor to 4.1 Essential Information threaded fasteners or coil springs. When ordering articles to be electroplated in 2 REFERENCES accordance with this standard, the purchaser shall provide the following information. 2.1 The standards given below are necessary adjuncts to this standard: 4.1.1 The number of this standard. IS No. T itle 4.1.2 The basis metal and either the service condition number (See 5.1) denoting the severity of the 3203 : 1982 Methods of testing local thickness conditions to be withstood by the coated arl.icle or of electroplated coatings ( first the classification code (see 5.2) of the particular coating revision ) required. 5528 : 1985 Method of testing corrosion If the basis metal and the service condition number resistance of electroplated and are quoted and not the classification code, the anodized aluminium coating by electroplater is free to supply any of the classes of copper accelerated acetic acid salt coating corresponding to the service condition spray (CASS) test (first revision ) number, but he shall inform the purchaser of the classification code of the coating which he has selected 6009 : 1970 Method for evaluation of results of (see also 7.2). accelerated corrosion tests 6910 : 1985 Method of testing corrosion 4.1.3 The finish required, for example, bright, dull, resistance of electroplated and or satin (see 7.2). Alternatively samples showing the anodized aluminium coatings by required finish or range of finish shall be supplied acetic acid salt spray test ( first or approved by the purchaser. revision ) 4.1.4 Significant surfaces, to be indicated on drawings 8038 : 1985 Method of testing corrosion. of the parts, or by the provision of suitably marked resistance of metallic and non- specimens. organic coatings by corrodkote test ( first revision ) 4.1.5 The type of corrosion test to be used. 1 IS 1068 : 1993 4.1.6 The type of adhesion test to be used. 4 A number indicating the minimum local thickness, in micmmetres, of the copper coating 4.1.7 The extent to which defects shall be tolerated where applicable. on non-significant surfaces. 4 The chemical symbol for nickel (Ni). 4.1.8 The positions on the significant surface for 4 A number indicating the minimum local rack or contact marks, where such marks are thickness, in micrometres, of the nickel coating. unavoidable. 0 A letter designating the type of nickel coating (see 7.2.3.2). 4.1.9 Sampling methods and acceptance levels. g) The chemical symbol for chromium (Cr). 4.2 Additional Information hl A letter or letters designating the type of The following additional information may be provided chromium coating and its minimum thickness. by the purchaser, when appropriate. Example of complete classification code : A coating 4.2.1 The tensile strength of the steel and any on steel comprising 20 urn copper (minimum) plus requirement for heat treatment either before or after 30 m bright nickel (minimum) plus 0.3 urn micro- electroplating. cracked chromium (minimum) has the classification code. 4.2.2 Thickness requirements on those areas, that Fe/Cu%O Ni30b Cr mc cannot be touched by a ball 20 mm in diameter. NOTE - For nickel plus chromium and copper plus nickel 4.23 Whetber or not a copper undercoat is required. plus chromium coatings, the minimum thickness requirements apply only to those portions of the significant surface that can 5 CLASSIFXCATION~ be toucbed by a ball 20 mm in diameter unless otherwise specified by the purchaser. 5.1 Service Condition Number 5.3 Coating Appropriate to Each Service Condition NMBnhgf The service condition number is used by the purchaser to specify the degree of protection Tables 1A to 4 show, for various basis metals, the required, as related to the severity of the conditions coating classification codes appropriate for each to which a product is to be subjected, in accordance service condition number. with the fdlOWinlj scale: 6 HEAT TREATMENT OF STEEL 4 = Extremely severe 6.1 If the purchaser specifies tbat heat treatment is 3 = Severe necessary before and/or after electroplating, it shall 2 = Moderate bc carried out in accordance with the appropriate 1 = Mild recommendations given in Annex B. 0 = Bxceptionally mild 7 COATING REQUIREMENTS Typical service conditions for which the various 7.1 Appearance service con&ion numbers are appropriate are listed in Annex A. Over the significant surface, there shall be no clearly visible plating defects such as blisters, pits, roughness, 5.2 Coating Classification Code cracks, unplated areas, stains or discoloration. The extent to which defects may occur on non-significant ?be coating classification code comprise the following: surfaces shall be specified by the purchaser. Where rack marks on the significant surface are unavoidable, 4 The chemical symbol for the basis metal (or their position shall be specified by the purchaser. for the principal metal if an alloy) followed by a ’ stroke, as follows: 7.2 Thickness and Type of Coatings - Fe / for iron or‘ steel 7.2.1 General - Zn I for zinc alloys For a specified service condition number, the - Cu / for copper or copper alloys thickness and type of coating shall correspond to the classification codes given in Tables 1A to 4. The - Al / for aluminium or aluminiunt alloys minimum allowable thickness for the metal coatings shall be required on any point of the significant b) The chemical symbol for copper (Cu), if surface that can -be touched by a ball 20 mm in copper or brass containing greater than 50 diameter and the purchaser may also specify that percent copper, is used as an undercoat other points shall meet those thickness requirements. 2 IS 1068 : 1993 Test methods for detemtining coating thickness are Table 2A Nickel Plus Chromium Coatings on specified in 9.1. Zinc Alloys (Clauses 3.1, 5.3, 7.2.1, 7.2.2 and 7.2.4.1) Table 1A Nickel Plus Chmmium Coatin@ on Iron or Steel h-vice Comditiom CIasaUlat&m Number ’ Code (Clauses 3.1, 5.3, 7.2.1 and 7.2.4.1) Service ComdlUom ClmssUhUom Zn/Cu Ni 35d Cr r Namtbcr Code ZtQCu Ni 25d Cr mc 4 FeiTVi 4Od Cr I ZnKu Ni 25d Cr mp Fe/Ni 306 Cr mc Fe/T% 30d Cr mp Z&u Ni 35p Cr r Z&u Ni 25p Cr mc Fe/M 4Op Cr r 4 ZtuCu Ni 25p Cr mp Fe/Ni 3op Cr mc Fe/Ni 3@ Cr mp Zn/Cu Ni 35b Cr mc Fe/Ni 30d Cr r Zn/Cu Ni 35b Cr mp FeJNi 2Sd Cr mc Fe-/Ni 2M Cr mp Zm’Cu Ni 25d Cr r FefTVi 30p Cr r Zn/Cu Ni 20d Cr mc Fe/M 25p Cr mc Zn/Cu Ni 206 Cr mp Fe/Ni 25p Cr mp Fe/Ni 4Ob Cr r Z&u Ni 25p Cr r Fe/Ni 30b Cr mc Zn/Cu Ni 2Op Cr mc FeiNi 30b Cr mp Z&u Ni 20p Cr mp 2 FeiNi 2Ob Cr r Zn/Cu Ni 35b Cr r i Fe/Ni 10b Cr r ZnKu Ni 25b Cr mc Z&u Ni 25b Cr mp 0 Fe/Ni 05b Cr r NOTE - s Nickel may be substituted for b nickel, and mc 2 Zn/Cu Ni 15b Cr r or mp chromium may be substituted for r chromium for service conditions 3, 2, 1 and 0. p and d nickel may be substituted for b nickel for service conditions 2 and 1. 0 and 1 Zn/Cu Ni Oftb Cr r Table 1B Copper Plus Nickel Plus Chromium NOTES Coatings on Iron or Steel 1 s nickel may be substituted for b nickel, and mc or mp (C&/ties 3.1, 5.3, 7.2.1, 7.2.2 and 7.2.4.1) chromium may be substituted for r chromium for service conditions 3, 2 and 1. p and d nickel may be substituted for Service Comditiom ClmssUiatIom b nickel for service condition 2. NUlllbW Cod e 2 Thinner coatings than those given for service condition 1 Fe/Cu 20 N i 3Od Cr r are not specified for service condition 0. Fe/Cu 20 Ni 25d Cr mc FeKu 20 Ni 25d Cr mp 3 A copper undercoat of at least 8 pm shall be given in all the cases. 4 Fe/Cu 20 Ni 3Op Cr r Fe/Cu 20 Ni 25p Cr mc Fe/Cu 20 Ni 25p Cr mp 7.2.2 Thickness of Copper Coating Fe/Cu 20 Ni 30b Cr mc For copper plus nickel plus chromium coatings, Fe/Cu 20 Ni 30b Cr mp the minimum thickness for copper is indicated in Fe/Cu 15 Ni 25d Cr r the classification codes given in Tables 1B and 2B. Fe/C% 15 Ni 2Od Cr mc The minimum copper thickness. for a system of Fe/Cu 15 Ni 20d Cr mp nickel plus chromium on zinc alloys is 8 pm (see Fe/Cu 15 Ni 25p Cr r Table 2A). 3 Fe/Cu 15 Ni 2% Cr mc NOTE -All the nickel coatings given in Table 2A are applied Fe/Cu 15 Ni 20p Cr mp over an undercoat of cdpper having a thickness of at least 8 Fe/Cu 20 Ni 35b Cr r pm [see 5.2(b) and 7.221. However, for articles of complex FeKu 20 Ni 25b Cr mc shape, the minimum thickness of copper on the significant Fe/Cu 20 Ni 25b Cr mp surface may need to he increased to 10 pm or 12 pm in order to achieve adequate coverage on low-current areas outside the 2 Fe/Cu 20 Ni lob Cr r significant surfaces. 1 Fe/Cu 10 Ni 05b Cr r 7.2.3 Thickness- and Type of Nickel Coatings 0 Fe/Cu 05 Ni 05b Cr r 7.2.3.1 Thickness of nickel coating NOTE - s Nickel may he substituted for b nickel, and mc or mp chromium may be substituted for r chromium for service The total minimum thickness of nickel shall be that conditions 3, 2, 1 and 0. p and d nickel may be substituted designated by the classification code (see 5.2). for b nickel for service condition 2. 3 IS 1068 : 1993 Table 2B Copper Plus Nickel Plus Chromium Table 4 Coatings of Nickel Plus Chromium on Coatings on Zinc Alloys [see also 5.2(b)] Aluminium or Aluminium Alloys (Clauses 3.1, 5.3, 7.2.1, 7.2.2 and 7.2.4.1) (Clauses 3.1, 5.3, 7.2.1 and 7.2.4.1) sa-vice condition classulcauon Service Condition CIassf5catfon Nlllllber Code NUtllber Code Al/Ni 5Od Cr r Zn/Cu 20 Ni 3Od Cr I Al/Ni 35d Cr mc ZtKu 20 Ni 20d Cr mc AilNi 35d Cr mp Z&u 20 Ni 2Od Cr mp 4 AIM 30d Cr r Zn!Cu 20 Ni 30~ Cr r AVNi 25d Cr mc Zn/Cu 20 Ni 20~ Cr mc AWNi 25d Cr mp Zn/Cu 20 Ni 20~ Cr mp 3 AUNi Up Cr r Audi 30~ Cr mc Zn/Cu 20 Ni 30d Cr mc AbNi 3Op Cr mp Zn/Cu 20 Ni 30d Cr mp 2 At/f% 20b Cr r Zn/Cu 15 Ni 20d Cr r 3 Zn/Cu 15 Ni 15d Cr mc 0 and 1 At/Ni 10b Cr r ZtVCu 15 Ni 15d Cr mp N0W.S ZKu 20 Ni 30b Cr r 1 A copper undercoat in addition to the specified nickel Zn/Cu 20 Ni 20b Cr mc coatings may be used on certain alloys and the certain Zn/Cu 20 Ni 20b Cr mp applications. Zn/Cu 15 Ni 20~ Cr r 2 Q, d or s nickel may be substituted for b nickel, and mc or Zn/Cu 15 Ni 15~ Cr mc mp chromium may be substituted for r chromium for service Zn/Cu 15 Ni 15~ Cr mp conditions numbers 2 and 1. 2 Zn/Cu 20 Ni lob Cr r 7.2.3.2 Type of nickel coating 0 and 1 This coating systems given in The typ of nickel coating shall be designated by Table 2A for service condition the following symbols: number 1 shall apply here. ‘b’ for nickel deposited in the fully bright condition; NOTE - s nickel may be substituted for b nickel, and mc or mp chromium may be substituted for r chromium for service 6 , conditions 3, 2 and 1: Q and d nickel may be substituted for P for dull or semi-bright nickel which has been mechanically polished; b nickel for service condition 2. ‘ , S for dull satin, or semi-bright nickel which Table 3 Nickel Plus Chromium Coatings on shall not have been mechanically polished; Copper or Copper Alloys and (Clauses 3.1, 5.3, 7.2.1 a n d 7.2.4.1) ‘d’ for double or triple-layer coatings; the requirements for such coatings are given in sa-vke conduion ClaasiflatIon Table 5. NUlEbcr COdC .NOTES Cu/Ni 30d Cr r 1 The test method for the determination of specific elongation Cu/Ni sd Cr mc is specified in Annex C. Cu/Ni 2Sd Cr mp 2 The sutphur contents are specified in order to indicate the Cu/Ni 30p Cr r type of nickel plating solution that is to be used. No simple 4 Cu/Ni 25p Cr mc method exists for determioiog the sulQhur content of a nickel Cu/Ni 25p Cr mp deposit on a coated article. However, an accurate determination is Qossibte 00 a specialty prepared test specimen using either Cu/Ni 30b Cr mc of the methods specified in Annex D. I Cu/Ni 30b Cr mp 3 It will usually be possible to identify the type and to determine the ratios of thicknesses of nickel layers by Cu/Ni 25b Cr r microscopical examination of a polished and etched section of an article prepared in accordance with IS 3203 : 1982. Cu/Ni lob Cr r Cu/Ni 05b Cr r 7.2.4 Thickness and Type of Chromium Conting CuMi 03b Cr r ’ 7.2.4.1 Thickness of chromium coating The thickness of the chromium coatings shall be as NOTE - s nickel may be substituted for b nickel, aod mc follows: or mp chromium may be substituted for r chromium for service conditions 3, 2, 1 and 0. Q and d nickel may be substituted - Regular (conventional) chromium (designated for b nickel for service conditions 3 and 2. Cr r) - minimum thickness 0.3 pm 4 IS 1068 : 1993 - Micro-cracked chromium (designated Cr 7.3 Adhesion mc) - minimum thickness of 0.3 pm (see The coating shall be sufficiently adherent to the basis Notes 1 and 2) metal, and the separate layers of a multilayer coating - Micro-cracked chromium (designated Cr mc shall be sufficiently adherent to each other, to pass 0.5) - minimum thickness 0.5 pm (see Note the appropriate test specified in 9.2. 2 and Note under 7.2.4.2) 7.4 Corrosion Resistance - Micro-cracked chromium (designated Cr Coated articles shall be sufficiently corrosion-resistant mp) - minimum thickness 0.3 pm (see and pore-free to pass the appropriate test specified Note 2) in 9.3 for the particular service condition number. - Micro-porous chromium (designated Cr mp The performance rating shall be determined in 0.5) - minimum thickness 0.5 pm (see accordance with IS 6009. The minimum acceptance Note 2) rating, after testing in accordance with 9.3 shall be a rating of 9. NOTES NOTE - For a quick identification for performance of pore free Ni, modified ferroxyl test may be used, as given in 1 With some processes a substantially greater mickness, Annex F. approximately 0.8 pm, may be required to achieve the necessary crack pattern. 8 SELECTION OF SAMPLES 2 There may be some loss of lustre after a period of service in the case of mp or mc chromium deposits which may be 8.1 Out of each lot of similar parts, a number of unacceptable in some applications. This tendency may be reduced samples shall be selected at random. The size of the by increasing the minimum chromium coating thickness to 0.5 pm in every case where micro-porous or micro-cracked chromium is lot and the number of samples to be selected shall specified in Tables 1A to 4. be agreed upon between the manufacturer and the purchaser. All of the samples selected shall be visually 7.2.4.2 Type of chromium coating examined for any defects referred to in 7.1. The type of chromium coating is designated by placing 9 METHODS OF TEST symbols after the chemical symbol, Cr as follows: 9.1 Thickness Cr r for regular chromium; 9.1.1 The thickness of a coating and its various layers Cr mc for micro-cracked chromium which, shall be measured at any part of the significant surface when tested by the method described in that can be touched by a ball 20 mm diameter. The Annex EZ, has more than 250 cracks per coulometric method described in Annex G may be centimetre in any direction and form a closed used to measure the thickness of the chromium, the network over the whole significant total thickness of the nickel, the thickness of the surface; copper and the thickness of a copper alloy undercoat, if its composition is known, In case the instrument Cr mp for micro-porous c hromium which, specified in Annex G is not available, the method when tested by the method specified in given in IS 3203 : 1982 may be used. Annex E, contains at least 10 000 pores per square centimetre (see Note). 9.1.2 The microscopical method specified in IS 3203 : 1982 may be used to measure the thickness of each NOTE -This type of coating is often achieved by depositing nickel layer where the minimum thickness is 10 pm, chromium over a special thin nickel layer which cohtains inert non-conducting particles, the special nickel layer being applied and of a copper or copper alloy undercoat, when on top of b, s, p or d nickel. present ( see 7.2 ). Table 5 Requirements for Double or T.tiple Layer Nickel Coatings (Clause 7.2.3.2) Layer SpedtlC Sulphur Thickness,I ISP Percentage flYFo.,,,kel Elongation content of Total Nickel Thickness Percent Percent (m/m) (see Note 3) (see Note 1) (see Note 2) / - . Double Layer Triple Layer Bottom(s) >8 < 0.005 + 60 L 50 Middle High-sulphur (b) - > 0.15 - 10 Top (b) - > 0.04 S 40 I 40 and 0.15 5