Instrumental Data for Drug Analysis Volume 6 CRC SERIES IN FORENSIC AND POLICE SCIENCE BARRY A. J. FISHER, Series Editor L.A. County Sheriff's Department TECHNIQUES OF CRIME SCENE INVESTIGATION Fifth Edition Barry A. J. Fisher SCIENTIFIC EXAMINATION OF QUESTIONED DOCUMENTS Revised Edition Ordway Hilton ADVANCES IN FINGERPRINT TECHNOLOGY Henry C. Lee R. E. Gaensslen INSTRUMENTAL DATA FOR DRUG ANALYSIS Second Edition, Volumes 1—4 Terry Mills III J. Conrad Roberson INSTRUMENTAL DATA FOR DRUG ANALYSIS Second Edition, Volume 5 Terry Mills III J. Conrad Roberson H. Horton McCurdy William H. Wall INSTRUMENTAL DATA FOR DRUG ANALYSIS Volume 6-7 Terry Mills III J. Conrad Roberson William H. Wall Kevin L. Lothridge William D. McDougall Michael W. Gilbert Instrumental Data for Drug Analysis Volume 6 Terry Mills III, J. Conrad Roberson, William H. Wall, Kevin L. Lothridge, William D. McDougall, and Michael W. Gilbert First published 1996 by CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 Reissued 2018 by CRC Press © 1996 by CRC Press, Inc. CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. 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Trademark Notice: Product or corporate names maybe trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Library of Congress Cataloging-in-Publication Data Mills, Terry Instrumental data for drug analysis / by Terry Mills III, J. Conrad Roberson, William H. Wall v. < 7 >; cm. — (CRC series on forensic and police science) Includes index Includes bibliographical references and index. ISBN 0-8493-8115-0 (alk. paper) 1. Drugs—Analysis—Standards. 2. Drugs—Sepctra—Standards. 3. Pesticides—Analysis—Standards. 4. Pesticides—Spectra—Standards. 5. Instrumental analysis—Standards—Indexes. I. Roberson, J. Conrad. II. Wall, William H. III. Title IV. Series RA1228.M54 1996 615M901—dc20 96-31352 Publisher's Note The publisher has gone to great lengths to ensure the quality of this reprint but points out that some imperfections in the original copies may be apparent. Disclaimer The publisher has made every effort to trace copyright holders and welcomes correspondence from those they have been unable to contact. ISBN 13: 978-1-315-89456-0 (hbk) ISBN 13: 978-1-351-07366-0 (ebk) Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com CONTENTS PREFACE vii ACKNOWLEDGMENTS ix INTRODUCTION xi DRUG DATA 1 GAS CHROMATOGRAPHY/INFRARED SPECTRA 279 OF DRUGS MASS SPECTRA OF PESTICIDES 501 PREFACE Almost everyone engaged in the analysis of drug-related compounds, whether in the forensic, clinical, or university laboratory, has an accumulation of analytical data and thus has acquired a data base for the analysis of these compounds. Some of the information contained in Volume 6 of Instrumental Data for Drug Analysis is available in the literature; however, there is no single source that contains timely, quality data of this type presented in a large, easily usable format. As in our previous volumes, we have included the six currently most popular analytical tech- niques: ultraviolet (UV), infrared (IR) spectrometry, proton nuclear magnetic resonance (NMR) spectrometry, mass speclrometry (MS), gas chromatography (GC), and high pressure liquid chromatography (HPLC). As the quality of data presented was of paramount importance in a reference source, we generated all of our data in our laboratories under uniform, reproducible conditions using state-of-the-art technology and verified chemical standards. In this Volume 6 of the second edition of IDDA, we have included a special section of analytical data especially designed for lexicologists. This text contains mass spectra of over 200 pesticides. In addition, there are over 600 GC/FTER spectra of many of the drugs found in previous volumes of IDDA. Six new tabulations of mass spectra data on these drugs and pesticides are included in the Cumulative Index Volume 7. In the Cumulative Index all indices have been expanded to include all data from volumes 1 through 6 with the corresponding page and volume number given after each entry. Terry Mills III J. Conrad Roberson William H. Wall Kevin L. Lothridge William D. McDougall Michael Gilbert ACKNOWLEDGMENTS The authors wish to express appreciation to the many individuals who contributed to this reference book by offering helpful suggestions, information, assistance, and reviews. We are grateful to Dr. Byron Dawson, Director and to Mr. Milton Nix, Director of the Georgia Bureau of Investigation, for making the facilities of the Georgia crime laboratory available for this work. We are grateful to Denver Chief of Police David L. Michaud and Crime Laboratory Bureau Commander Captain Steve C. Metros and Forensic Supervisor Sergeant Mark R. Olin for making the facilities of the Denver crime laboratory available for this work. We are grateful for Kevin Lothridge, forensic Laboratory Director for making the facilities of the Pinellas County crime laboratory available for this work. We appreciate the assistance of Patricia Price for helping with the mass spectral data, and the assistance of Mathew Philip and Len Brown for helping with the computer word-processing. We also appreciate the help from William Pearson, Jeff Martinez, Adel Ashcroft, Adam Dryden, Devona Vix, and members of the crime laboratories for their help. We are indebted to Bradley Mills for drawing most of the chemical structures. We appreciate the program ChemWindow from SoftShell International.