SAFETY DATA SHEET GOJO® Antibacterial Plum Foam Handwash Version Revision Date: MSDS Number: Date of last issue: 02/16/2015 2.0 04/17/2015 31854-00003 Date of first issue: 11/24/2014 SECTION 1. IDENTIFICATION Product name : GOJO® Antibacterial Plum Foam Handwash Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron OH 44311 Telephone : 1 (330) 255-6000 Emergency telephone : 1-800-424-9300 CHEMTREC Recommended use of the chemical and restrictions on use Recommended use : Antibacterial Soap Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Serious eye damage : Category 1 GHS Label element Hazard pictograms : Signal Word : Danger Hazard Statements : H226 Flammable liquid and vapor. H318 Causes serious eye damage. 1 / 21 SAFETY DATA SHEET GOJO® Antibacterial Plum Foam Handwash Version Revision Date: MSDS Number: Date of last issue: 02/16/2015 2.0 04/17/2015 31854-00003 Date of first issue: 11/24/2014 Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards Vapors may form explosive mixture with air. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous ingredients Chemical Name CAS-No. Concentration (%) Ethanol 64-17-5 >= 10 - < 20 Dodecanoic acid 143-07-7 >= 5 - < 10 Propylene glycol 57-55-6 >= 5 - < 10 Ethanolamine 141-43-5 >= 1 - < 5 Imidazolium compounds, 1-[2- 68650-39-5 >= 1 - < 5 (carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5- dihydro-2-norcoco alkyl, hydroxides, sodium salts SECTION 4. FIRST AID MEASURES General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. Get medical attention if symptoms occur. In case of skin contact : Wash with water and soap as a precaution. Get medical attention if symptoms occur. 2 / 21 SAFETY DATA SHEET GOJO® Antibacterial Plum Foam Handwash Version Revision Date: MSDS Number: Date of last issue: 02/16/2015 2.0 04/17/2015 31854-00003 Date of first issue: 11/24/2014 In case of eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn. Get medical attention immediately. If swallowed : If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water. Most important symptoms : Causes serious eye damage. and effects, both acute and delayed Protection of first-aiders : First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists. Notes to physician : Treat symptomatically and supportively. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing : High volume water jet media Specific hazards during fire : Do not use a solid water stream as it may scatter and spread fighting fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health. Hazardous combustion prod- : Carbon oxides ucts Nitrogen oxides (NOx) Metal oxides Specific extinguishing : Use extinguishing measures that are appropriate to local methods circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area. Special protective equipment : In the event of fire, wear self-contained breathing apparatus. for fire-fighters Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, : Remove all sources of ignition. 3 / 21 SAFETY DATA SHEET GOJO® Antibacterial Plum Foam Handwash Version Revision Date: MSDS Number: Date of last issue: 02/16/2015 2.0 04/17/2015 31854-00003 Date of first issue: 11/24/2014 protective equipment and Use personal protective equipment. emergency procedures Follow safe handling advice and personal protective equipment recommendations. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for : Non-sparking tools should be used. containment and cleaning up Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements. SECTION 7. HANDLING AND STORAGE Technical measures : See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section. Local/Total ventilation : Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation. Advice on safe handling : Avoid inhalation of vapor or mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment. Conditions for safe storage : Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. 4 / 21 SAFETY DATA SHEET GOJO® Antibacterial Plum Foam Handwash Version Revision Date: MSDS Number: Date of last issue: 02/16/2015 2.0 04/17/2015 31854-00003 Date of first issue: 11/24/2014 Store in accordance with the particular national regulations. Keep away from heat and sources of ignition. Materials to avoid : Do not store with the following product types: Strong oxidizing agents Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Value type Control Basis (Form of parameters / exposure) Permissible concentration Ethanol 64-17-5 TWA 1,000 ppm NIOSH REL 1,900 mg/m3 TWA 1,000 ppm OSHA Z-1 1,900 mg/m3 STEL 1,000 ppm ACGIH Propylene glycol 57-55-6 TWA 10 mg/m3 US WEEL Ethanolamine 141-43-5 TWA 3 ppm ACGIH STEL 6 ppm ACGIH TWA 3 ppm NIOSH REL 8 mg/m3 ST 6 ppm NIOSH REL 15 mg/m3 TWA 3 ppm OSHA Z-1 6 mg/m3 Hazardous components without workplace control parameters Ingredients CAS-No. Dodecanoic acid 143-07-7 Imidazolium compounds, 1-[2- 68650-39-5 (carboxymethoxy)ethyl]-1- (carboxymethyl)-4,5-dihydro-2- norcoco alkyl, hydroxides, sodium salts Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation. Personal protective equipment 5 / 21 SAFETY DATA SHEET GOJO® Antibacterial Plum Foam Handwash Version Revision Date: MSDS Number: Date of last issue: 02/16/2015 2.0 04/17/2015 31854-00003 Date of first issue: 11/24/2014 Respiratory protection : General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection. Hand protection Material : Impervious gloves Material : Flame retardant gloves Remarks : Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday. Eye protection : Wear the following personal protective equipment: Chemical resistant goggles must be worn. If splashes are likely to occur, wear: Face-shield Skin and body protection : Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc). Hygiene measures : Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Color : clear, purple Odor : citrus Odor Threshold : No data available 6 / 21 SAFETY DATA SHEET GOJO® Antibacterial Plum Foam Handwash Version Revision Date: MSDS Number: Date of last issue: 02/16/2015 2.0 04/17/2015 31854-00003 Date of first issue: 11/24/2014 pH : 7.8 - 9.7 Melting point/freezing point : No data available Initial boiling point and boiling : 97.00 °C range Flash point : 56.00 °C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Upper explosion limit : No data available Lower explosion limit : No data available Vapor pressure : No data available Relative vapor density : No data available Density : 1.00 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- : Not applicable octanol/water Autoignition temperature : No data available Decomposition temperature : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 10 - 20 mm2/s (20 °C) Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Possibility of hazardous reac- : Flammable liquid and vapor. tions Vapors may form explosive mixture with air. Can react with strong oxidizing agents. Conditions to avoid : Heat, flames and sparks. 7 / 21 SAFETY DATA SHEET GOJO® Antibacterial Plum Foam Handwash Version Revision Date: MSDS Number: Date of last issue: 02/16/2015 2.0 04/17/2015 31854-00003 Date of first issue: 11/24/2014 Incompatible materials : Oxidizing agents Hazardous decomposition : No hazardous decomposition products are known. products SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Acute inhalation toxicity : Acute toxicity estimate: > 40 mg/l Exposure time: 4 h Test atmosphere: vapor Method: Calculation method Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Ingredients: Ethanol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor Dodecanoic acid: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity : LC50 (Rat): > 0.162 mg/l Exposure time: 4 h Test atmosphere: vapor Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials Propylene glycol: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rabbit): > 159 mg/l, > 51091 ppm Exposure time: 4 h 8 / 21 SAFETY DATA SHEET GOJO® Antibacterial Plum Foam Handwash Version Revision Date: MSDS Number: Date of last issue: 02/16/2015 2.0 04/17/2015 31854-00003 Date of first issue: 11/24/2014 Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Ethanolamine: Acute oral toxicity : LD50 (Rat): 1,515 mg/kg Acute inhalation toxicity : Acute toxicity estimate: 11 mg/l Test atmosphere: vapor Method: Expert judgment Remarks: Based on harmonised classification in EU regulation 1272/2008, Annex VI Acute dermal toxicity : LD50 (Rabbit): 1,025 mg/kg Imidazolium compounds, 1-[2-(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5-dihydro-2- norcoco alkyl, hydroxides, sodium salts: Acute oral toxicity : LD50 (Rat, male): > 5,000 mg/kg Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg Method: OECD Test Guideline 402 Remarks: Based on data from similar materials Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Ingredients: Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Dodecanoic acid: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Propylene glycol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Ethanolamine: Species: Rabbit Result: Corrosive after 3 minutes to 1 hour of exposure 9 / 21 SAFETY DATA SHEET GOJO® Antibacterial Plum Foam Handwash Version Revision Date: MSDS Number: Date of last issue: 02/16/2015 2.0 04/17/2015 31854-00003 Date of first issue: 11/24/2014 Imidazolium compounds, 1-[2-(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5-dihydro-2- norcoco alkyl, hydroxides, sodium salts: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Remarks: Based on data from similar materials Serious eye damage/eye irritation Causes serious eye damage. Ingredients: Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Dodecanoic acid: Species: Rabbit Result: Irreversible effects on the eye Method: OECD Test Guideline 405 Propylene glycol: Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405 Ethanolamine: Species: Rabbit Result: Irreversible effects on the eye Imidazolium compounds, 1-[2-(carboxymethoxy)ethyl]-1-(carboxymethyl)-4,5-dihydro-2- norcoco alkyl, hydroxides, sodium salts: Species: Rabbit Result: Irreversible effects on the eye Method: OECD Test Guideline 405 Remarks: Based on data from similar materials Respiratory or skin sensitization Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information. Product: Assessment: Does not cause skin sensitization. Ingredients: Ethanol: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Dodecanoic acid: Test Type: Maximization Test (GPMT) 10 / 21