2008_eng.qxp 2/21/2008 8:30 AM Page 1 2 2008 Emergency 0 0 Response THIS DOCUMENT SHOULD NOT BE USED TO DETERMINE COMPLIANCE WITH THE DANGEROUS GOODS REGULATIONS 8 OR Guidebook TO CREATE WORKER SAFETY DOCUMENTS FOR SPECIFIC CHEMICALS E M E R G E N N O T F O R S A L E C Y This document is distributed free of charge to Public Safety Organizations and may not be resold. R E S P O N S U.S. Department of Transportation E Pipeline and Hazardous Materials Safety Administration G AGUIDEBOOK U FOR FIRST RESPONDERS I DURING THE INITIALPHASE D OF ADANGEROUS GOODS/ E B HAZARDOUS MATERIALS Secretariat of Transport and Communications O TRANSPORTATION INCIDENT O K 2008_eng.qxp 2/21/2008 8:30 AM Page 2 SHIPPING DOCUMENTS (PAPERS)* EMERGENCYRESPONSETELEPHONENUMBERS The shipping document provides vital information when responding to a hazardous materials/dangerous goods** incident. The shipping document CANADA contains information needed to identify the materials involved. Use this 1. CANUTEC information to initiate protective actions for your own safety and the safety of the 613-996-6666 public. The shipping document contains the 4-digit ID number (see yellow- (Collect calls are accepted) bordered pages) preceded by the letters UN or NA, the proper shipping name *666 cellular(in Canada only) (see blue-bordered pages), the hazard class or division of the material(s), and, UNITEDSTATES where appropriate, the Packing Group. The shipping document will also display a 24-hour emergency response telephone number. In addition, there must be 1. CHEMTREC® information available that describes the hazards of the material which can be 1-800-424-9300 used in the mitigation of an incident. The information must be entered on or be (Toll-free in the U.S., Canada and the U.S. Virgin Islands) with the shipping document. This requirement may be satisfied by attaching a 703-527-3887 For calls originating elsewhere guide from the ERG2008 to the shipping document, or by having the entire (Collect calls are accepted) guidebook available for ready reference. Shipping documents are required for 2. CHEMTEL, INC. most dangerous goods in transportation. Shipping documents are kept in • the cab of the motor vehicle, 1-888-255-3924 (Toll-free in the U.S., Canada, Puerto Rico and the U.S. Virgin Islands) • the possession of the train crew member, 813-248-0585For calls originating elsewhere • a holder on the bridge of a vessel, or (Collect calls are accepted) • an aircraft pilot’s possession. 3. INFOTRAC EMERGENCY CONTACT EXAMPLE OF EMERGENCY 1-800-535-5053 1-000-000-0000 CONTACT TELEPHONE NUMBER (Toll-free in the U.S., Canada and the U.S. Virgin Islands) 352-323-3500For calls originating elsewhere HAZARD CLASS (Collect calls are accepted) NO. & TYPE OR DIVISION NO. QUANTITY OF PACKAGES 4. 3E COMPANY 1 TANKT RUCK UN1219 ISOPROPANOL 3 II 12,000 LITERS 1-800-451-8346 (Toll-free in the U.S., Canada and the U.S. Virgin Islands) ID NUMBER SHIPPING NAME PACKING GROUP 760-602-8703 For calls originating elsewhere (Collect calls are accepted) 5. MILITARYSHIPMENTS EXAMPLE OF PLACARD AND PANELWITH ID NUMBER 703-697-0218 - Explosives/ammunition incidents The 4-digit ID Number may be shown on the diamond-shaped placard or on (Collect calls are accepted) an adjacent orange panel displayed on the ends and sides of a cargo tank, 1-800-851-8061 - All other dangerous goods incidents vehicle or rail car. 6. NATIONWIDE POISON CONTROLCENTER (United States only) ANumbered or APlacard 1-800-222-1222 (toll-free in the U.S.) 1219 Placard and an FLAMMABLE Orange Panel 1219 * For the purposes of this guidebook, the terms shipping document/shipping paper are synonymous. ** For the purposes of this guidebook, the terms hazardous materials/dangerous goods are synonymous. BEFORE AN EMERGENCY – BECOME FAMILIAR WITH THIS GUIDEBOOK! In the U.S., according to the requirements of the U.S. Department of Labor’s Occupational Safety and Health Administration (OSHA, 29 CFR 1910.120), and regulations issued by the U.S. Environmental Protection Agency (EPA, 40 CFR Part 311), first responders must be trained regarding the use of this guidebook. RESIST RUSHING IN ! APPROACH INCIDENT FROM UPWIND STAY CLEAR OF ALL SPILLS, VAPORS, FUMES, SMOKE AND SUSPICIOUS SOURCES HOW TO USE THIS GUIDEBOOK DURING AN INCIDENT INVOLVING DANGEROUS GOODS STEP ONE: IDENTIFY THE MATERIAL. USE ANY OF THE FOLLOWING: • IDENTIFICATION NUMBER (4-DIGIT ID) FROM A PLACARD, ORANGE PANEL, SHIPPING PAPER OR PACKAGE (after UN/NA) • NAME OF THE MATERIAL FROM A SHIPPING DOCUMENT OR PACKAGE STEP TWO: IDENTIFY 3-DIGIT GUIDE NUMBER USE: • ID NUMBER INDEX in yellow-bordered pages or • NAME OF MATERIAL INDEX in blue-bordered pages Guide number supplemented with the letter “P” indicates that the material may undergo violent polymerization if subjected to heat or contamination. INDEX ENTRIES HIGHLIGHTED IN GREEN are TIH (Toxic Inhalation Hazard) material, a chemical warfare agent or a Dangerous Water Reactive Material (produces toxic gas upon contact with water). IDENTIFY ID NUMBER AND NAME OF MATERIAL IN TABLE 1 – INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES (the green-bordered pages). IF NECESSARY, BEGIN PROTECTIVE ACTIONS IMMEDIATELY (see Protective Actions page 296). If no protective action required, use the information jointly with the 3-digit guide. STEP THREE: TURN TO THE NUMBERED GUIDE (the orange-bordered pages) READ CAREFULLY. USE GUIDE 112 FOR ALL EXPLOSIVES EXCEPT FOR EXPLOSIVES 1.4 (EXPLOSIVES C) WHERE GUIDE 114 IS TO BE CONSULTED. NOTE: IF ABOVE STEPS CANNOT BE COMPLETED AND PLACARD IS VISIBLE: Turn to pages 16-17; use 3-digit guide next to placard; PROCEED TO NUMBERED GUIDE (orange-bordered pages). If shipping document is available, call emergency response telephone number listed. If document or emergency response telephone is not available, IMMEDIATELY CALL the appropriate emergency response agency listed in the back of this guidebook. Provide as much information as possible, such as the name of the carrier (trucking company or railroad) and vehicule number. IF A REFERENCE TO A GUIDE CANNOT BE FOUND AND THIS INCIDENT IS BELIEVED TO INVOLVE DANGEROUS GOODS, TURN TO GUIDE 111 NOW, AND USE IT UNTIL ADDITIONAL INFORMATION BECOMES AVAILABLE. AS A LAST RESORT: IF ONLY THE CONTAINER CAN BE IDENTIFIED, CONSULT THE TABLE OF RAIL CAR AND ROAD TRAILER IDENTIFICATION CHART (pages18-19). REMEMBER THAT THE INFORMATION ASSOCIATED WITH THESE CONTAINERS IS FOR WORST CASE SCENARIOS. Page 1 WhitePages 1_14 Eng.pmd 1 2/14/08, 10:21 AM ERG2008 USER’S GUIDE The 2008 Emergency Response Guidebook (ERG2008) was developed jointly by Transport Canada (TC), the U.S. Department of Transportation (DOT), the Secretariat of Transport and Communications of Mexico (SCT) and with the collaboration of CIQUIME (Centro de Información Química para Emergencias) of Argentina, for use by fire fighters, police, and other emergency services personnel who may be the first to arrive at the scene of a transportation incident involving dangerous goods. It is primarily a guide to aid first responders in quickly identifying the specific or generic hazards of the material(s) involved in the incident, and protecting themselves and the general public during the initial response phase of the incident. For the purposes of this guidebook, the “initial response phase” is that period following arrival at the scene of an incident during which the presence and/or identification of dangerous goods is confirmed, protective actions and area securement are initiated, and assistance of qualified personnel is requested. It is not intended to provide information on the physical or chemical properties of dangerous goods. This guidebook will assist responders in making initial decisions upon arriving at the scene of a dangerous goods incident. It should not be considered as a substitute for emergency response training, knowledge or sound judgment. ERG2008 does not address all possible circumstances that may be associated with a dangerous goods incident. It is primarily designed for use at a dangerous goods incident occurring on a highway or railroad. Be mindful that there may be limited value in its application at fixed facility locations. ERG2008 incorporates dangerous goods lists from the most recent United Nations Recommendations as well as from other international and national regulations. Explosives are not listed individually by either proper shipping name or ID Number. They do, however, appear under the general heading “Explosives” on the first page of the ID Number index (yellow-bordered pages) and alphabetically in the Name of Material index (blue-bordered pages). Also, the letter “P” following the guide number in the yellow-bordered and blue- bordered pages identifies those materials which present a polymerization hazard under certain conditions, for example: Acrolein, stabilized 131P. First responders at the scene of a dangerous goods incident should seek additional specific information about any material in question as soon as possible. The information received by contacting the appropriate emergency response agency, by calling the emergency response telephone number on the shipping document, or by consulting the information on or accompanying the shipping document, may be more specific and accurate than this guidebook in providing guidance for the materials involved. BEFORE AN EMERGENCY – BECOME FAMILIAR WITH THIS GUIDEBOOK! In the U.S., according to the requirements of the U.S. Department of Labor’s Occupational Safety and Health Administration (OSHA, 29 CFR 1910.120), and regulations issued by the U.S. Environmental Protection Agency (EPA, 40 CFR Part 311), first responders must be trained regarding the use of this guidebook. Page 2 WhitePages 1_14 Eng.pmd 2 2/14/08, 10:21 AM GUIDEBOOK CONTENTS 1-Yellow-bordered pages: Index list of dangerous goods in numerical order of ID number. This section quickly identifies the guide to be consulted from the ID Number of the material involved. This list displays the 4-digit ID number of the material followed by its assigned emergency response guide and the material name. For example: ID No. GUIDE No. Name of Material 1090 127 Acetone 2-Blue-bordered pages: Index list of dangerous goods in alphabetical order of material name. This section quickly identifies the guide to be consulted from the name of the material involved. This list displays the name of the material followed by its assigned emergency response guide and 4-digit ID number. For example: Name of Material GUIDE No. ID No. Sulfuric acid 137 1830 3-Orange-bordered pages: This section is the most important section of the guidebook because it is where all safety recommendations are provided. It comprises a total of 62 individual guides, presented in a two-page format. Each guide provides safety recommendations and emergency response information to protect yourself and the public. The left hand page provides safety related information whereas the right hand page provides emergency response guidance and activities for fire situations, spill or leak incidents and first aid. Each guide is designed to cover a group of materials which possess similar chemical and toxicological characteristics. The guide title identifies the general hazards of the dangerous goods covered. For example: GUIDE 124 - Gases-Toxic and/or Corrosive-Oxidizing. Each guide is divided into three main sections: the first section describes potential hazards that the material may display in terms of fire/explosion and health effects upon exposure. The highest potential is listed first. The emergency responder should consult this section first. This allows the responder to make decisions regarding the protection of the emergency response team as well as the surrounding population. The second section outlines suggested public safety measures based on the situation at hand. It provides general information regarding immediate isolation of the incident site, recommended type of protective clothing and respiratory protection. Suggested evacuation distances are listed for small and large spills and for fire situations (fragmentation hazard). It also directs the reader to consult the tables listing Toxic Inhalation Hazard (TIH) materials, chemical warfare agents and water-reactive materials (green-bordered pages) when the material is highlighted in the yellow- bordered and blue-bordered pages. The third section covers emergency response actions, including first aid. It outlines special precautions for incidents which involve fire, spill or chemical exposure. Several Page 3 WhitePages 1_14 Eng.pmd 3 2/14/08, 10:21 AM recommendations are listed under each part which will further assist in the decision making process. The information on first aid is general guidance prior to seeking medical care. 4-Green-bordered pages: This section contains two tables. Table 1 lists, by ID number order, TIH materials, including certain chemical warfare agents, and water-reactive materials which produce toxic gases upon contact with water. This table provides two different types of recommended safe distances which are “Initial isolation distances” and “Protective action distances.” The materials are highlighted in green for easy identification in both numeric (yellow-bordered pages) and alphabetic (blue-bordered pages) lists of the guidebook. This table provides distances for both small (approximately 200 liters or less for liquids and 300 kilograms or less for solids when spilled in water) and large spills (more than 200 liters for liquids and more than 300 kilograms for solids when spilled in water) for all highlighted materials. The list is further subdivided into daytime and nighttime situations. This is necessary due to varying atmospheric conditions which greatly affect the size of the hazardous area. The distances change from daytime to nighttime due to different mixing and dispersion conditions in the air. During the night, the air is generally calmer and this causes the material to disperse less and therefore create a toxic zone which is greater than would usually occur during the day. During the day, a more active atmosphere will cause a greater dispersion of the material resulting in a lower concentration of the material in the surrounding air. The actual area where toxic levels are reached will be smaller (due to increased dispersion). In fact, it is the quantity or concentration of the material vapor that poses problems not its mere presence. Table 2 lists, by ID number order, materials which produce large amounts of Toxic Inhalation Hazard (TIH) gases when spilled in water and identifies the TIH gases produced. These Water Reactive materials are easily identified in Table 1 as their name is immediately followed by (when spilled in water). Note, however, if this material is NOT spilled in water, Table 1 and Table 2 do not apply and safety distances will be found within the appropriate orange guide. The “Initial Isolation Distance” is a distance within which all persons should be considered for evacuation in all directions from the actual spill/leak source. It is a distance (radius) which defines a circle (Initial Isolation Zone) within which persons may be exposed to dangerous concentrations upwind of the source and may be exposed to life threatening concentrations downwind of the source. For example, in the case of Compressed gas, toxic, n.o.s., ID No. 1955, Inhalation Hazard Zone A, the isolation distance for small spills is 100 meters, therefore, representing an evacuation circle of 200 meters in diameter. For the same material, the “Protective Action Distance” for a small spill is 0.5 kilometers for a daytime incident and 2.1 kilometers for a nighttime incident, these distances represent a downwind distance from the spill/leak source within which Protective Actions could be implemented. Protective Actions are those steps taken to preserve the health and safety of emergency responders and the public. People in this area could be evacuated and/or sheltered in-place. For more information, consult pages 293 to 299. What is a TIH? It is a gas or volatile liquid which is known to be so toxic to humans as to pose a hazard to health during transportation, or in the absence of adequate data on human Page 4 WhitePages 1_14 Eng.pmd 4 2/14/08, 10:21 AM toxicity, is presumed to be toxic to humans because when tested on laboratory animals it has a Lethal Concentration 50 (LC50) value of not more than 5000 ppm. It is important to note that even though the term zone is used, the hazard zones do not represent any actual area or distance. The assignment of the zones is strictly a function of their Lethal Concentration 50 (LC50); for example, TIH Zone A is more toxic than Zone D. All distances which are listed in the green-bordered pages are calculated by the use of mathematical models for each TIH material. For the assignment of hazard zones refer to the glossary. ISOLATION AND EVACUATION DISTANCES Isolation or evacuation distances are shown in the guides (orange-bordered pages) and in the Table 1 - Initial Isolation and Protective Action Distances (green-bordered pages). This may confuse users not thoroughly familiar with ERG2008. It is important to note that some guides refer only to non-TIH materials (36 guides), some refer to both TIH and non-TIH materials (21 guides) and some (5 guides) refer only to TIH or Water-reactive materials (WRM). A guide refers to both TIH and non-TIH materials (for example see GUIDE 131) when the following sentence appears under the title EVACUATION-Spill: “See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For non-highlighted materials, increase, in the downwind direction, as necessary, the isolation distance shown under ‘PUBLIC SAFETY.’” A guide refers only to TIH or WRM materials (for example see GUIDE 124) when the following sentence appears under the title EVACUATION- Spill: “See Table 1 - Initial Isolation and Protective Action Distances”. If the previous sentences do not appear in a guide, then this particular guide refers only to non-TIH materials (for example see GUIDE 128). In order to identify appropriate isolation and protective action distances, use the following: If you are dealing with a TIH/WRM/Chemical warfare material (highlighted entries in the index lists), the isolation and evacuation distances are found directly in the green-bordered pages. The guides (orange-bordered pages) also remind the user to refer to the green-bordered pages for evacuation specific information involving highlighted materials. If you are dealing with a non-TIH material but the guide refers to both TIH and non-TIH materials, an immediate isolation distance is provided under the heading PUBLIC SAFETY as a precautionary measure to prevent injuries. It applies to the non-TIH materials only. In addition, for evacuation purposes, the guide informs the user under the title EVACUATION-Spill to increase, for non-highlighted materials, in the downwind direction, if necessary, the immediate isolation distance listed under “PUBLIC SAFETY”. For example, GUIDE 131 – Flammable Liquids-Toxic, instructs the user to: "As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions." In case of a large spill, the isolation area could be expanded from 50 meters to a distance deemed as safe by the On-scene commander and emergency responders. If you are dealing with a non-TIH material and the guide refers only to non-TIH materials, the immediate isolation and evacuation distances are specified as actual distances in the guide (orange-bordered pages) and are not referenced in the green-bordered pages. Page 5 WhitePages 1_14 Eng.pmd 5 2/14/08, 10:21 AM SAFETY PRECAUTIONS APPROACH CAUTIOUSLY FROM UPWIND. If wind direction allows, consider approaching the incident from uphill. Resist the urge to rush in; others cannot be helped until the situation has been fully assessed. SECURE THE SCENE. Without entering the immediate hazard area, isolate the area and assure the safety of people and the environment, keep people away from the scene and outside the safety perimeter. Allow enough room to move and remove your own equipment. IDENTIFY THE HAZARDS. Placards, container labels, shipping documents, material safety data sheets, Rail Car and Road Trailer Identification Charts, and/or knowledgeable persons on the scene are valuable information sources. Evaluate all available information and consult the recommended guide to reduce immediate risks. Additional information, provided by the shipper or obtained from another authoritative source, may change some of the emphasis or details found in the guide. Remember, the guide provides only the most important and worst case scenario information for the initial response in relation to a family or class of dangerous goods. As more material-specific information becomes available, the response should be tailored to the situation. ASSESS THE SITUATION. Consider the following: - Is there a fire, a spill or a leak? - What are the weather conditions? - What is the terrain like? - Who/what is at risk: people, property or the environment? - What actions should be taken: Is an evacuation necessary? Is diking necessary? What resources (human and equipment) are required and are readily available? - What can be done immediately? OBTAIN HELP. Advise your headquarters to notify responsible agencies and call for assistance from qualified personnel. DECIDE ON SITE ENTRY. Any efforts made to rescue persons, protect property or the environment must be weighed against the possibility that you could become part of the problem. Enter the area only when wearing appropriate protective gear (see PROTECTIVE CLOTHING, page 348). RESPOND. Respond in an appropriate manner. Establish a command post and lines of communication. Rescue casualties where possible and evacuate if necessary. Maintain control of the site. Continually reassess the situation and modify the response accordingly. The first duty is to consider the safety of people in the immediate area, including your own. ABOVE ALL. Do not walk into or touch spilled material. Avoid inhalation of fumes, smoke and vapors, even if no dangerous goods are known to be involved. Do not assume that gases or vapors are harmless because of lack of a smell—odorless gases or vapors may be harmful. Use CAUTION when handling empty containers because they may still present hazards until they are cleaned and purged of all residues. Page 6 WhitePages 1_14 Eng.pmd 6 2/14/08, 10:21 AM WHO TO CALL FOR ASSISTANCE Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods, protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit. Follow the steps outlined in your organization’s standard operating procedures and/or local emergency response plan for obtaining qualified assistance. Generally, the notification sequence and requests for technical information beyond what is available in this guidebook should occur in the following order: 1. ORGANIZATION/AGENCY Notify your organization/agency. This will set in motion a series of events based upon the information provided. Actions may range from dispatching additional trained personnel to the scene to activating the local emergency response plan. Ensure that local fire and police departments have been notified. 2. EMERGENCY RESPONSE TELEPHONE NUMBER Locate and call the telephone number listed on the shipping document. The person answering the phone at the listed emergency response number must be knowledgeable of the materials and mitigation actions to be taken, or must have immediate access to a person who has the required knowledge. 3. NATIONAL ASSISTANCE Contact the appropriate emergency response agency listed on the inside back cover of this guidebook when the emergency response telephone number is not available from the shipping papers. Upon receipt of a call describing the nature of the incident, the agency will provide immediate advice on handling the early stages of the incident. The agency will also contact the shipper or manufacturer of the material for more detailed information and request on-scene assistance when necessary. Collect and provide as much of the following information as can safely be obtained to your chain- of-command and specialists contacted for technical guidance: Your name, call back telephone number, FAX number Location and nature of problem (spill, fire, etc.) Name and identification number of material(s) involved Shipper/consignee/point of origin Carrier name, rail car or truck number Container type and size Quantity of material transported/released Local conditions (weather, terrain, proximity to schools, hospitals, waterways, etc.) Injuries and exposures Local emergency services that have been notified Page 7 WhitePages 1_14 Eng.pmd 7 2/14/08, 10:21 AM CANADA 1. CANUTEC CANUTEC is the Canadian Transport Emergency Centre operated by the Transport Dangerous Goods Directorate of Transport Canada. CANUTEC provides a national bilingual (French and English) advisory service and is staffed by professional scientists experienced and trained in interpreting technical information and providing emergency response advice. In an emergency, CANUTEC may be called collect at 613-996-6666 (24 hours) *666 cellular (Press Star 666, Canada only) In a non-emergency situation, please call the information line at 613-992-4624 (24 hours). 2. PROVINCIAL AGENCIES Although technical information and emergency response assistance can be obtained from CANUTEC, there are federal and provincial regulations requiring the reporting of dangerous goods incidents to certain authorities. The following list of provincial agencies is supplied for your convenience. Province Emergency Authority and/or Telephone Number Alberta.........................................Local Police and Provincial Authorities 1-800-272-9600* or 780-422-9600 British Columbia..........................Local Police and Provincial Authorities 1-800-663-3456 Manitoba......................................Provincial Authority 204-945-4888 and Local Police or fire brigade, as appropriate New Brunswick............................Local Police or 1-800-565-1633** or 902-426-6030 Newfoundland and Labrador.......Local Police and 709-772-2083 Northwest Territories...................867-920-8130 Nova Scotia.................................Local Police or 1-800-565-1633** or 902-426-6030 Nunavut Territory.........................Local Police and 1-800-693-1666 or 867-979-6262 Ontario.........................................Local Police Prince Edward Island..................Local Police or 1-800-565-1633** or 902-426-6030 Quebec........................................Local Police Saskatchewan.............................Local Police or 1-800-667-7525 Yukon Territory............................867-667-7244 * This number is not accessible from outside Alberta. ** This number is not accessible from outside of New Brunswick, Nova Scotia or Prince Edward Island. 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