COMPUTATIONAL AND EXPERIMENTAL ANALYSIS OF FUNCTIONAL MATERIALS AAP Research Notes on Polymer Engineering Science and Technology COMPUTATIONAL AND EXPERIMENTAL ANALYSIS OF FUNCTIONAL MATERIALS Edited by Oleksandr V. Reshetnyak, DSc Gennady E. Zaikov, DSc Apple Academic Press Inc. Apple Academic Press Inc. 3333 Mistwell Crescent 9 Spinnaker Way Oakville, ON L6L 0A2 Canada Waretown, NJ 08758 USA ©2017 by Apple Academic Press, Inc. No claim to original U.S. Government works Printed in the United States of America on acid-free paper International Standard Book Number-13: 978-1-77188-342-9 (Hardcover) International Standard Book Number-13: 978-1-315-36635-7 (CRC Press/Taylor & Francis eBook) International Standard Book Number-13: 978-1-77188-343-6 (eBook) All rights reserved. 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The authors, editors, and the publisher have attempted to trace the copyright holders of all mate- rial reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged, please write and let us know so we may rectify in any future reprint. Trademark Notice: Registered trademark of products or corporate names are used only for explanation and identification without intent to infringe. Library and Archives Canada Cataloguing in Publication Computational and experimental analysis of functional materials / edited by Oleksandr Reshetnyak, DSc, Gennady E. Zaikov, DSc. (AAP research notes on polymer engineering science and technology series) Includes bibliographical references and index. Issued in print and electronic formats. ISBN 978-1-77188-342-9 (hardcover).--ISBN978-1-315-36635-7 (PDF) 1. Polyanilines--Synthesis. 2. Polymeric composites. I. Zaikov, G. E. (Gennadii Efremovich), 1935-, editor II. Reshetnyak, Oleksandr, author, editor III. Series: AAP research notes on polymer engineering science and technology series TP1180.P552C64 2017 668.9 C2016-907864-7 C2016-907865-5 Library of Congress Cataloging-in-Publication Data Names: Reshetnyak, Oleksandr, editor. | Zaikov, G. E. (Gennadiæi Efremovich), 1935- editor. Title: Computational and experimental analysis of functional materials / editors, Oleksandr Reshetnyak, DSc, Gennady E. Zaikov, DSc. Description: Toronto : Apple Academic Press, [2017] | Includes bibliographical references and index. Identifiers: LCCN 2016054503 (print) | LCCN 2016057620 (ebook) | ISBN 9781771883429 (hardcover : alk. paper) | ISBN 9781315366357 (ebook) Subjects: LCSH: Polyanilines. | Conducting polymers. | Materials science. Classification: LCC TP1180.P552 C66 2017 (print) | LCC TP1180.P552 (ebook) | DDC 620.1/9204297--dc23 LC record available at https://lccn.loc.gov/2016054503 Apple Academic Press also publishes its books in a variety of electronic formats. Some content that appears in print may not be available in electronic format. For information about Apple Academic Press products, visit our website at www.appleacademicpress.com and the CRC Press website at www.crcpress.com This book is dedicated to the memory of Professor Eugen P. Koval’chuk, DSc (1939–2012) ABOUT THE EDITORS Oleksandr V. Reshetnyak, DSc Oleksandr Reshetnyak, DSc, is Head of the Department of Physical and Colloid Chemistry of Ivan Franko National University of Lviv (Lviv, Ukraine). He is the author of two monographs and more than 150 publica- tions in various journals and conference proceedings. His scientific activity is in the fields of physical chemistry of nanosystems, conductive polymers and its composites, electrochemistry of organic compounds, and chemi- and electrochemiluminescence. He is a member of the Editorial Board of the Visnyk Lviv University Journal (Series: Chemistry) (Lviv, Ukraine) as well as a member of the Editorial Board of the bimonthly scientific and technical international journal Materials Science. He is also an active member of the Taras Shevchenko Scientific Society (Lviv, Ukraine). Contact address: 6 Kyryla & Mefodiya Str., Lviv, 79005, Ukraine Tel: (+38) (032) 2600–397 Fax: (+38) (032) 2600–397 E-mail: [email protected]; [email protected]. Gennady E. Zaikov, DSc Gennady Zaikov, DSc, is Head of the Department of the Kinetics of Chem- ical & Biological Processes at the N. M. Emanuel Institute of Biochemical Physics at the Russian Academy of Sciences (Moscow, Russia) and Professor at Moscow State Academy of Fine Chemical Technology (Russia) as well as Professor at Kazan National Research Technological University (Kazan, Russia). He is also a prolific author, researcher, and lecturer. Contact address: 4 Kosygin Str., Moscow, 119991, Russia Tel: 7 (495) 1374–101 Fax: 7 (495) 9397–320 E-mail: [email protected] CONTENTS List of Contributors .......................................................................................xi List of Abbreviations ...................................................................................xiii Supporting Institutions ................................................................................xix Preface ........................................................................................................xxi 1. Polyanilines: The Role of Particles of Radical Nature in Obtaining of Polymers/Copolymers with a System of Conjugated π-Bonds ...............1 O. V. Reshetnyak, M. M. Yatsyshyn, and L. I. Bazylyak 2. Morphology of Polyaniline’s Films Electrochemically Deposited on the Surface of Al-Based Amorphous Metal Alloys ................................61 М. М. Yatsyshyn, L. М. Boichyshyn, I. I. Demchyna, and Yu. A. Hnizdiukh 3. Electrooptic Phenomena in Conjugated Polymeric Systems Based on Polyaniline and Its Derivatives ...............................................................91 О. I. Aksimentyeva, О. I. Konopelnyk, and D. О. Poliovyi 4. An Investigation of Monomolecular Films of Polyanilines .....................151 I. Ye. Opaynych, О. I. Aksimentyeva, and Yu. Yu. Horbenko 5. Epoxy–Polyaniline Composites: Synthesis, Structure, Properties .........179 V. P. Zakordonskiy, О. I. Aksimentyeva, and A. I. Krupak 6. Thermochromic Effect in the Films of Conjugated Polyaminoarenes ...219 О. I. Konopelnyk and О. I. Aksimentyeva 7. Polyaniline in Chemo-and Biosensorics: Overview .................................243 Ya. S. Kovalyshyn and O. V. Reshetnyak 8. Corrosion Protection of Aluminum and Al-Based Alloys by Polyaniline and Its Composites ..................................................................287 О. V. Reshetnyak and М. M. Yatsyshyn 9. Synthesis and Physico–Chemical Properties of Composites of Conjugated Polyaminoarenes with Dielectric Polymeric Matrices ........331 О. I. Aksimentyeva, О. I. Konopelnyk, G. V. Martyniuk, and O. M. Yevchuk 10. Polyanilines: Generation of Electrochemiluminescence ..........................371 О. V. Reshetnyak