3M™ Acryl-Green Spot Putty PN 05096 01/18/18 Safety Data Sheet Copyright,2018,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 27-0721-4 Version Number: 3.02 Issue Date: 01/18/18 Supercedes Date: 09/24/15 SECTION 1: Identification 1.1. Product identifier 3M™ Acryl-Green Spot Putty PN 05096 Product Identification Numbers LB-K100-0714-5, 41-0003-6502-7, 41-0003-8043-0, 60-4550-4709-6 1.2. Recommended use and restrictions on use Recommended use Automotive, For Industrial or Professional use. 1.3. Supplier’s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 2. Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 2. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word __________________________________________________________________________________________ Page 1 of 15 3M™ Acryl-Green Spot Putty PN 05096 01/18/18 Danger Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Highly flammable liquid and vapor. Causes serious eye irritation. Causes skin irritation. May cause drowsiness or dizziness. May damage fertility or the unborn child. Suspected of causing cancer. Causes damage to organs through prolonged or repeated exposure: nervous system | respiratory system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to __________________________________________________________________________________________ Page 2 of 15 3M™ Acryl-Green Spot Putty PN 05096 01/18/18 extinguish. Storage: Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 13% of the mixture consists of ingredients of unknown acute oral toxicity. 13% of the mixture consists of ingredients of unknown acute dermal toxicity. 13% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Talc 14807-96-6 15 - 40 Trade Secret * Toluene 108-88-3 10 - 30 Trade Secret * Titanium Dioxide 13463-67-7 7 - 13 Trade Secret * Acrylic Polymers Trade Secret* 7 - 13 Trade Secret * Magnesium Carbonate 546-93-0 3 - 7 Trade Secret * Benzoate Esters Trade Secret* 3 - 7 Trade Secret * Butyl Alcohol 71-36-3 1 - 5 Trade Secret * Rheological Additive Trade Secret* 1 - 5 Trade Secret * Synthetic Crystalline-Free Silica Gel 112926-00-8 < 3 Trade Secret * Chlorite (Mineral) 1318-59-8 < 2 Trade Secret * Ethylbenzene 100-41-4 < 0.2 Trade Secret * Benzene 71-43-2 < 0.05 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. __________________________________________________________________________________________ Page 3 of 15 3M™ Acryl-Green Spot Putty PN 05096 01/18/18 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. Vapors may travel long distances along the ground or floor to an ignition source and flash back. __________________________________________________________________________________________ Page 4 of 15 3M™ Acryl-Green Spot Putty PN 05096 01/18/18 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylbenzene 100-41-4 ACGIH TWA:20 ppm A3: Confirmed animal carcin. Ethylbenzene 100-41-4 OSHA TWA:435 mg/m3(100 ppm) Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm SILICA, AMORPHOUS 112926-00- OSHA TWA concentration:0.8 8 mg/m3;TWA:20 millions of particles/cu. ft. Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 DUST, INERT OR NUISANCE 14807-96-6 OSHA TWA(as total dust):15 mg/m3;TWA(as total dust):50 millions of particles/cu. ft.(15 mg/m3);TWA(respirable fraction):15 millions of particles/cu. ft.(5 mg/m3);TWA(respirable fraction):5 mg/m3 Talc 14807-96-6 ACGIH TWA(respirable fraction):2 A4: Not class. as human mg/m3 carcin Talc 14807-96-6 OSHA TWA:2 mg/m3 Magnesium Carbonate 546-93-0 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Butyl Alcohol 71-36-3 ACGIH TWA:20 ppm Butyl Alcohol 71-36-3 OSHA TWA:300 mg/m3(100 ppm) Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm SKIN, A1: Confirmed human carcin. Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 29 CFR 1910.1028 ppm;STEL:5 ppm;CEIL:25 ppm ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls __________________________________________________________________________________________ Page 5 of 15 3M™ Acryl-Green Spot Putty PN 05096 01/18/18 8.2.1. Engineering controls Provide appropriate local exhaust ventilation for sanding, grinding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Paste Odor, Color, Grade: Solvent Odor, Green Smooth Paste Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point >=200 ºF Flash Point 63 ºF [Test Method:Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.00 % Flammable Limits(UEL) 13.00 % Vapor Pressure <=27 psia [@ 131.0000000000 ºF] [Details:MITS data] Vapor Density No Data Available Density 1.46 - 1.60 g/ml Specific Gravity 1.46 - 1.60 [Ref Std:WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available __________________________________________________________________________________________ Page 6 of 15 3M™ Acryl-Green Spot Putty PN 05096 01/18/18 Decomposition temperature No Data Available Viscosity 200,000 - 400,000 centipoise Hazardous Air Pollutants 0.43 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 420 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 27.5 % weight [Test Method:calculated per CARB title 2] Percent volatile 27.6 % weight VOC Less H2O & Exempt Solvents 421 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames Heat 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). __________________________________________________________________________________________ Page 7 of 15 3M™ Acryl-Green Spot Putty PN 05096 01/18/18 Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause target organ effects: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Generic: CAS NO S14807966D 14807-96-6 Grp. 2B: Possible human carc. International Agency for Research on Cancer Benzene 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Benzene 71-43-2 Known human carcinogen National Toxicology Program Carcinogens Benzene 71-43-2 Cancer hazard OSHA Carcinogens Ethylbenzene 100-41-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- No data available; calculated ATE >50 mg/l Vapor(4 hr) Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Talc Dermal LD50 estimated to be > 5,000 mg/kg __________________________________________________________________________________________ Page 8 of 15 3M™ Acryl-Green Spot Putty PN 05096 01/18/18 Talc Ingestion LD50 estimated to be > 5,000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Rat LC50 30 mg/l Vapor (4 hours) Toluene Ingestion Rat LD50 5,550 mg/kg Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium Dioxide Inhalation- Rat LC50 > 6.82 mg/l Dust/Mist (4 hours) Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg Magnesium Carbonate Dermal LD50 estimated to be > 5,000 mg/kg Magnesium Carbonate Ingestion Mouse LD50 > 5,000 mg/kg Butyl Alcohol Dermal Rabbit LD50 3,402 mg/kg Butyl Alcohol Inhalation- Rat LC50 24 mg/l Vapor (4 hours) Butyl Alcohol Ingestion Rat LD50 2,290 mg/kg Chlorite (Mineral) Dermal LD50 estimated to be > 5,000 mg/kg Chlorite (Mineral) Ingestion LD50 estimated to be > 5,000 mg/kg Synthetic Crystalline-Free Silica Gel Dermal Rabbit LD50 > 5,000 mg/kg Synthetic Crystalline-Free Silica Gel Inhalation- Rat LC50 > 0.691 mg/l Dust/Mist (4 hours) Synthetic Crystalline-Free Silica Gel Ingestion Rat LD50 > 5,110 mg/kg Ethylbenzene Dermal Rabbit LD50 15,433 mg/kg Ethylbenzene Inhalation- Rat LC50 17.4 mg/l Vapor (4 hours) Ethylbenzene Ingestion Rat LD50 4,769 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Talc Rabbit No significant irritation Toluene Rabbit Irritant Titanium Dioxide Rabbit No significant irritation Magnesium Carbonate In vitro Minimal irritation data Butyl Alcohol Rabbit Mild irritant Chlorite (Mineral) Professio No significant irritation nal judgeme nt Synthetic Crystalline-Free Silica Gel Rabbit No significant irritation Ethylbenzene Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value Talc Rabbit No significant irritation Toluene Rabbit Moderate irritant Titanium Dioxide Rabbit No significant irritation Magnesium Carbonate Rabbit Mild irritant Butyl Alcohol Rabbit Severe irritant Chlorite (Mineral) Professio No significant irritation nal judgeme nt Synthetic Crystalline-Free Silica Gel Rabbit No significant irritation Ethylbenzene Rabbit Moderate irritant __________________________________________________________________________________________ Page 9 of 15 3M™ Acryl-Green Spot Putty PN 05096 01/18/18 Skin Sensitization Name Species Value Toluene Guinea Not classified pig Titanium Dioxide Human Not classified and animal Butyl Alcohol Human Not classified Synthetic Crystalline-Free Silica Gel Human Not classified and animal Ethylbenzene Human Not classified Respiratory Sensitization Name Species Value Talc Human Not classified Germ Cell Mutagenicity Name Route Value Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Titanium Dioxide In Vitro Not mutagenic Titanium Dioxide In vivo Not mutagenic Butyl Alcohol In vivo Not mutagenic Butyl Alcohol In Vitro Some positive data exist, but the data are not sufficient for classification Synthetic Crystalline-Free Silica Gel In Vitro Not mutagenic Ethylbenzene In vivo Not mutagenic Ethylbenzene In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Titanium Dioxide Ingestion Multiple Not carcinogenic animal species Titanium Dioxide Inhalation Rat Carcinogenic Synthetic Crystalline-Free Silica Gel Not Mouse Some positive data exist, but the data are not Specified sufficient for classification Ethylbenzene Inhalation Multiple Carcinogenic animal species Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Talc Ingestion Not classified for development Rat NOAEL 1,600 during mg/kg organogenesi s __________________________________________________________________________________________ Page 10 of 15