4th International Symposium on High-Temperature Metallurgical Processing TIMIS2013 nd 142 Annual Meeting & Exhibition Check out these new proceedings volumes from the TMS2013 Annual Meeting, available from publisher John Wiley & Sons: 4th International Symposium on High-Temperature Metallurgical Processing Characterization of Minerals, Metals, and Materials 2013 Energy Technology 2013 EPD Congress 2013 Friction Stir Welding and Processing VII Light Metals 2013 Magnesium Technology 2013 Materials Processing Fundamentals Ni-Co2013 REWAS 2013 (CD) Supplemental Proceedings To purchase any of these books, visit www.wiley.com. TMS members: Log in to the Members Only area of www.tms.org and learn how to get your discount on these and other books offered by Wiley. 4th International Symposium on High-Temperature Metallurgical Processing Proceedings of a symposium sponsored by the Pyrometallurgy Committee and the Energy Committee of the Extraction and Processing Division of TMS (The Minerals, Metals & Materials Society) Held during the TMS 2013 Annual Meeting & Exhibition San Antonio, Texas, USA March 3-7, 2013 Edited by Tao Jiang Jiann-Yang Hwang Phillip J. Mackey Onuralp Yucel Guifeng Zhou WILEY TIMS A John Wiley & Sons, Inc., Publication Copyright © 2013 by The Minerals, Metals & Materials Society. All rights reserved. Published by John Wiley & Sons, Inc., Hoboken, New Jersey. Published simultaneously in Canada. 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For general information on other Wiley products and services or for technical sup- port, please contact the Wiley Customer Care Department within the United States at (800) 762-2974, outside the United States at (317) 572-3993 or fax (317) 572-4002. Library of Congress Cataloging-in-Publication Data is available. ISBN 978-1-11860-569-1 Printed in the United States of America. 10 987654321 WILEY TIMS A John Wiley & Sons, Inc., Publication TABLE OF CONTENTS 4th International Symposium on High- Temperature Metallurgical Processing Preface xiii About the Editors xv High Efficiency New Metallurgical Technology A New Copper Smelting Technology - Bottom Blown Oxygen Furnace Developed at Dongying Fangyuan Nonferrous Metals 3 B. Zhao, Z. Cui, and Z. Wang A Novel Vacuum Aluminothermic Reduction Lithium Process 11 Y. Di, Z. Wang, S. Tao, andN. Feng Study on Double-Layered Pellet Roasting of Sulfur and Arsenic-Bearing Gold Concentrate 19 T. Jiang, X. Li, J. Ge, L. Cui, Q. Li, and Y. Yang Preparation of M00 from Ammonium Tetramolybdate in Microwave 3 Fields 27 J. Li, L. Zhang, G Chen, J. Peng, B. Liu, and H. Xia Looping Sulfide Oxidation™ Process for Anode Copper Production 37 L. Shekhter, C. Anderson, D. Gribbin, E. Cankaya-Yalcin, J. Lessard, and L. McHugh Direct Redaction of TI-V Magnetite Via ITmk3 Technology 45 N. Panishev, B. Dubrovsky, A. Starikov, E. Redin, andE. Knyazev Research and Industrial Application of Oxygen-rich Side-blow Bath Smelting Technology 49 L. Chen, W. Bin, T. Yang, W. Liu, and S. Bin Thermal Plasma Torches for Metallurgical Applications 57 L. Rao, F. Rivard, and P. Carabin v Research on Removal of Potassium and Sodium by Pre-reduction Sintering 67 Q. Li, Z. Jing, Y. Yang, T. Jiang, G Li, andX. Chen Fundamental Research of Metallurgical Process Reaction Mechanisms and Product Morphologies on Gaseous Reduction of Metal Compounds - Extractive Metallurgy Meets Materials Science 77 P. Hayes Research on the Slag Phase Type of Vanadium-Titanium Magnetite in Pre-Reduction-Electric Furnace Smelting 87 Y. Guo, M. Tang, T. Jiang, L. Qing, and J. Zhou Density of CaO-5%MgO-Al 0 -Si0 Slag with Low Silica 95 2 3 2 J. Li, T. Zeng, J. Xu, C. Jie, J. Zhang, and K. Chou Study on Magnetic Roasting Kinetic of Oolitic Hematite 103 Y. Guo, L. Qing, T. Jiang, L. Yang, S. Liu, M. Tang, X. Song, andJ. Zhou Basic Research on External Desulfurization of Hot Iron by Dolomite Ill X. Ren, T. Zhang, Y. Liu, Z. Dou, and G Lv Iron-Carbon Nuggets Coalescence: Influence of Slag's Liquidus Temperatures 117 A. Nogueira, C. Takano, M. Mourào, and A. Pillihuaman Effect of Mixed Charge of Ore and Lump Coal on the Softening-Melting Property of the Burden 125 H. Guo, G Yang, J. Zhang, J. Shao, Y. Fu, and D. Wan Effects of Oxygen Content and Roasting Temperature on the Sintering Mineralization Properties of Different Iron Ores 131 X. Mao, Z. You, Y. Zhang, Z. Fan, and T. Jiang Analysis on Wear Mechanism of Refractories Used in Hot Air Pipeline for Large Scale Blast Furnaces 139 G Xu, X. Chen, X. Huang, W. Xiang, and H Zhang VI Alloy and Materials Preparation I Hot Workability of M42 Tool Steel Additionally Alloyed with Co and Mo ....147 M. Tercelj, G Kugler, M. Fazarinc, and I. Perm Effects of Crystallization of Mould Fluxes on Property of Liquid Slag Film and Its Impact onPeritectic Steel Slab Continuous Casting 155 X. Long, S. He, L. Zhu, T. Wu, and Q. Wang Hot Ductility of Nb-V Containing Microalloyed Steel during Solidification...163 Y. Sun, Y. Zeng, andK. Cai Co-Cr-Mo Alloys Production by Self Propagating High Temperature Synthesis 171 O. Okur, M. Alkan, and O. Yiicel High-Temperature Oxidation and Corrosion Behaviors of Ni-Fe-Cr Alloy for Inert Anode Materials in Aluminum Electrolysis 177 J. Xue, L. Feng, G Ndong, J. Zhu, and Q. Liu Production of Molybdenum Containing Iron Based Alloys via Metallothermic Processes 185 D. Kirgöz, M. Alkan, and O. Yiicel Electrical Resistance of TiB -C/C Function Gradient Materials for Aluminum 2 Reduction Cathodes 191 J. Zhu, J. Xue, and B. Li Experimental Study of Phosphorus Distribution Between Slag and Metal during Duplex Dephosphorus Converter Processing 199 X. Qiu, B. Xie, L. Jiang, X. Zhang, J. Diao, and H. Li The Effect of Aluminum Addition to the ESR Process Slag on IN718 Superalloy Characteristics 207 A. Sheikhhosseini, and S. Abbasi Alloy and Materials Preparation II Production of Fe-Based Alloys by Metall othermic Reduction of Mill Scales from Continuous Casting Processes 219 M. Bugdayci, M. Alkan, and O. Yiicel Study of Heat Flux in CSP Continuous Casting Mold 227 W. Yang, X. Wang, L. Zhang, D. Yang, andX. Liu vn The Effect of Thermomechanical Ageing of Aluminium-Copper Alloy (MATLAB Approach) 239 A. Amos, G Akeem, F. Emmanuel, O. Ajibade, and O. Oladayo Research on Inclusions in CuCr Alloy Prepared by Thermit Reduction 247 Z. Dou, T. Zhang, G Shi, Y. Du, L. Niu, G Lv, Y. Liu, and J. He Copper-Based Multi-Component Alloys by Vacuum Distillation to Separate Copper Enriched Lead, Silver and Other Valuable Metals Research 255 H. Xiong, B. Yang, D. Liu, B. Xu, X. Chen, and Y. Deng An Overview of Research on Au & Ag Recovery in Copper Smelter 265 Y. Shi, and Z. Ye The Analysis of Orthogonal Experiment Method of Carbon-Coated LiNi/3Mn Co/302 via Microwave-pyrolysis Method 277 1 1/3 1 Y. Han, Z. Zhang, L. Zhang, J. Peng, and M. Fu Comparative Study on the Metal Aluminum Produced from Alumina by Carbothermic Reduction and Carbothermic-Chlorination 287 Q. Yu, B. Yang, Y. Deng, F. Wang, H Xiong, and M. Chen Continuously Synthesis and Performance of Cathode Material LiNi/Co/Mn/02 for Lithium Ion Batteries 293 13 13 13 M. Fu, L. Zhang, Z. Zhang, J. Peng, Y. Han, and J. Du Tensile Mechanical Properties and Brittle Effect of Austempered Cr-Mo Alloy Steel 299 C Chen, F. Hung, T. Lui, and L. Chen Roasting, Reduction and Smelting Cost Benefits of EAF Bottom Purging Systems Due to Metallurgical Improvements 309 M. Kirschen, A. Hanna, andK. Zettl Researches on Reduction Roasting of Low-Grade Manganese Oxide Ores Using Biomass Charcoal asReductant 317 Y. Zhang, D. Duan, Z. You, G Li, X. Fan, and T. Jiang Reduction Behavior of Pellets Balled with Bentonite 325 T. Jiang, G Han, Y. Huang, G Li, and Y. Zhang vin